Docsity
Docsity

Prepare for your exams
Prepare for your exams

Study with the several resources on Docsity


Earn points to download
Earn points to download

Earn points by helping other students or get them with a premium plan


Guidelines and tips
Guidelines and tips

Answer Key for Past Exam 2 - Chemistry 1 - Introduction |, Exams of Chemistry

Material Type: Exam; Class: Chemistry 1 - Introduction; Subject: Chemistry; University: Albright College; Term: Forever 1989;

Typology: Exams

Pre 2010

Uploaded on 12/04/2009

biochick
biochick 🇺🇸

12 documents

1 / 8

Toggle sidebar

This page cannot be seen from the preview

Don't miss anything!

bg1
Chemistry 105 Exam II November 30, 2007
I certify I have not used a programming calculator for anything other than simple mathematical
operations.
_______________________________________ (Signature)
_______________________________________ (Printed name)
Multiple choice (3 pts. each) DARKEN THE CORRECT ANSWER ON THE ANSWER SHEET.
Remember there are also 3 problems given after the 22 multiple-choice questions. Budget your time
accordingly.
1. Which one of the following bonds would be the least polar?
a) N-F b) C-F c) Si-F d) O-F
2. Which one of the following ionic compounds would have the highest melting point?
a) K2O b) MgO
c) CaCl2d) KCl
e) NaBr
3. Based on formal charges, identify the most favorable resonance form of the cyanate ion.
a)
NCO
b)
NC O
c)
NC O
d) All are equivalent
4. The Lewis electron-dot structure of ClF3 gives the central Cl
a) 3 nonbonding pairs and 2 bonding pairs
b) 5 bonding pairs only
c) 2 nonbonding pairs and 4 bonding pairs
d) an octet
e) 2 nonbonding pairs and 3 bonding pairs
5. For the nitrite ion (NO2-),
a) both bonds are single bonds
b) both bonds are double bonds
c) both bonds are the same, each being stronger than a single bond but longer and weaker than a
double bond
d) one bond is a single bond and the other is a double bond
6. For resonance forms of a molecule or ion
a) one always corresponds to the actual observed structure
b) all always correspond to the actual observed structure
c) the same atoms need not be bonded to each other in all resonance forms
d) the actual observed structure is an average of the resonance forms
e) all always correspond to the actual observed structure and the same atoms need not be bonded to
each other in all resonance forms
Chemistry 105A –Exam 3: 2007 WHITE 1 / 4
pf3
pf4
pf5
pf8

Partial preview of the text

Download Answer Key for Past Exam 2 - Chemistry 1 - Introduction | and more Exams Chemistry in PDF only on Docsity!

Chemistry 105 Exam II November 30, 2007 I certify I have not used a programming calculator for anything other than simple mathematical operations. _______________________________________ (Signature) _______________________________________ (Printed name) Multiple choice (3 pts. each) DARKEN THE CORRECT ANSWER ON THE ANSWER SHEET. Remember there are also 3 problems given after the 22 multiple-choice questions. Budget your time accordingly.

  1. Which one of the following bonds would be the least polar? a) N-F b) C - F c) Si-F d) O-F
  2. Which one of the following ionic compounds would have the highest melting point? a) K 2 O b) MgO c) CaCl 2 d) KCl e) NaBr
  3. Based on formal charges, identify the most favorable resonance form of the cyanate ion. a) N (^) C O b) N C^ O c) N C O d) All are equivalent
  4. The Lewis electron-dot structure of ClF 3 gives the central Cl a) 3 nonbonding pairs and 2 bonding pairs b) 5 bonding pairs only c) 2 nonbonding pairs and 4 bonding pairs d) an octet e) 2 nonbonding pairs and 3 bonding pairs
  5. For the nitrite ion (NO 2 - ), a) both bonds are single bonds b) both bonds are double bonds c) both bonds are the same, each being stronger than a single bond but longer and weaker than a double bond d) one bond is a single bond and the other is a double bond
  6. For resonance forms of a molecule or ion a) one always corresponds to the actual observed structure b) all always correspond to the actual observed structure c) the same atoms need not be bonded to each other in all resonance forms d) the actual observed structure is an average of the resonance forms e) all always correspond to the actual observed structure and the same atoms need not be bonded to each other in all resonance forms
  1. The bond angles in SF 4 are a) all 109.5 b) all 120 c) all 90 d) 90 & 180 e) 90, 120, & 180
  2. The respective hybridizations of tellurium in TeCl 2 and xenon in XeF 4 are a) sp^3 and sp^3 d b) sp^2 and sp^3 d^2 c) sp^3 and sp^3 d^2 d) sp^2 and sp^3 d e) sp and sp^3

