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Equilibrium Reactions in CHEM105 Lab: Le Chatelier's Principle and Beer's Law, Lab Reports of Chemistry

A prelab for week 1 of the chem105 lab focused on equilibrium. Students are required to define le chatelier's principle and beer's law, perform calculations related to reactant concentrations and molar ratios, and make predictions about the color intensity of solutions based on these concepts. The document also includes instructions for lab experiments and reading assignments.

Typology: Lab Reports

Pre 2010

Uploaded on 08/19/2009

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Prelab #9—Week 1—Equilibrium
CHEM105 lab p. 1/2
Name _______________
Lab section: M T W Th F
Reading Assignment:
Theory of experiment—see lab manual.
Equilibrium and Le Chatelier’s Principle—Zumdahl, Chapter 6.
Questions:
1) In the space available, define the following terms in your own words:
a. Le Chatelier's Principle ___________________________________________
_____________________________________________________________
b. Beer's Law (see Vitamin Pill lab) _____________________________________
_____________________________________________________________
2) Review the procedure for Part I where two reactants will be added as outlined in the
data table below.
a. Fill in the shaded cells in the table below. The concentrations that you will fill in
refer to the concentration immediately after the reactants are mixed but before
any reaction occurs to bring the system to equilibrium. Using the stock solution
concentrations and the amounts of each reactant, calculate the initial
concentration of the reactants. Then calculate the molar ratio.
Solution
Stock solution:
0.2M Fe3+
in 0.5 HNO3
Stock solution:
0.002M SCN-
in 0.5 HNO3
Fe3+
Vol.
(mL)
Fe3+
Conc.*
(M)
SCN-
Conc.*
(M)
Water
Vol.
(mL)
TOTAL
Vol.
(mL)
Molar
Ratio of
Fe3+ to
SCN-
1
1.00
44
50.00
* This is the concentration immediately after the reactants are mixed but before any reaction occurs to bring the system to
equilibrium
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Prelab #9—Week 1—Equilibrium

CHEM105 lab p. 1 / 2

Name _______________

Lab section: M T W Th F

Reading Assignment:

• Theory of experiment—see lab manual.

• Equilibrium and Le Chatelier’s Principle—Zumdahl, Chapter 6.

Questions:

1) In the space available, define the following terms in your own words :

a. Le Chatelier's Principle ___________________________________________

_____________________________________________________________

b. Beer's Law (see Vitamin Pill lab) _____________________________________

_____________________________________________________________

2) Review the procedure for Part I where two reactants will be added as outlined in the

data table below.

a. Fill in the shaded cells in the table below. The concentrations that you will fill in

refer to the concentration immediately after the reactants are mixed but before

any reaction occurs to bring the system to equilibrium. Using the stock solution

concentrations and the amounts of each reactant, calculate the initial

concentration of the reactants. Then calculate the molar ratio.

Solution Stock solution: 0.2M Fe3+ in 0.5 HNO 3 Stock solution: 0.002M SCN- in 0.5 HNO 3 Fe3+ Vol. (mL) Fe3+ Conc. (M)*

SCN-

Vol. (mL)

SCN-

Conc. (M) Water Vol. (mL)*

TOTAL

Vol. (mL ) Molar Ratio of Fe3+^ to SCN- 1 1.00 5.00 44 50.

  • This is the concentration immediately after the reactants are mixed but before any reaction occurs to bring the system to equilibrium

Prelab #9—Week 1—Equilibrium

CHEM105 lab p. 2 / 2

b. Fill in the shaded portions of the table below. For the second solution you will be

making, you will take 5.0 mL of solution 1, which will be at equilibrium, and perturb

the equilibrium by adding additional Fe+3. How much iron (III) nitrate [Fe(NO 3 ) 3 ]

will you need to add in order to make 5.0mL of a solution that has an initial Fe

concentration of 0.18M? (Hints: You will need to calculate the molar mass of iron

(III) nitrate. Assume that the initial Fe

concentration from solution 1 is

insignificant and does not contribute to the 0.18M. First calculate the grams of

iron (III) nitrate then fill in the other cells.)

Solution Solution composition Fe3+ Conc. (M)*

SCN-

Conc. (M)*

TOTAL

Vol. (mL ) Molar Ratio of Fe3+^ to SCN- 2 5.0 mL of solution 1

  • _______ g iron (III) nitrate [Fe(NO 3 ) 3 ] crystals 0.18M = (initial Fe+ from solution 1) + (added Fe+3)
  • This is the concentration immediately after the reactants are mixed but before any reaction occurs to bring the system to equilibrium

c. Now make a hypothesis about the relative color intensity you expect for solutions

1 and 2 once they have a chance to come to equilibrium. Explain your prediction

using Le Chatelier's Principle and Beer's Law.