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Energy Changes in Chemical Reactions: Exothermic and Endothermic Reactions, Study notes of Chemical Kinetics

Information on energy changes during chemical reactions, focusing on exothermic and endothermic reactions. It includes examples of reactions, energy absorption and release, and diagrams. Students can use this document for understanding the concepts of energy changes in chemical reactions, preparing for exams, or as a study aid.

Typology: Study notes

2021/2022

Uploaded on 09/12/2022

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KEY
1
Energy Changes in Chemical Reactions
Name - _______________
1.) You can think of this reaction, CH
4
+ 2 O
2
CO
2
+ 2 H
2
O , as occurring in two steps (it doesn’t
go this way, but it is convenient to think of it this way).
Step 1 - CH
4
+ 2 O
2
C + 4 H + 4 O (the reactants are broken down to individual atoms)
Step 2 - C + 4 H + 4 O CO
2
+ 2 H
2
O (the individual atoms are assembled into products)
a.) Does step 1 absorb or give off energy? absorb
b.) Does step 2 absorb or give off energy? give off
c.) Since the overall reaction is exothermic, which step involves more energy, step 1 or 2?
Step 2
2.) The energy needed to break an H-Cl bond is 432. 2 HCl + 432 H
2
+ Cl
2
How many kilojoules of energy are given off in the following reaction? Why?
H
2
+ Cl
2
HCl + _432_ kJ
Answer – The two reactions are the exact opposite of each other.
3.) Is the burning of wood exothermic or endothermic?
Answer – exothermic as heat (energy) is produced.
4.) Is the melting of sugar exothermic or endothermic?
Answer – endothermic as heat (energy) is absorbed by the sugar to change phases.
5.) A beaker becomes warm when a reaction occurs in it. Are the chemicals in the beaker gaining or losing
energy? Is the reaction endothermic or exothermic?
Answer – losing energy. Exothermic as energy is released (lost).
6.) Which contains more energy in an endothermic reaction, the reactants or products?
Answer – products. The reactants gain energy to become high energy products.
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KEY

1

Energy Changes in Chemical Reactions

Name - _______________

1.) You can think of this reaction, CH 4 + 2 O 2  CO 2 + 2 H 2 O , as occurring in two steps (it doesn’t go this way, but it is convenient to think of it this way). Step 1 - CH 4 + 2 O 2  C + 4 H + 4 O (the reactants are broken down to individual atoms) Step 2 - C + 4 H + 4 O  CO 2 + 2 H 2 O (the individual atoms are assembled into products) a.) Does step 1 absorb or give off energy? absorb b.) Does step 2 absorb or give off energy? give off c.) Since the overall reaction is exothermic, which step involves more energy, step 1 or 2? Step 2

2.) The energy needed to break an H-Cl bond is 432 ᡣᠶ. 2 HCl + 432 ᡣᠶ  H 2 + Cl 2 How many kilojoules of energy are given off in the following reaction? Why? H 2 + Cl 2  HCl + _ 432 _ kJ Answer – The two reactions are the exact opposite of each other.

3.) Is the burning of wood exothermic or endothermic?

Answer – exothermic as heat (energy) is produced.

4.) Is the melting of sugar exothermic or endothermic?

Answer – endothermic as heat (energy) is absorbed by the sugar to change phases.

5.) A beaker becomes warm when a reaction occurs in it. Are the chemicals in the beaker gaining or losing energy? Is the reaction endothermic or exothermic? Answer – losing energy. Exothermic as energy is released (lost).

6.) Which contains more energy in an endothermic reaction, the reactants or products?

Answer – products. The reactants gain energy to become high energy products.

KEY

2

7.) In an exothermic reaction, do you have to add or remove energy in order to allow particles to form?

Answer – remove energy from reactants as lower erngy products are formed.

8a.) Is ∆ᠴ > 0 or ∆ᠴ < 0 for an endothermic reaction? Hreactants ‹ Hproducts and ∆H = Hp - Hr

b.) Is ∆ᠴ > 0 or ∆ᠴ < 0 for an exothermic reaction? ∆ᠴ < 0

9.) Draw an energy diagram having ∆ᠴ = +25 ᡣᠶ.

10.) Draw and energy diagram having ∆ᠴ = −50 ᡣᠶ.

11.) ∆ᠴ = −50 ᡣᠶ for the reaction F  G. Re-write this equation to show the 50 ᡣᠶ properly on the reactant or product side. Answer – F  G + 50 ᡣᠶ

12.) If a reaction absorbs 30 ᡣᠶ of heat, what is the ∆H for the reaction? ∆ᠴ = +30 ᡣᠶ

13.) If P  Q + 25 ᡣᠶ, what is the ∆H for the reaction? Which have more energy, the reactants or products? ∆ᠴ = −25 ᡣᠶ reactants have more energy.

Reaction Proceeds 

Products

Reactants

Energy

Reactants

Products

Energy

Reaction Proceeds