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9 Problems with Solution in Exam - Introduction to Chemical Principles | CHEM 40, Exams of Chemistry

Material Type: Exam; Professor: Pauly; Class: Intro to Chemical Principles; Subject: Chemistry; University: City College of San Francisco; Term: Spring 2009;

Typology: Exams

Pre 2010

Uploaded on 08/19/2009

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LMrn L- Whrte
Short Answer Fill in the blank(s) with the best
possible
word,
expression or number.
7. In one or two complete sentences,
explain
the difference
between the terms empirical formula
and
molecular fo nula. (4
poinrs)
1r^- e^q,nlt,"l -{o,^rL[^ 'p Itra (owet+ w\^ole 6111..6",-
zti- .{
t ur),, < \.w,eal )y, 7a ,utv-y,t^n).
-h. !,.o\d,^U^c Qr.-r\.n \s + Q .\.4v-a-! nutr"rLr c,{ zL"b,.=
(eseul vt rn ,'rol"L-\< , fnn 1,rtt.. ".L.n n,J,
8. How many moles
of each
element
are
present
in I mole
of Cur(POJr?
(3
points)
1 rc-le:;
2 uv'-\<
:'
? ,*-lrs
L,.^
9, An aqueous solution of sodium carbonate was mixed with
an aqueous
solution of calcium chloride,
The
precipitate
calcium carbonate was formed. Write
a balanced chemical
eqlntion for this
process.
(6 poinls)
Na,2.('O
j1/
or) *( aLlz ,0,,, +) Na( | 1,r,,,
t(
aCO
e
,r;
10. Classify the following
compounds as strong electrolyte, weak
electrolyte, non-electrolyte or
insoluble.
Write the
formula
of the species
(atom,
ion, or molecule)
that exists in water for each
case. (6
pointr)
Non-electrolyte, or Insoluble cies in Water
P
()
MgC03
C"H,O" rslucose)
tutl tn 9 $)
C.,
t\rz
oc.
(.2)
N^+
cn" , W-{a
Strong-, Weak-, or
i
n< at
tL
[i<
n oia
-
$lrru nA -
NaBr
pf3
pf4
pf5

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LMrn L-

Whrte

Short Answer Fill in theblank(s)with thebestpossibleword,expressionor number.

  1. In oneor two completesentences, explain

thedifference betweenthetermsempiricalformulaand

molecularfo nula. (4poinrs)

1r^-

e^q,nlt,"l -{o,^rL[^

'p

Itra

(owet+

w^ole 6111..6",- zti-

t ur),, < .w,eal )y, 7a

,utv-y,t^n).

-h.

!,.o\d,^U^c

Qr.-r.n \s

+ Q

..4v-a-!

nutr"rLr

c,{ zL"b,.=

(eseul

vt rn

,'rol"L-<

fnn 1,rtt..

".L.n

n,J,

  1. How manymolesof eachelementarepresentin I moleof Cur(POJr?(3points)

rc-le:;

uv'-<:'

?

,*-lrs

L,.^

9, An aqueoussolutionof sodiumcarbonatewasmixedwith an aqueous solutionof calciumchloride,

The

precipitate calciumcarbonatewasformed.Writea balancedchemicaleqlntionfor this process.

(6 poinls)

Na,2.('Oj1/

or)

( aLlz

Na( | 1,r,,,t

aCOe

,r;

  1. Classifythefollowingcompoundsasstrongelectrolyte,weakelectrolyte, non-electrolyteor

insoluble.Writetheformulaof thespecies

(atom,ion,or molecule) thatexistsin waterfor each

case.

