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Elementary Inorganic Chemistry Problem Set 6 - Morehouse College - Prof. Brian Lawrence, Assignments of Inorganic Chemistry

A problem set for chemistry 112 - elementary inorganic chemistry at morehouse college. The assignment includes various questions on specific heats, thermodynamics, combustion, and enthalpy of formation. Students are required to answer the questions neatly and without explanations for full credit.

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Pre 2010

Uploaded on 08/04/2009

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Chemistry 112 – Elementary Inorganic Chemistry
Morehouse College – Problem Set 6
DUE: Wednesday, April 9, 2008 in class
Answer all questions in the space provided, neatly written. Thanks.--BML
1. (1 pt. each) For each of the following questions, circle the BEST answer (no
explanation is required for full credit).
a. 1.219 kJ of heat are required to raise the temperature of 250 g of an unknown
metal by 64 °C. What is the specific heat of this metal (in J g
-1
°C
-1
)?
2.0 x 10
7
1.3 x 10
1
3.1 x 10
-2
4.8 x 10
3
7.6 x 10
-2
b. Based on your knowledge of thermodynamics, which of the following statements
is FALSE?
Kinetic energy Energy is Heat moves from none of these
is the energy of the capacity to a warmer body to
motion do work a colder one
c. 708 mg of C
6
H
12
O (
f
= -890.7 kcal mol
-1
) undergoes complete combustion in
a bomb calorimeter with heat capacity 2.70 kcal °C
-1
? What is the final
temperature if the initial water temperature is 27.0 °C?
24.7 °C 26.6 °C 27.4 29.3 none of these
d. Which of following substances has a standard enthalpy of formation of zero?
That is,
f
= 0 kJ mol
-1
?
I
2(g)
Ar
(g)
Br
2(g)
O
3(g)
e. How much work is done (in J) when a gas expands by 24.0 L against a constant
pressure of 75 atm at 45.3 °C?
1.8 x 10
3
-8.2 x 10
4
8.2 x 10
4
-1.8 x 10
5
none of these
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Chemistry 112 – Elementary Inorganic Chemistry

Morehouse College – Problem Set 6

DUE: Wednesday, April 9, 2008 in class

Answer all questions in the space provided, neatly written. Thanks.--BML

  1. (1 pt. each) For each of the following questions, circle the BEST answer (no explanation is required for full credit).

a. 1.219 kJ of heat are required to raise the temperature of 250 g of an unknown metal by 64 °C. What is the specific heat of this metal (in J g-1^ °C -1)?

2.0 x 10^7 1.3 x 10^1 3.1 x 10-2^ 4.8 x 10^3 7.6 x 10-

b. Based on your knowledge of thermodynamics, which of the following statements is FALSE?

Kinetic energy Energy is Heat moves from none of these is the energy of the capacity to a warmer body to motion do work a colder one

c. 708 mg of C 6 H 12 O (∆H° f = -890.7 kcal mol-1) undergoes complete combustion in a bomb calorimeter with heat capacity 2.70 kcal °C -1? What is the final temperature if the initial water temperature is 27.0 °C?

24.7 °C 26.6 °C 27.4 29.3 none of these

d. Which of following substances has a standard enthalpy of formation of zero? That is, ∆H° f = 0 kJ mol-1?

I2(g) Ar(g) Br2(g) O3(g)

e. How much work is done (in J) when a gas expands by 24.0 L against a constant pressure of 75 atm at 45.3 °C?

1.8 x 10^3 -8.2 x 10^4 8.2 x 10^4 -1.8 x 10^5 none of these

  1. (5 pts) A 12-inch diameter ball of pure cobalt metal (ρ = 8.862 g mL-1) at 225 °C is placed in 10.0 gal of water at 15.0 °C. Assuming t hat no heat is lost to the surroundings, calculate the final temperature of the water once homeostasis has been reached. Report your answers in the space provided with the correct number of significant figures. Show your work. A correct response without any justification (work) will receive no credit. You may attach additional sheets as required.

NOTE: The molar heat capacity ( C p) for cobalt is 7.14 x 10-3^ J mol-1^ °C -