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Understanding Covalent Bonds & Non-Bonding Electrons in Organic Chemistry, Study notes of Organic Chemistry

An introduction to chemical bonding theory in organic chemistry, focusing on the unique properties of carbon compounds and the formation of covalent bonds. Topics covered include the origins of organic chemistry, the development of chemical bonding theory, and the nature of chemical bonds, including valence electrons and non-bonding electrons.

Typology: Study notes

2021/2022

Uploaded on 09/12/2022

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Chemical Bonding Theory
Organic Chemistry
Mrs. Dormer
*Organic chemistry is study of carbon compounds.
*Why is it so special?
*90% of more than 30 million chemical compounds contain carbon.
*Examination of carbon in periodic chart answers s ome of these questions.
*Carbon is group 4A element, it can share 4 valence electrons and form 4
covalent bonds.
Origins of Organic Chemistry
*Kekulé and Couper independently observed that carbon
always has four bonds
*van't Hoff and Le Bel proposed that the four bonds of
carbon have specific spatial directions
*Atoms surround carbon as corners of a tetrahedron
Development of Chemical
Bonding Theory
*Atoms form bonds because the compound that results is
more stable than the separate atoms
*Ionic bonds in salts form as a res ult of electron transfers
*Sodium Chloride
*Magnesium Oxide
The Nature of Chemical
Bonds
O + O
[
[
2-
Ionic Bonding
O
[
[
2-
Mg 2+
Magnesium Oxide
[
[
*Organic compounds have covalent bonds from
sharing electrons
Cl
Cl
Cl
Cl
+
pf3

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Chemical Bonding Theory

Organic Chemistry Mrs. Dormer

  • Organic chemistry is study of carbon compounds.
  • Why is it so special?
  • 90% of more than 30 million chemical compounds contain carbon.
  • Examination of carbon in periodic chart answers some of these questions.
  • Carbon is group 4A element, it can share 4 valence electrons and form 4 covalent bonds.

Origins of Organic Chemistry

  • Kekulé and Couper independently observed that carbon always has four bonds
  • van't Hoff and Le Bel proposed that the four bonds of carbon have specific spatial directions
  • Atoms surround carbon as corners of a tetrahedron

Development of Chemical

Bonding Theory

  • Atoms form bonds because the compound that results is more stable than the separate atoms
  • Ionic bonds in salts form as a result of electron transfers
  • Sodium Chloride
  • Magnesium Oxide

The Nature of Chemical

Bonds

O + [O

[ 2 -

Ionic Bonding

[^ O

[ 2 -

Mg

Magnesium Oxide

[

[

  • Organic compounds have covalent bonds from sharing electrons

Cl

• Cl

Cl

• Cl•

  • Lewis structures (electron dot) show valence electrons of an atom as dots
  • Hydrogen has one dot, representing its 1 s electron
  • Carbon has four dots (2 s^2 2 p^2 )

The Nature of Chemical Bonds

  • Kekulé structures (line-bond structures) have a line drawn between two atoms indicating a 2 electron covalent bond.
  • Stable molecule results at completed shell, octet (eight dots) for main-group atoms (two for hydrogen) Line-Bond Structures
  • Atoms with one, two, or three valence electrons form one, two, or three bonds.
  • Atoms with four or more valence electrons form as many bonds as they need electrons to fill the s and p levels of their valence shells to reach a stable octet.
  • Carbon has four valence electrons ( 2s^2 2p^2 ), forming four bonds (CH 4 ).

The Nature of Chemical Bonds

  • Nitrogen has five valence electrons (2 s^2 2 p^3 ) but forms only three bonds (NH 3 ).
  • Oxygen has six valence electrons (2 s^2 2 p^4 ) but forms two bonds (H 2 O)

The Nature of Chemical Bonds

The Nature of Chemical Bonds

  • Valence electrons not used in bonding are called nonbonding electrons , or lone-pair electrons
  • Nitrogen atom in ammonia (NH 3 )
  • Shares six valence electrons in three covalent bonds and remaining two valence electrons are nonbonding lone pair Non-Bonding Electrons