Download Electric Dipoles: Properties and Interactions and more Study notes Chemistry in PDF only on Docsity!
EM 3 Section 5: Electric Dipoles
An electric dipole is formed by two point charges +q and −q connected by a vector a. The
electric dipole moment is defined as p = qa.
By convention the vector a points from the negative to the positive charge. Here we also take the origin to be at the centre and a to be aligned to the z axis (see diagram)
Figure 1: Diagram of electric dipole aligned along z axis. Griffiths Fig 3.
- Field of an electric dipole
We first calculate the potential and then the field:
V =
q 4 π 0
( 1 r+
r−
) (1)
where r± are the distances from the +ve(-ve) charge to the point r.
Now
r^2 ∓ = |r ± a/ 2 |^2 = (r^2 ± a · r + a^2 /4) = r^2
( 1 ± a r cos θ + a^2 4 r^2
)
Now consider the “far field limit” r a
r±
r
( 1 ∓ a r cos θ + a^2 4 r^2
)− 1 / 2
r
( 1 ± a 2 r
cos θ + O((a/r)^2 )
)
where O((a/r)^2 ) indicates terms proportional to (a/r)^2 or higher powers
Thus we obtain in the far-field limit
V = qa cos θ 4 π 0 r^2
p · ˆr 4 π 0 r^2
One can check that away from the charges this is a solution of Laplace’s equation (see tut)
The components of the electric field E= −∇V are simplest in spherical polar coordinates:
Er = −
∂V
∂r
2 p cos θ 4 π 0 r^3 Eθ = −
r
∂V
∂θ
p sin θ 4 π 0 r^3
To get a co-ordinate free form of the electric field we can use (see tutorial sheet 1)
E = −∇V = −
4 π 0
( p · ˆr r^2
)
4 π 0
( 3(p · r)r r^5
p r^3
) (4)
The important point to note is that a dipole field is 1 /r^3 , whereas a point charge field is 1 /r^2
N.B. The above ‘far-field’ limit r a can also be presented as an ideal dipole which is the limit a → 0, q → ∞ but p finite. The ideal dipole is a useful approximation to the ‘physical dipole’ for which the potential is given by (1) and
E = −∇V =
q 4 π 0
[ r − a/ 2 |r − a/ 2 |^3
r + a/ 2 |r + a/ 2 |^3
] (5)
However the sketches look a little different:
Figure 2: Sketch of electric dipole field: ideal and ‘physical’ Griffiths Fig 3.
Why dipoles matter I: Many molecules have a permanent dipole moment p (e.g. H 2 0) All others, and all atoms, acquire an induced dipole when placed in E field Since atoms and molecules are (a) neutral and (b) almost pointlike, the ideal dipole concept is crucial to understanding media see later.
- Interaction of dipole with external Electric Field
To calculate the force on a dipole in an external field Eext = −∇φ (note here we use φ for the electrostatic potential of the external field) it is simplest to first calculate the potential energy of the dipole in this field:
Udip = qφ(a/2) − qφ(−a/2) ' qa · ∇φ = −p · Eext
where we have made a Taylor expansion to first order in a.
We can tidy up the expansion to write it as
V (r) =
4 π 0
Q
r
4 π 0
ˆr · P r^2
4 π 0
r^3
∑ i,j
Qij ˆri ˆrj + · · · (9)
where Q =
∫ V dV ′ρ(r′)
P =
∫ V
dV ′r′ρ(r′)
Qij =
∫ V dV ′(3r i′r′ j − (r′)^2 δij )ρ(r′)
Thus Q is the total net charge ; P is the dipole moment and ˆrT^ Qˆr r^3
is the quadupole moment
with Q the quadrupole tensor (a basis dependent matrix). Each of the monopole, dipole, quadrupole fields have distinct and characteristic shapes.
The first term (‘monopole term’) would normally be the dominant term and this would quite reasonably represent the far-field charge distribution as that of a single lump of charge at the origin.
However, when the total charge Q vanishes (as in the case of a dipole) it is the next term (‘dipole term’) which is dominant. One can think of charge distributions where the second term term also vanishes (e.g. electric quadrupole where P = 0 see figure) then the dominant term becomes the third term (quadrupole term) and so on.
Figure 3: 4 charges forming an electric quadrupole Griffiths Fig 3.
Significantly, each term in the expansion (9) is separately a solution of Laplace’s equation (outside of the region V that contains the charges).
Thus one can use the idea of the method of images and use an image dipole
V =
4 π 0
(r ̂− r′) · P |r − r′|^2
at some point r′^ outside of the physical region to solve Poison’s equation inside the physical region, and fix certain boundary conditions on the boundary of the physical region.
An example is a conducting sphere in a uniform external field E 0. The boundary condition is that E is radial at the surface of the sphere which is an equipotential. This is achieved by using an image electric dipole at the centre of the sphere - see tutorial. The result is that on the surface of the sphere there is an induced charge distribution which is positive on one side and negative on the other.
