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MS University detailed course list for all students
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Table – 4 : Common Course Structure for M.Sc. ( Chemistry) Degree programme (with effect from the academic year 2017-2018 onwards) Sem. (1) Sub. No. (2) Subject Status (3) Subject Title (4) Contact Hrs/ week (5) Credits (6) I 1 Core - 1 Organic Chemistry – I 4 4 2 Core - 2 Inorganic Chemistry – I 5 4 3 Core - 3 Physical Chemistry – I 5 4 4 Elective - 1 Advanced Topics In Chemistry – I 4 4 5 Core - 4 Practical - 1 Organic Chemistry Practical – I 4 2 6 Core - 5 Practical - 2 Inorganic Chemistry Practical – I 4 2 7 Core - 6 Practical - 3 Physical Chemistry Practical – I 4 2 Sub total 30 22 II 8 Core - 7 Organic Chemistry – II 5 4 9 Core - 8 Inorganic Chemistry – II 4 4 10 Core - 9 Physical Chemistry – II 5 4 11 Elective - 2 Advanced Topics In Chemistry – II 4 4 12 Core - 10 Practical - 1 Organic Chemistry Practical – II 4 2 13 Core - 11 Practical - 2 Inorganic Chemistry Practical – II 4 2 14 Core - 12 Practical - 3 Physical Chemistry Practical – II 4 2 Sub total 30 22
Components Sub.Code Contact Hrs /Week Credits Internal Marks External Marks Total Marks Passing Minimum External Total Core – 1 Organic Chemistry - I PCHM11 4 4 25 75 100 38 50 Core – 2 Inorganic Chemistry - I PCHM12 5 4 25 75 100 38 50 Core – 3 Physical Chemistry - I PCHM13 5 4 25 75 100 38 50 Elective – 1 Advanced Topics in Chemistry – I PCHE11 4 4 25 75 100 38 50 FIRST SEMESTER PRACTICAL Components Sub.Code Contact Hrs / Week Credits Internal Marks External Marks Total Marks Passing Minimum External Total Core – 4 Organic Chemistry practical – I PCHL11 4 2 50 50 100 25 50 Core – 5 Inorganic Chemistry practical-I PCHL12 4 2 50 50 100 25 50 Core – 6 Physical Chemistry practical- I PCHL13 4 2 50 50 100 25 50
Components Sub.Code Contact Hrs / Week Credits Internal Marks External Marks Total Marks Passing Minimum External Total Core – 7 Organic Chemistry - II PCHM 5 4 25 75 100 38 50 Core – 8 Inorganic Chemistry – II PCHM22 (^4 4 25 75 100 38 ) Core – 9 Physical Chemistry - II PCHM 5 4 25 75 100 38 50 Elective – 2 Advanced Topics in Chemistry – II PCHE 4 4 25 75 100 38 50 SECOND SEMESTER PRACTICAL Components Sub. Code Contact Hrs / Week Credits Internal Marks External Marks Total Marks Passing Minimum External Total Core – 10 Organic Chemistry practical – II PCHL21 4 2 50 50 100 25 50 Core – 11 Inorganic Chemistry practical-II PCHL22 4 2 50 50 100 25 50 Core – 12 Physical Chemistry practical- II PCHL23 4 2 50 50 100 25 50
Components Sub.Code Cont. Hrs / Week Credits Internal Marks External Marks Total Marks Passing Minimum External Total Core – 20 Organic Chemistry - IV PCHM41 4 4 25 75 100 38 50 Core – 21 Inorganic Chemistry-IV PCHM42 4 4 25 75 100 38 50 Core – 22 Physical Chemistry-IV PCHM 4 4 25 75 100 38 50 FOURTH SEMESTER PRACTICAL Components Sub.Code Contact Hrs / Week Credits Internal Marks External Marks Total Marks Passing Minimum External Total Core – 23 Organic Chemistry practical – IV PCHL 4 2 50 50 100 25 50 Core – 24 Inorganic Chemistry practical-IV PCHL 4 2 50 50 100 25 50 Core – 25 Physical Chemistry practical- IV PCHL 4 2 50 50 100 25 50 Core- 26 Project & viva- voce PCHP 6+6* 6 0 100 100 50 50 ***** Extra hours for the project For the project, flexible credits are b/w 5- 8 & Hours per week are b/w 10-16. Total number of credits ≥ 90 : 90 Total number of Core Courses : 26 (13T+12P+1Project) Total number of Elective Courses : 02 Total number of Courses : 28 Total hours : 120
The evaluation for each course consists of two components that are internal and external. Theory External : Internal = 75: Practical External : Internal = 50: INTERNAL The internal component consists of following: THEORY Regarding the internal assessment, the maximum 25 marks is allocated in the following manner. Components Marks The average of the best two tests From three compulsory tests 15 Assignment 4 Seminar 6
Total 25
Note : Re internal assessment test for the student will not be allowed PRACTICAL The break-up for the internal component for the practicals will be as follows. Number of experiments = 30 Record = 10 Mid-term test and Model test average = 10
EXTERNAL
The external evaluation will be based on the examinations to be conducted by the university at the end of each semester.
