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Definitions, examples and properties comparing acid, bases and alkalis
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Definitions Acids Acids are compounds which ionise/dissociate in water to produce hydrogen ions (H ). Bases Bases are compounds that are metal oxides or hydroxides that react with an acid to give a salt and water only. Alkalis Alkalis are bases that ionise/dissociate in water to produce hydroxide ions (OH ). Examples of Acids & Bases Acid Chemical Formula Base Chemical Formula Hydrochl oric Acid HCl Magnesium Oxide MgO Sulfuric Acid H2SO4 Copper (II) Oxide CuO Nitric Acid HNO3 Sodium Hydroxide NaOH Citric Acid C6H8O7 Potassium Hydroxide
Ethanoic Acid CH3CO2H Calcium Hydroxide Ca(OH) Lactic Acid C3H6O3 Aqueous Ammonia
Acids 1 to 3 are known as mineral / inorganic acids while Acids 4 to 6 are known as organic acids. Bases 1 & 2 are insoluble bases while Bases 3 to 6 are soluble bases / alkalis. Metal Reactivity Series Types of Reactions Metal + Acid Salt + Hydrogen Gas Metal Carbonate + Acid Salt + Water + Carbon Dioxide Metal Oxide + Acid Salt + Water Metal Hydroxide + Acid Salt + Water Base + Acid Salt + Water (Neutralisation) Alkali + Acid Salt + Water (Neutralisation) Alkali + Ammonium Salt Salt + Water + Ammonia Gas Alkali + Salt Metal Hydroxide + Salt Tests for Gases: Hydrogen Gas - Extinguishes a lighted splinter with a 'pop' sound. Carbon Dioxide Gas - Released as effervescence. Reacts with limewater to form a white precipitate. Ammonia Gas - Pungent odour. Turns red litmus paper blue. Notes: Base / Alkali + Acid is an exothermic reaction. Pb (s) + H2SO4 / HCl PbSO4 / PbCl2 + H Lead reacts slowly then stops. Salt forms on the surface of the lead. The salt formed is insoluble. pH Scale Acidic solutions have pH values < 7. They contain more H ions and fewer OH ions. Neutral solutions have pH values = 7. They contain equal amounts of H ions and OH ions. Alkaline solutions have pH values > 7. They contain more OH ions and fewer H ions. Ionic Equations
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Balancing Chemical Equations Step 1: Write down the chemical equation. Step 2: List down the atoms (or polyatomic ions) involved in both sides. Step 3: Count the number of atoms on both sides. Step 4: Compare both sides and change the coefficients (not subscripts) so that the atoms on the left side are equal to the atoms on the right side. (Tip: Balance the Metals first, then the Non-Metals , and then the Oxygen atoms and Hydrogen atoms.) Step 5: Double check both sides to make sure the atoms on both sides are equal. Soluble Salts Soluble Insoluble All nitrates None Most sulfates Lead sulfate, barium sulfate and calcium sulfate Most chlorides, bromides and iodides Silver chloride, silver bromide, silver iodide, lead chloride, lead bromide, lead iodide Sodium carbonate, potassium carbonate, ammonium carbonate Most other carbonates Sodium hydroxide, potassium hydroxide, ammonium hydroxide Most other hydroxides Uses of Acids Citric Acid Used as a sour flavouring agent in food Hydrochloric Acid Used as a rust remover Sulfuric Acid Used in car batteries Nitric Acid Used in fertilisers Uses of Acids (cont) Ethanoic Acid Used as a food preservative Carbonic Acid Used in making soft drinks Uses of Alkalis Sodium Hydroxide Used in making soap Calcium Hydroxide Used in making toothpaste and to reduce acidity in soil Aqueous Ammonia Used in making fertilisers and as a bleaching agent Aqueous Ammonia Used in making fertilisers and as a bleaching agent Potassium Hydroxide Used in electroplating and in making cement and plaster Magnesium Hydroxide Used as a detergent Strength of Acids Strong Acids Weak Acids Hydrochloric Acid Citric Acid Sulfuric Acid Tartaric Acid Nitric Acid Ethanoic Acid Strong Acids: React very fast & vigorously Ionise completely to produce large amounts of H ions Weak Acids: React slowly & less vigorously Ionise partially to produce small amounts of H ions Do not confuse the strength of an acid with the concentration of an acid. The strength tells you how many H ions are produced while the concentration tells you how much of an acid is dissolved in water. Strength of Alkalis Strong Alkalis Weak Alkalis Sodium Hydroxide Aqueous Ammonia Potassium Hydroxide Calcium Hydroxide Strong Alkalis ionise completely to produce large amounts of OH ions. Weak Alkalis ionise partially to produce small amounts of OH ions. How to Carry Out Titration
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