Docsity
Docsity

Prepare for your exams
Prepare for your exams

Study with the several resources on Docsity


Earn points to download
Earn points to download

Earn points by helping other students or get them with a premium plan


Guidelines and tips
Guidelines and tips

Exceptions to the Octet Rule and Resonance Structures in Chemistry, Slides of Chemistry

The concept of exceptions to the octet rule in chemistry, focusing on elements be and b, and the third period and lower elements. It also introduces resonance structures and their importance in displaying the true arrangement of electrons. Examples of lewis structures for pcl5 and so4-2, and explains how to calculate formal charges for atoms.

What you will learn

  • What elements commonly violate the octet rule?
  • How do you calculate formal charges for atoms in a molecule?
  • What is resonance and why is it important in chemistry?

Typology: Slides

2021/2022

Uploaded on 09/12/2022

explain
explain 🇺🇸

4

(2)

230 documents

1 / 2

Toggle sidebar

This page cannot be seen from the preview

Don't miss anything!

bg1
Exceptions to the Octet Rule
C, N, O, F always follow the octet rule.
Be and B usually have fewer that 8 electrons.
Third period and lower elements can exceed the octet rule.
Try to satisfy the octet rule then, place any extra electrons on an element in the third period
or lower.
!! !
P
Cl
ClCl
Cl Cl
Resonance Structures
Draw the Lewis structure for NO3-
Resonance occurs when more than one equivalent Lewis structure can be drawn.
Resonance is needed because the localized electron model can not accurately display the true
arrangement of the electrons.
The true structure is a combination of all the resonance forms. It is not one of the structures
but all of them superimposed.
1
Ex: PCl5 P- 5e-
Cl- 7e- x5= 35e-
Total- 40e-
Use 10 e- to form bonds, leaving 30 e-
pf2

Partial preview of the text

Download Exceptions to the Octet Rule and Resonance Structures in Chemistry and more Slides Chemistry in PDF only on Docsity!

Exceptions to the Octet Rule

C, N, O, F always follow the octet rule.

Be and B usually have fewer that 8 electrons.

Third period and lower elements can exceed the octet rule.

Try to satisfy the octet rule then, place any extra electrons on an element in the third period

or lower.

P

Cl

Cl Cl

Cl Cl

Resonance Structures

Draw the Lewis structure for NO3-

Resonance occurs when more than one equivalent Lewis structure can be drawn.

Resonance is needed because the localized electron model can not accurately display the true

arrangement of the electrons.

The true structure is a combination of all the resonance forms. It is not one of the structures

but all of them superimposed.

1

Ex: PCl

P- 5e-

Cl- 7e- x5= 35e-

Total- 40e-

Use 10 e- to form bonds, leaving 30 e-

Formal Charge

When there are more than one Lewis structure that are not equivalent we use minimal formal

charge to decide which is the most correct structure. Formal charge is determined for each

atom in a molecule by:

Taking the normal number of valence electrons the atom has then subtract the sum of lone

pair electrons and half the bonding electrons. The result is the formal charge on the atom.

2

Sulfur has 4 e- and

would normally have 6

e-. +2 formal charge Each oxygen has 7

e-. formal charge -

Ex: SO 4

Here the sulfur has

a formal charge of 0

Oxygen with a double bond has

a formal charge of 0, the single

bonded oxygens still have -