2017 - 18/ MSU/ 46 th^ SCAA/ Affiliated coll. /PG/M.Sc.,(Chemistry)/Sem.-1/Core-1/ Objectives:
Stereospecific and stereoselective synthesis – Methods of Asymmetric synthesis including enzymatic and catalytic process – Cram’s rule and Prelog’s rule – Cram chelation model and Felkin – Ahn model. UNIT – IV: REARRANGEMENT REACTIONS Types of rearrangements: Nucleophilic, electrophilic and Free radical and protrophic reactions. Mechanism: Nature of migration – migrating aptitude and memory effects, ring enlargement and ring contraction rearrangements. Reactions: Carbon to carbon migration : Wagner – Meerwein, Pinacol – Pinacolone, Benzil – Benzilic acid, Arndt – Eistert synthesis, Demjanov and dienone-phenol rearrangements. Carbon to oxygen migration: Baeyer–Villiger, Hydro peroxide and Dakin rearrangements. Carbon to Nitrogen migration: Lossen, Neber and curtius rearrangements. Miscellaneous: Von – Richter rearrangement and Fischer - Indole synthesis. UNIT – V: REAGENTS IN ORGANIC SYNTHESIS Gilman’s reagent – LDA – DCC – 1,3 – dithane (umpolung synthesis ) – Selenium dioxide. Fetizon’s reagent – Lemieux – Von Rudloff reagent – Lemieux–Johnson reagent – Woodward and prevost hydroxylation. Merrifield resin – Vaskas catalyst – Wilkinson’s catalyst. REFERENCES
2017 - 18/ MSU/46th^ SCAA/ Affiliated coll./PG/M.Sc.(Chemistry)/Sem.-1/Core-2/ Objectives:
Unit – III: SOLID STATE CHEMISTRY Description of crystal structures : calcite, zinc blende, wurtzite, rutile, fluorite, antifluorite, CsCl, CdI 2 , K 2 NiF 4 – spinels and perovskite. Crystal defects in solids – line and plane defects
2017 - 18/ MSU/46th^ SCAA/ Affiliated coll./PG/M.Sc.(Chemistry)/Sem.-1/Core-3/ Objective : To learn the definitions of Partial molar properties and Phase rule. To understand the Principles of Thermodynamics of irreversible processes, Quantum mechanics and Statistical Thermodynamics UNIT-I Thermodynamics Concepts of Partial molar properties – Partial molar free energy, chemical potential, partial molar volume and its significance. Gibbs-Duhem equation, Gibbs-DuhemMargulus equation. Chemical Potential, Variation of Chemical Potential with temperature and Variation of Chemical Potential with pressure. Determination of partial molar volume: Graphical method, intercept method and Apparent molar volume method. Concept of Fugacity; Determination of Fugacity by graphical method and compressibility factor method, Fugacity of a liquid component in a liquid mixture, Physical significance of Fugacity. Activity and activity coefficient: Definition of activity and activity coefficient, determination of activity coefficient by EMF and solubility method. Thermodynamics of non ideal system-Excess thermodynamic function, GE, SE, HE etc. UNIT-II Phase Rule & Thermodynamics of irreversible processes : Lever rule, Derivation of Lever rule. Phase rule and compressed Phase rule, Derivation of phase rule from the concept of chemical potential. Application of Phase rule to three components system. Principle of triangular diagram: Plots for a mixture of three liquids consisting of one, two and three pairs of partially miscible liquids. Thermodynamics of irreversible processes with simple examples. Uncompensated heat and its physical significance. Entropy production- rate of entropy production, entropy production in chemical reactions. The principle of microscopic reversibility, the Onsager reciprocal relations- Validity and Verification. Thermal osmosis, Thermoelectric phenomena- Electro kinetic and thermo mechanical effects. Application of irreversible thermodynamics to biological and non-linear systems.
