Docsity
Docsity

Prepare for your exams
Prepare for your exams

Study with the several resources on Docsity


Earn points to download
Earn points to download

Earn points by helping other students or get them with a premium plan


Guidelines and tips
Guidelines and tips

Understanding Conjugate Acids and Bases: Strong, Weak, and Indicators, Study Guides, Projects, Research of Chemistry

The concepts of conjugate acids and bases through different definitions, examples, and their role in determining acid and base strength. Learn about strong and weak acids and bases, and the significance of indicators in pH measurements.

What you will learn

  • What is the difference between Arrhenius and Brønsted-Lowry definitions of acids and bases?
  • What are some common examples of weak acids and bases?
  • How do conjugate acids and bases determine the strength of an acid or base?

Typology: Study Guides, Projects, Research

2021/2022

Uploaded on 09/12/2022

shailen_555cell
shailen_555cell 🇺🇸

4.7

(19)

264 documents

1 / 8

Toggle sidebar

This page cannot be seen from the preview

Don't miss anything!

bg1
1
Conjugate acids and
bases
Different definitions of
acids and bases
Arrhenius definition
acids generate H
3
O
+
in water
bases generate OH
-
in water
Brønsted Lowry definition
Acids are proton donors
Bases are proton acceptors
which is an acid/base?
HF + H
2
O H
3
O
+
+ F
-
CH
3
NH
2
+ H
2
O CH
3
NH
3+
+ OH
-
By Arrhenius, HF is an acid, is a CH
3
NH
2
base.
Follow the proton
HF + H
2
O H
3
O
+
+ F
-
CH
3
NH
2
+ H
2
O CH
3
NH
3 +
+OH
-
What about the reverse reaction?
H
+
H
+
H
+
H
+
pf3
pf4
pf5
pf8

Partial preview of the text

Download Understanding Conjugate Acids and Bases: Strong, Weak, and Indicators and more Study Guides, Projects, Research Chemistry in PDF only on Docsity!

Conjugate acids and

bases

Different definitions of

acids and bases

  • Arrhenius definition
  • acids generate H 3 O+^ in water
  • bases generate OH-^ in water
  • Brønsted Lowry definition
  • Acids are proton donors
  • Bases are proton acceptors
  • which is an acid/base?
  • HF + H 2 O  H 3 O+^ + F-
  • CH 3 NH 2 + H 2 O  CH 3 NH 3 +^ + OH-
  • By Arrhenius, HF is an acid, is a CH 3 NH 2 base.

Follow the proton

  • HF + H 2 O  H 3 O+^ + F-
  • CH 3 NH 2 + H 2 O  CH 3 NH 3 ++OH-
  • What about the reverse reaction?

H+

H+

H+

H+

Conjugate acids and

bases

  • When you run the reverse reaction you find the products are also acids and bases. The acids and bases that are formed are called conjugate acids or bases
  • H 2 O + HF  H 3 O+^ + F-
  • base acid conjugate acid conjugate base
  • CH 3 NH 2 + H 2 O  CH 3 NH 3 +^ +OH-
  • base acid CA CB

Label Acid, Base, Conjugate

Acid, Conjugate Base

  • HClO 3 + H 2 O  ClO 3 -^ +H 3 O+
  • ClO-^ + H 2 O  HClO + OH-
  • HSO 4 -^ + H 2 O  SO 4 2-^ +H 3 O+
  • NH 3 + H 2 O  NH 4 +^ + OH-

Label Acid, Base, Conjugate

Acid, Conjugate Base

  • HClO 3 + H 2 O  ClO 3 -^ +H 3 O+
  • A B CB CA
  • ClO-^ + H 2 O  HClO + OH-
  • B A CA CB
  • HSO 4 -^ + H 2 O  SO 4 2-^ +H 3 O+
  • A B CB CA
  • NH 3 + H 2 O  NH 4 +^ + OH-
  • B A CA CB

Strong acids

Acid formula Acid Formula Hydrochloric acid HCl Sulfuric Acid H 2 SO 4 Hydrobromic acid HBr Nitric Acid HNO 3 Hydriodic acid HI Perchloric Acid HClO 4

Strong bases

  • All of group 1 and group 2 elements make strong bases.
  • However, most of them are not very soluble.
  • For example, Mg(OH) 2 is a saturated solution at 1.6 x10-4^ M

Commonly used Strong

Bases

Name Formula Name Formula Sodium Hydroxide NaOH Calcium Hydroxide Ca(OH) 2 Potassium Hydroxide KOH Strontium Hydroxide Sr(OH) 2 Barium Hydroxide Ba(OH) 2 these make a lightning bolt on the periodic table!

Weak acids and bases

  • can be forced the other way
  • So ammonia…
  • NH 3 + H 2 O NH 4 ++OH-
  • Ammonia is a gas with a distinct odor
  • Ammonium and hydroxide are both odorless.
  • If base is added to the solution you will smell ammonia, if hydroxide is removed you won’t smell anything.

Pet “Stain” Problem

  • Urine has ammonia in it.
  • Most cleansers are basic.
  • After cleaning, we still leaves small amounts behind.
  • If it is small amount of ammonia and a basic cleanser the equilibrium will be shifted to the ammonia side so some thing with a great sense of smell (dog) could pick it up.
  • A slightly acidic cleanser shifts the equilibrium to the ammonium side to solve this problem

Other weak acids and

bases

  • Weak Acids
    • Acetic Acid (vinegar)
    • Citric Acid
    • Ascorbic Acid (vitamin C)
    • Boric Acid
    • Carbonic Acid
  • Weak Bases
    • Sodium Bicarbonate
    • Ammonia
    • Sodium Hypochlorite (bleach)

Other pH indicators

  • Litmus and phenolphthalein are indicators
  • Red cabbage juice has a pigment that changes colors at different pH values

Buffers

  • Buffers are solutions that don’t change in pH when acids or bases are added.
  • They use weak acids/bases and Le Châtelier’s principle.
  • You will have a large amount of weak acid and conjugate base
  • WA = weak acid
  • HWA + H 2 O  H 3 O+^ + WA-

pH

  • pH depends on the concentration of hydronium
  • pH = -log [H 3 O+]
  • Concentration of hydronium is the ratio of solute to solvent or in this case H 3 O+^ / H 2 O

What it does

• HWA + H 2 O  H 3 O+^ + WA-

  • adding H 3 O+^ forces the equation to SHIFT the left
  • The new hydronium reacts with the excess of conjugate base.
  • Which makes more water and removes some H 3 O+, so the [H 3 O+] remains constant

What it does

• HWA + H 2 O  H 3 O+^ + WA-

  • removing H 3 O+^ or adding OH- forces the equation to SHIFT to the right
  • The new hydroxide will react with the excess weak acid.
  • Which make more H 3 O+, and removes some water
  • so the [H 3 O+] remains constant
  • There is a breaking point where the pH will begin to change.

What does this have to

do with my life?

  • Your blood is a buffered solution
  • The pH must remain between 7.35-7.
  • Outside of that range can kill you
  • below this range is called acidosis
  • above is called alkalosis