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These notes offers an in-depth exploration of cycloaddition reactions, a core type of pericyclic reaction vital to modern organic synthesis. Students will learn about the mechanisms, stereochemistry, and regioselectivity involved in common cycloaddition reactions, including the Diels-Alder reaction, [2+2] cycloadditions, and [3+2] cycloadditions. Key concepts such as concerted mechanisms, orbital symmetry, and transition states will be examined, with a strong emphasis on applying Woodward-Hoffmann rules to understand the role of thermal and photochemical activation.
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2023/2024
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