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The concept of exceptions to the octet rule in chemistry, focusing on elements be and b, and the third period and lower elements. It also introduces resonance structures and their importance in displaying the true arrangement of electrons. Examples of lewis structures for pcl5 and so4-2, and explains how to calculate formal charges for atoms.
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C, N, O, F always follow the octet rule.
Be and B usually have fewer that 8 electrons.
Third period and lower elements can exceed the octet rule.
Try to satisfy the octet rule then, place any extra electrons on an element in the third period
or lower.
Draw the Lewis structure for NO3-
Resonance occurs when more than one equivalent Lewis structure can be drawn.
Resonance is needed because the localized electron model can not accurately display the true
arrangement of the electrons.
The true structure is a combination of all the resonance forms. It is not one of the structures
but all of them superimposed.
1
Ex: PCl
P- 5e-
Cl- 7e- x5= 35e-
Total- 40e-
Use 10 e- to form bonds, leaving 30 e-
When there are more than one Lewis structure that are not equivalent we use minimal formal
charge to decide which is the most correct structure. Formal charge is determined for each
atom in a molecule by:
Taking the normal number of valence electrons the atom has then subtract the sum of lone
pair electrons and half the bonding electrons. The result is the formal charge on the atom.
2
Sulfur has 4 e- and
would normally have 6
e-. +2 formal charge Each oxygen has 7
e-. formal charge -
Ex: SO 4
Here the sulfur has
a formal charge of 0
Oxygen with a double bond has
a formal charge of 0, the single
bonded oxygens still have -