Quantum Chemistry Inadequacy of classical mechanics, Black body radiation, Planck’s quantum theory, Photoelectric effect. Bohr’s theory of hydrogen atom :Hydrogen spectra, wave particle duality – uncertainty principle. Operators- Linear, differential, Laplacian, Hermitian and Hamiltonian operators angular momentum operator. Eigen functions and Eigen values. commutation relations, related theorems, simultaneous measurement of several properties : evaluation of commutators such as [(x , Px) and (Lx, Ly)] and their significance. Commutation relations, related theorems. Time-dependent and time-independent Schrödinger wave equations – Postulates of quantum mechanics. UNIT-IV Statistical thermodynamics Concept of thermodynamics and mathematical probabilities – Micro and macro state - phase space – Maxwell – Boltzmann, Bose – Einstein statistics and Fermi – Dirac statistics – comparison and applications – modes of contribution to energy. Partition functions. Separation of partition functions. Translational, rotational, vibrational and electronic partition functions. Interpretation of partition function- relation between partition function and Thermodynamic properties: Internal energy, entropy, enthalpy, Helmholtz function, pressure, Gibbs function, residual entropy, equilibrium constant, average energies. Equipartition theorem. Statistical approach to Heat capacity of mono and diatomic gases. Heat capacity of solids- Einstein and Debye models. UNIT-V: MOLECULAR SPECTROSCOPY Introduction and Rotational Spectroscopy Electromagnetic radiation: quantization of energy; rotational, vibrational, and electronic energy levels and transitions in molecules; regions and representation of spectra. Resolution and intensity of spectral transition: signal-to-noise ratio; width of spectral lines- collision broadening, Doppler broadening, Heisenberg uncertainty principle; intensity of spectral lines-selection rules and transition probability, transition moment integral, Einstein absorption and emission coefficients, Boltzmann distribution. Enhancing sensitivity of spectral lines: Fourier Transform (FT) and computer averaging techniques (CAT). Diatomic molecules as rigid rotors: rotational energy levels, intensity of spectral lines, select ion rules, effect of isotopic substitution. Diatomic molecules as non-rigid rotors: rotational transitions, centrifugal distortion constant; rotational spectra of linear and symmetric top polyatomic molecules.
2017 - 18/ MSU/46th^ SCAA/ Affiliated coll./PG/M.Sc.(Chemistry)/Sem.-1/Core - 4/Cpr-1/ A. Separation of Organic mixture: (i) Separation of two component mixture and determination of their physical Constants. (ii) Separation and analysis of at least six two component mixture. The students are expected to determine the physical constants for both the components as well as their Derivatives. (iii) Analysis may be performed in micro (or) macro scale depending upon the Conditions of the laboratory B. For Class Work Only: (1) Separation of Caffeine from Tea / Coffee. (2) Separation of green, blue, red inks by TLC method REFERENCES:
th SCAA/ Affiliated coll./PG/M.Sc.(Chemistry)/Sem.-1/Core - 5/Cpr-2/ I. Qualitative analysis of inorganic mixtures containing two familiar and two less familiar cations: Pb, Cu, Bi, Cd, Sb, Zn, Co, Ni, Mn, Ca, Ba, Sr, W, Tl, Te, Se, Mo, Ce, Th, Zr, V, U, Ti and Li. REFERENCES
