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Alcohols and Ether Problems - Practice Quiz | CHEM 212, Assignments of Organic Chemistry

Material Type: Assignment; Class: Organic Chemistry II; Subject: Chemistry; University: Bucknell University; Term: Unknown 1989;

Typology: Assignments

Pre 2010

Uploaded on 08/18/2009

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OH
OH
OH
Chem 212
Alcohols and Ethers Problems
OH
1. Provide products for the following reactions.
a.
OH
b.
c.
OH
d.
e.
OH
f.
g.
OH
h.
i.
OH
j.
k.
OH
l.
m.
OH
n.
NaH
OH
PhMgBr
H2SO4
H2O,
OH
HBr
PBr3
SOCl2
pyr
TsCl, pyr
CrO3
H2SO4
PCC
Na2Cr2O7
Me3SiCl
Et3N
1) NaH
2) MeBr
H2SO4
1) Hg(O2CCF3)3, propanol
2) NaBH4
o.
p.
q.
r.
O
s.
t.
O
u.
v.
O
w.
x.
y.
z.
CF3CO2H
O
HBr
HI
O
mCPBA
mCPBA
1) Cl2, H2O
2) NaOH
O
KOH, H2O
1) PhMgBr
2) H3O+
O
1) mCPBA
2) NaOEt, EtOH
O
HBr, ether
1) LiAlH4
2) H3O+
1) MeMgBr
2) H3O+
3) H2SO4,
4) 1,3-butadiene, heat
5) mCPBA
6) NaOH, H2O

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OH

OH

OH

Chem 212Alcohols and Ethers Problems

OH

  1. Provide products for the following reactions.a.

OH

b. c.

OH

d. e.

OH

f. g.

OH

h. i.

OH

j. k.

OH

l. m.

OH

n.

NaH

OH

PhMgBr

HH2 2 SO4 O, ∆

OH

HBr PBr 3

SOCl2pyr

TsCl, pyr

CrOH2 SO4 (^3)

PCC

Na (^) 2Cr2O

MeEt 33 N SiCl

  1. NaH2) MeBr

H 2SO

  1. Hg(O2) NaBH2CCF 4 3)3, propanol

o. p. q. r.

O

s. t.

O

u. v.

O

w. x. y. z.

CF 3 CO 2H

O

HBr HI

O

mCPBA mCPBA

  1. Cl2) NaOH 2 , H (^) 2O

O

KOH, H2O

  1. PhMgBr2) H 3 O+

O

  1. mCPBA2) NaOEt, EtOH

O

HBr, ether

  1. LiAlH2) H (^) 3O+ (^4)
  2. MeMgBr2) H3O+
  3. H2SO 4) 1,3-butadiene, heat5) mCPBA4, ∆
  4. NaOH, H2O