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Understanding Kekule Structures & Resonance: Chemical Structures & Polar Covalent Bonds, Study notes of Chemistry

An introduction to writing chemical structures using various notations, including condensed and skeletal. It covers the basics of polar covalent bonds, electronegativity, and the inductive effect. The document also explains the concept of resonance and its significance in chemistry. Students will learn how to draw structures for molecules like nitromethane and benzene using the curved arrow convention.

What you will learn

  • What are the differences between condensed and skeletal notations for writing chemical structures?
  • What is the significance of electronegativity in polar covalent bonds?

Typology: Study notes

2021/2022

Uploaded on 09/12/2022

palumi
palumi 🇺🇸

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Writing (Drawing) Chemical Structures
CH3CH2CHCH3CH3CH2CH(CH3)2
H C C
H
H
C C
C
H
H
H
H
H
H
H
HH CH3
Kekule Condensed Skeletal
Skeletal Notation
1. Carbon atoms are at the ends of lines and at the intersection of two lines
2. Hydrogens on carbon atoms are not shown.
3. All non-carbon and non-hydrogen atoms (heteroatoms) are shown.
4. Hydrogens on heteroatoms are shown
5. Formal Charges are shown
Polar Covalent Bonds: covalent bonds in which the electrons are not
equally shared between the two atoms. \ The is a net dipole.
Electronegativity: intrinsic ability of an atom to attract electrons
Inductive Effect: atom’s (or group of atoms) ability to polarize a bond
through electronegativity differences
Chapter 2: Polar Covalent Bonds and Their Consequences
pf3
pf4

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Download Understanding Kekule Structures & Resonance: Chemical Structures & Polar Covalent Bonds and more Study notes Chemistry in PDF only on Docsity!

Writing (Drawing) Chemical Structures

H C C^ CH^3 CH^2 CHCH^3 CH^3 CH^2 CH(CH^3 )^2

H

H

C C

C

H

H

H

H

H

H

H H H CH 3

Kekule (^) Condensed Skeletal

Skeletal Notation

1. Carbon atoms are at the ends of lines and at the intersection of two lines

2. Hydrogens on carbon atoms are not shown.

3. All non-carbon and non-hydrogen atoms (heteroatoms) are shown.

4. Hydrogens on heteroatoms are shown

5. Formal Charges are shown

Polar Covalent Bonds: covalent bonds in which the electrons are not

equally shared between the two atoms. \ The is a net dipole.

Electronegativity: intrinsic ability of an atom to attract electrons

Inductive Effect: atom’s (or group of atoms) ability to polarize a bond

through electronegativity differences

Chapter 2: Polar Covalent Bonds and Their Consequences

Electronegativity tends to decrease down a period,

and increase across a row (from left to right

Resonance

H C N

H

H

O

O _^

H C N

H

H

O _

O

C

C

C

C

C

C

H

H

H

H

H

H

C

C

C

C

C

C

H

H

H

H

H

H

nitromethane

benzene

Which is the correct structure?