(6 pointr)

Non-electrolyte,or Insoluble ciesin Water

P

()

MgC

C"H,O" rslucose)

tutl tn

C.,t\rz oc. (.2)

N^+cn"

,

W-{a

Strong-,Weak-,or

i n< attL[i<

n oia -

$lrru nA - NaBr

  1. Completeandbalancetlefollowing molecularequations.Writethenetionicreaction in the

appropriateblank. Be sureto indicatethestateof each compound,ion,or atom. Pleasenote,the

complete ionic equationwill not be

graded.(12poinrs)

a) NH4CI(act +

A".CIrr, +

NltaN\o'.r

AgNO

(aq)

netionic:

CI t

^1>

l-

M*

f

^rl

b) Ba(OH),
(aq) +
HCIO(aq)
(noprecipitate
obseryed)
I

t/\J

( 4k

aU''! /qaaa

r.Ar+Y"a

tk

lter lonlc:

!

2 r\2o

(,

I

bcx( +lc

to)z r

^J)

  1. Combustion of a 2,000g sampleof an unknowncompoundprcduced 0.1033molesof carbon

dioxideand0.1033molesof water. How manymolesofcarbonandhydrogen does the sampleof

the unknowncompoundcontain? (3points)

-,

1- Stl c I o,.,, y

'-->

2+trO1a |

2

O. lo

.*.,l

o t to bV m-|

*\2,c,

X

Z

^.f

r\

molescarbon:

moleshydrogen:

O, Zc,("te

--\

l"d-l
h\zc)
  1. 3-Chlorotolueneis composed

of 66.4270carbon,5.58%hydroger,ard 28.0070chlodneby mass.

The molecularmass

wasfoundto be 126.

glrr,ol.Determine theempiricalandmolecular

formulasof 3-chlorotoluene.

points)

Assuwre \0o

)

S".\r'Tk-

I

bb.c

t

qSlo+

^", "-.< ^^

7.auz c

tl.ol,
'J.-7bqP

s.sf X

fl

["""rH

=

7-sz\t

^ot

A--

--

u,q

v]

| ,ot,

d.

at.oosc).

l*'t ct

. E.=7T-q-t

."t cl

I c I

" as\n

lru

M-olarr',.a-rs

C1)\14. lzc,s1 Slw,ol

UH"1C\

t

9^vne

as

v".o t e[r.Ia,r r"^a-t

So

S 4 r"v? {Vrntr-Ul

empiricalformula:

C1fl1 cl

, a-H.C(

molecularlormula:

  1. Dr. Bunsenhasaskedfor your helpin herresearchlab. Sinceyou lovechemistry,you helpby

combining2.729of tin with 1.46g of hydrochloricacid. Thefollowingreactionoccurs.

Sn(s) + 2Hcl(aq)

Snct(aq) + Hz(g)

a) How manygramsof hydrogengaswill be

produced? (10points)

r ,Ltb$

H( |

l.'"t u^

o. oqt6t?

z

'1b.qu
i^$l F{(l

/,r?

g Sn

l*'l

Sn

I rt.r,

O.o2)1lL{'1 $.)
Sn
f 'l'.tt

/ z-"r u.q

/ x-

i

/*ol Sa

o .O+ot+.\

q

K_

Iis.-?<

(

l^.t

sn

2^^

Ftcl

\

o, o$ I &1e_&

\

/\oI

fcl

I

tW ru'r

'

'

tFn ot

{un o

'-t

\

{:.

!4^d

o7007t1.g.ol

I

*9n

r?14-/ ce,{

fuLwe eno45r

dr- u8-

FCI

o. oqo5+3q

^\o

I Hcl

I

"*.r

l.tz-

),'u'"

rlcl

o.ul\oi{

D.o)TqA

-ro

I Sn

o. oJ6-o2l 4,v,."I S"-'

0, o-0>8q,
^ol \ i'\

qh.

wl

J |

-2,-

b) Determinethe amount,in grams,of eachreactant

plesent

AIICI

thereactionis complete.

(6 points)

e^.r-A

o

^-a)
ns
v rr,r,eo,
cte'{

o. oDttl]

Yv\oI 54

x

a.24 341

)n

Hcl:

O

I Sn