9. Which of the following statements is untrue concerning the carbon-oxygen bond in H 2 C=O?

a) The bond limits free rotation about the axis between carbon and oxygen. b) The bond is formed by the overlap of one sp^2 hybrid orbital and one unhybridized p orbital from carbon and one sp hybrid orbital and two unhybridized p orbitals from oxygen. c) The bond causes the carbon, oxygen and hydrogens to exist in a plane. d) The bond is formed by the overlap of one sp^2 hybrid orbital and one unhybridized p orbital from each atom.

  1. How many  bonds are in the molecule shown? a) 14 b) 13 c) 11 d) 3
  2. Adding an electron to N 2 changes the bond order from a) 3/2 to 2 b) 3 to 2 c) 3 to 5/2 d) 3 to 3/ e) 2 to 1

C C O H

H

H

C

H

N

O

H

C

..^.

a) Patm = Pgas + Ph b) Pgas = Patm + Ph c) Pgas = Patm d) Pgas + Patm = Ph

  1. What is the predominant intermolecular force in CHBr 3? a) London-dispersion forces b) ion-dipole attraction c) hydrogen-bonding d) ionic bonding e) dipole-dipole attraction
  2. Which of the following substances would have the highest boiling point? CH 3 C

O

a) (^) CH 3 CH 3 C H

O

b) CH 3 C O H

H

H

c) CH 3 N^ CH 3 CH 3 d)

  1. Which of the compounds given below has the lowest London dispersion forces? a) C 4 H 9 OH b) C 3 H 7 OH c) C 2 H 5 OH d) CH 3 OH
  2. Which one of the following properties of a liquid is not affected by an increase in intermolecular forces? a) molecular weight b) surface tension c) viscosity d) boiling point YOU MUST SHOW ALL WORK ON THE ANSWER SHEET FOR THE FOLLOWING PROBLEMS
  3. (7 pts.) Explain how hydrogen bonding occurs and give a specific example. Sketches are preferred.
  1. (15 pts) Using molecular orbital theory, predict which of the following molecules is expected to be a stable species: N (^) 22 ^ , O 22 (^) ^ , F 22 ^ .To receive full credit: give proof with the MO diagram (show only the molecular orbitals labeled completely) and calculate the bond order. Give the designation of either diamagnetic or paramagnetic for each species.
  2. (14 pts.) Assume complete consumption of NOCl in the following reaction. 2NOCl (g)  2NO(g) + Cl 2 (g) Determine the partial pressures of Cl 2 and NO (in atm) that can be produced by the reaction of 58.9g of NOCl(g) at 80C given that the Cl 2 (g) and NO(g) are collected in a separate 25 L vessel over water. If the total pressure within the vessel is 2.03 atm, what is the vapor pressure of water at 80C? (R = 0.0821 (^) KL ^ ^ mole^ atm )

Both N 2 2-^ and O 2 2-^ are stable with bond orders of 2 and 1, respectively. F 2 2-^ does not exist with a bond order of 0. Bond order Bond enthalpy (kJ/mol) Bond length (Å) Magnetic behavior

N 2 2-^ O 2 2-^ F 2 2-

  1. PNO = 1.0429 atm, PCl2 = 0.5214 atm, PH2O = 0.466 atm

  ^ 

2 2 2 L-atm K-mole NO Cl 1 mole NOCl 2 mole NO 58 9g NOCl 0 899 mole NO 65.5g 2 mole NOCl 1 mole NOCl 1 mole Cl 58.9g NOCl 0 450 mole Cl 65.5g 2 mole NOCl 0 899 mole 0.0821 353 15 K P 1 0429 atm 25 L 0 450 mole 0. P

  ^ 

2 2 2 L-atm K-mole H O T NO Cl H O

1 353 15 K

0 5214 atm 25 L P P P P P 2 03 atm 1.0429 atm 0.5214 atm 0 466atm