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Atoms are made up of even smaller particles called subatomic particles. These subatomic particles are: electrons, protons, and neutrons.
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Atomic Structure
Subatomic Particles Atoms are made up of even smaller particles called subatomic particles. These subatomic particles are: electrons, protons, and neutrons. [There are other subatomic particles, but from a chemical perspective, they are rather unimportant.]
Symbol, charge, and approximate mass of subatomic particles Particle Symbol Electrical Charge Approximate Mass Proton P+^ +1 1 amu Neutron N 0 1 amu Electron e-^ -1 0 amu amu=atomic mass unit 1 amu=1.66 x 10-24g
Arrangement of subatomic particles
The nucleus contains the protons and neutrons. The nucleus is very small in comparison to the size of the atom, yet it is very heavy. Most of the mass of the atom is found inside the nucleus. If the nucleus was the size of a marble, the atom would be about the size of a football field. The electrons are found outside the nucleus in certain energy levels.
Atomic Number (Z) and Mass Number (M)
The atomic number is what determines the atom’s identity. Atomic number = number of protons in an atom For atoms that are electrically neutral, the number of protons = the number of electrons For ions, the number of protons ≠ the number of electrons Cations have less electrons than an electrically neutral atom Anions have more electrons than an electrically neutral atom Mass number = number of protons + number of neutrons So, number of neutrons = mass number – number of protons
Isotopes Isotopes are atoms of the same element that have the same number of protons but different number of neutrons. Because isotopes of an element have different numbers of neutrons, they also have different mass numbers. To distinguish between isotopes of the same element, we write an isotope symbol to indicate the mass number and the atomic number of the atom. Example, the isotope symbol for one isotope of argon is:
Examples:
Atomic Mass Scale The atomic mass scale is based on the mass of the carbon-12 isotope. All masses are determined relative to the mass of carbon-12, which by definition is exactly 12 amu.
The atomic mass of an element is the weighted average mass of the atoms in a naturally occurring sample of the element. A weighted average mass reflects both the mass and the relative abundance of the isotopes as they occur in nature.