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A problem set for chemistry 112 - elementary inorganic chemistry at morehouse college. The assignment includes various questions on specific heats, thermodynamics, combustion, and enthalpy of formation. Students are required to answer the questions neatly and without explanations for full credit.
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DUE: Wednesday, April 9, 2008 in class
Answer all questions in the space provided, neatly written. Thanks.--BML
a. 1.219 kJ of heat are required to raise the temperature of 250 g of an unknown metal by 64 °C. What is the specific heat of this metal (in J g-1^ °C -1)?
2.0 x 10^7 1.3 x 10^1 3.1 x 10-2^ 4.8 x 10^3 7.6 x 10-
b. Based on your knowledge of thermodynamics, which of the following statements is FALSE?
Kinetic energy Energy is Heat moves from none of these is the energy of the capacity to a warmer body to motion do work a colder one
c. 708 mg of C 6 H 12 O (∆H° f = -890.7 kcal mol-1) undergoes complete combustion in a bomb calorimeter with heat capacity 2.70 kcal °C -1? What is the final temperature if the initial water temperature is 27.0 °C?
24.7 °C 26.6 °C 27.4 29.3 none of these
d. Which of following substances has a standard enthalpy of formation of zero? That is, ∆H° f = 0 kJ mol-1?
I2(g) Ar(g) Br2(g) O3(g)
e. How much work is done (in J) when a gas expands by 24.0 L against a constant pressure of 75 atm at 45.3 °C?
1.8 x 10^3 -8.2 x 10^4 8.2 x 10^4 -1.8 x 10^5 none of these
NOTE: The molar heat capacity ( C p) for cobalt is 7.14 x 10-3^ J mol-1^ °C -