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Formation of Compounds: Ionic and Covalent Bonds, Exams of Chemistry

An in-depth exploration of the formation of compounds through ionic and covalent bonds. It covers the seven diatomic molecules, the concept of valence electrons, and the octet rule. The document also discusses the properties of various elements and their ions, as well as the ways to achieve a stable outer energy level. It includes numerous examples and electron dot diagrams.

Typology: Exams

2021/2022

Uploaded on 09/27/2022

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Ch. 4 NOTES ~ Formation of Compounds
NOTE: Vocabulary terms are in boldface and underlined. Supporting details are in italics.
I. Element Review
THE SEVEN DIATOMIC MOLECULES (“Super Seven”):
H2 F2 O2 N2 Cl2 Br2 I2
THE METALLOIDS: B, Si, Ge, As, Sb, Te, Po, At
COMMON ELEMENTS TO KNOW (symbols and names):
Ag, Al, Ar, As, Au, B, Ba, Be, Bi, Br, C, Ca, Cl, Co, Cr, Cs, Cu, F, Fe, Fr, H,
He, Hg, I, K, Kr, Li, Mg, Mn, N, Na, Ne, Ni, O, P, Pb, Ra, Rb, S, Sb, Si, Sr,
Sn, U, W, Zn
II. Valence Electron Review
A. Valence electrons—the electrons in the highest energy level of at atom (“highest
shell” or highest n)
1) tells how many are available for bonding
2) tells how many e- will be gained or lost in forming ions
GROUP #: VALENCE # USUALLY, WHEN FORMING IONS:
OUT OF 8:
Group IA 1 loses 1
Group IIA 2 loses 2
Group IIIA 3 loses 3
Group IVA 4 can lose or gain
Group VA 5 gains 3
Group VIA 6 gains 2
Group VIIA 7 gains 1
Group VIIIA 8 does not form ions
B. Review electron dot diagrams (Lewis structures)
III. Atoms and Ions
A. atomic neutrality: atoms are neutral (net charge of zero) # protons = # electrons
B. iona charged atom(s) or a charged group of atoms
1) formed by gain or loss of electrons
2) cationa positive ion formed by losing electrons
3) aniona negative ion formed by gaining electrons
common ending is —IDE (chloride, bromide, iodide...)
ions of Group VIIA, the halogens, are called halide ions
CP AN Cations Positive, Anions Negative “Cat People Are Nice”
YOU CAN’T LOSE OR GAIN PROTONS TO FORM AN ION !
4) an ion has different properties than its element (Na atom vs. Na+ ion)
5) examples...
Q: Aluminum loses three electrons when its ion is formed. Write its symbol and charge. A: Al3+
Q: Oxygen gains two electrons when its ion is formed. Write its symbol and charge. A: O2-
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Ch. 4 NOTES ~ Formation of Compounds

NOTE: Vocabulary terms are in boldface and underlined. Supporting details are in italics.

I. Element Review

THE SEVEN DIATOMIC MOLECULES (“Super Seven”) :

H 2 F 2 O 2 N 2 Cl 2 Br2 I 2

THE METALLOIDS: B, Si, Ge, As, Sb, Te, Po, At

COMMON ELEMENTS TO KNOW (symbols and names):

Ag, Al, Ar, As, Au, B, Ba, Be, Bi, Br, C, Ca, Cl, Co, Cr, Cs, Cu, F, Fe, Fr, H,

He, Hg, I, K, Kr, Li, Mg, Mn, N, Na, Ne, Ni, O, P, Pb, Ra, Rb, S, Sb, Si, Sr,

Sn, U, W, Zn

II. Valence Electron Review A. Valence electrons —the electrons in the highest energy level of at atom (“highest shell” or highest n)

  1. tells how many are available for bonding
  2. tells how many e- will be gained or lost in forming ions

GROUP #: VALENCE # USUALLY, WHEN FORMING IONS: OUT OF 8:

Group IA 1 loses 1 Group IIA 2 loses 2 Group IIIA 3 loses 3 Group IVA 4 can lose or gain Group VA 5 gains 3 Group VIA 6 gains 2 Group VIIA 7 gains 1 Group VIIIA 8 does not form ions

B. Review electron dot diagrams (Lewis structures)

III. Atoms and Ions A. atomic neutrality: atoms are neutral (net charge of zero) # protons = # electrons B. iona charged atom(s) or a charged group of atoms

  1. formed by gain or loss of electrons
  2. cationa positive ion formed by losing electrons
  3. aniona negative ion formed by gaining electrons
  • common ending is —IDE (chloride, bromide, iodide...)
  • ions of Group VIIA , the halogens, are called halide ions

CP AN Cations Positive, Anions Negative “Cat People Are Nice” YOU CAN’T LOSE OR GAIN PROTONS TO FORM AN ION!

