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Colligative Properties: Understanding the Impact of Solutes on Freezing and Boiling Points, Study notes of Chemistry

The concept of colligative properties, focusing on how the presence of solutes affects the freezing and boiling points of solutions. Topics include particle arrangement during freezing and boiling, the effect of salt on the freezing and boiling points, and the relationship between concentration, dissociation, and colligative properties. The document also covers the van hoff factor and provides formulas for calculating freezing point depression and boiling point elevation.

What you will learn

  • How does the presence of a solute affect the freezing point of a solution?
  • How does the van Hoff factor relate to the number of particles a solute dissociates into in solution?
  • Why does the boiling point of a solution increase when a solute is added?

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ColligativeProperties2018.notebook
1
April09,2018
Mar114:12PM
Colligative Properties
Aim: To observe and explain the affect that a solute has on
colligative properties (freezing and boiling points)
Mar114:18PM
DO NOW
Why do you put salt in water when cooking pasta?
Why do you put rock salt down on the roads when its icy?
Mar114:18PM
DEMO‐ Boiling Point of Water
Mar114:18PM
COLLIGATIVE PROPERTIES AND
FREEZING POINT
Intermsofparticlearrangement,explainwhatoccurswhenasubstancesfreezes .
Howisthepresenceofsaltmoleculesaffectingthefreezingprocessofwater?
Whatwillthisdototheamountofenergythatmustbelosttofreezethewater?
Howwillthesaltaffectthefreezingpointofwater?
Theparticlesmoveclosertogetherastheyfreeze.
Thesaltmoleculesareblockingthewatermoleculesfromfreezingtogether.
Thisincreasestheamountofpotentialenergythatmustbelosttofreeze.
Thefreezingpointdecreases.
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Mar 114:12 PM

Colligative Properties

Aim: To observe and explain the affect that a solute has on colligative properties (freezing and boiling points) Mar 114:18 PM

DO NOW

  • Why do you put salt in water when cooking pasta?
  • Why^ do^ you^ put^ rock^ salt^ down^ on^ the^ roads^ when^ its^ icy? Mar 114:18 PM

DEMO‐ Boiling Point of Water

Mar 114:18 PM

COLLIGATIVE PROPERTIES AND

FREEZING POINT

  • In terms of particle arrangement, explain what occurs when a substances freezes.
  • How^ is^ the^ presence^ of^ salt^ molecules^ affecting^ the^ freezing^ process^ of^ water?
  • What will this do to the amount of energy that must be lost to freeze the water?
  • How will the salt affect the freezing point of water?
    • The particles move closer together as they freeze.
  • The salt molecules are blocking the water molecules from freezing together.
  • This^ increases^ the^ amount^ of^ potential^ energy^ that^ must^ be^ lost^ to^ freeze.
  • The freezing point decreases.

Mar 114:18 PM

COLLIGATIVE PROPERTIES AND

BOILING POINT

  • In terms of particle arrangement, explain what occurs when a substance boils.
  • How are the presence of salt molecules affecting the boiling process of water?
  • What will this do to the amount of energy that is required to boil the water?
  • What will the requirement for more energy do to the boiling point?
    • The^ particles^ move^ farther^ apart^ as^ they^ vaporize.
  • The salt molecules are blocking the water molecules from boiling and escaping
  • This^ increases^ the^ amount^ of^ potential^ energy^ that^ must^ be^ absorbed^ to^ boil
  • The boiling point increases. Mar 114:18 PM

Concentration, Dissocation and

Colligative Properties

  • According to the diagrams above, which compound dissociates into ions?
  • Complete the dissolving equations for the compounds below. If dissociation occurs, write the individual ions and their charges. C 6 H 12 O 6 (aq) ‡ NaCl (aq) ‡ - Sodium chloride C 6 H 12 O 6 (aq) Na+^ (aq) + Cl‐^ (aq) NO DISSOCIATION; Covalent bonds Mar 114:18 PM

Concentration, Dissocation and

Colligative Properties

Which of these compounds would cause a greater change in the boiling point or freezing point of a substance, 1 M NaCl or 1 M C 6 H 12 O 6? Explain your answer in terms of particle quantities and concentrations. (Hint: Think about dissociation) The 1 M NaCl solution because it dissociates into ions and yields more particles in solution to cause more interference with the water boiling or freezing. Feb 2210:18 AM

What affects colligative properties?

The addition of any solute to a solution will increase the boiling point and decrease the freezing point. This is because the solute particles block the water molecules from escaping as a gas when boiling and from moving together to form a solid when freezing. As a result additional energy is required to boil (higher BP) and additional energy must be lost to freeze (lower FP).

Feb 2312:34 PM

Freezing Point Depression

  1. What is the freezing point depression of an aqueous solution of 10.0 g of sodium chloride (NaCl) in 50.0 g H 2 O? ∆T =? i = 2 (Na+^ + Cl‐ ) m = molality=3.42 m Kf=1.86°C/ m ∆T = i m Kf m = moles of solute = 0.171 mol kg of solvent 0.05 kg 10.0 g x 1 mol = 0.171 mol 58.5 g NaCl

∆T = (2)(3.42)(1.86)= 12.72°C

The solutions freezing point is lowered to ‐12.72 °C. Feb 2312:34 PM

Boiling Point Elevation

  1. What is the boiling point of a 1.50 m aqueous NaCl solution? ∆T =? i = 2 (Na+^ + Cl‐ ) m = molality=1.50 m Kf=0.51°C/ m ∆T = i m Kb ∆T = (2)(1.50)(0.51)= 1.53°C The solutions boiling point is elevated 101.53 °C. Feb 237:27 PM
  2. What is the boiling point of a solution that contains 1.25 mol CaCl 2 in 1400 g of water?

Boiling Point Elevation

∆T =?

i = 3 (Ca+2^ + 2 Cl‐ ) m = molality= 0.89 m Kf=0.51°C/ m ∆T = i m Kb ∆T = (3)(0.89)(0.51)= 1.36°C The solutions boiling point is elevated 101.36 °C. m = moles of solute = 1.25 mol kg of solvent 1.4 kg