  1. an ion has different properties than its element (Na atom vs. Na +^ ion)
  2. examples...

Q: Aluminum loses three electrons when its ion is formed. Write its symbol and charge. A: Al 3+

Q: Oxygen gains two electrons when its ion is formed. Write its symbol and charge. A: O2-

IV. 4.1 Notes: The Variety of Compounds ** properties of individual elements may differ from their ions ** properties of individual elements may differ from the compounds they can form

NAME SYMBOL PHYSICAL STATE at room temp.

PROPERTIES

sodium Na solid 1) metal

  1. silver-white
  2. soft
  3. reacts violently with H 2 O and O (^2) chlorine Cl 2 gas 1) nonmetal
  4. greenish
  5. poisonous
  6. stinging odor
  7. disinfectant sodium chloride NaCl solid 1) white crystals
  8. soluble in water
  9. important to cells
  10. stable

carbon C solid 1) nonmetal

  1. brown to black
  2. main ingredient of charcoal and coal
  3. burns at high temperatures
  4. main component of organic chemicals oxygen O 2 gas 1) nonmetal
  5. colorless
  6. odorless
  7. vital to living organisms carbon dioxide CO 2 gas 1) colorless
  8. odorless
  9. stable
  10. dissolves in water

hydrogen H 2 gas 1) nonmetal

  1. flammable
  2. colorless oxygen O 2 gas 1) nonmetal
  3. colorless
  4. odorless
  5. vital to living organisms water H 2 O liquid 1) colorless
  6. odorless
  7. stable
  8. vital to living organisms

b) Aluminum has three valence electrons. It is easier to lose three than to gain five. It forms a 3+ ion, exposing its filled n = 2 shell.

Al Æ Al 3+^ + 3e -

The aluminum ion has the Noble Gas configuration of neon (10 e-), but it still has a nucleus with 13 protons, keeping it an ion of aluminum.

B. formation of anions

  1. the octet rule applies
  2. common ending is —IDE (chloride, sulfide, oxide...)
  3. examples a) Chlorine has seven valence electrons. It only needs one more to achieve a Noble Gas configuration. It forms a 1- ion and has the configuration of argon.

Cl + e -^ Æ Cl -

The chloride ion has the Noble Gas configuration of argon (18 e-), but it still has a nucleus with 17 protons, keeping it an ion of Cl. b) Sulfur has six valence electrons. It only needs two more to achieve a Noble Gas configuration. It forms a 2- ion and has the configuration of argon.

S + 2 e -^ Æ S2-

The sulfide ion has the Noble Gas configuration of argon (18 e-), but it still has a nucleus with 16 protons, keeping it an ion of S.

IX. Electron Dot Diagrams for Ionic Compounds

sodium atom chlorine atom Æ Æ sodium ion chloride ion “sodium chloride”

aluminum atom chlorine atom Æ Æ aluminum ion chloride ions “aluminum chloride” (three chlorines are needed to balance the charges)

X. Formation of Covalent Compounds (electron sharing) A. single covalent bond —a sharing of electrons between two atoms

  1. consists of one electron from each partne r
  2. weaker than an ionic bond
  3. smaller difference in electronegativity between the bonding partners
  4. bonding will occur to achieve a Noble Gas valence configuration B. structural formula —set of symbols showing the arrangement and bonding patterns of atoms C. molecule —a covalent compound existing as defined molecules, not formula units

XI. Multiple Covalent Bonds: Double and Triple Bonds A. double covalent bond —sharing two pairs of electrons B. triple covalent bond —sharing three pairs of electrons

XII. Electron Dot Diagrams for Covalent Compounds A. remember the octet rule (no lone electron dots when finished) B. draw each electron dot diagram using the “A” group numbers C. make the compound by combining the individual structures D. examples

  1. single bonds

OR

single boron atom with three fluorines Æ boron trifluoride

  1. double bonds

OR

single O atom single O atom Æ diatomic oxygen molecule

  1. triple bonds

OR 2 nitrogen atoms Æ diatomic nitrogen molecule