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Material Type: Exam; Professor: Castellani; Class: Principles of Chemistry I; Subject: Chemistry; University: Marshall ; Term: Fall 2007;
Typology: Exams
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Chemistry 211 Key 3 Fall 2007
a) CO 2 b) HF c) NH 4 Cl d) O 2 e) SCl 2
a) 0.0143 M b) 0.0314 M c) 0.105 M d) 0.119 M e) 0.197 M
a) All types of radiant energy travel at 3.00 x 10^8 m/s. b) Energy is inversely proportional to frequency. c) The probability of finding an electron at a certain place is its electron density. d) Each electron has four quantum numbers associated with it. e) A collection of orbitals with the same principle (n) quantum number is called a shell.
a) infrared light c) radiowaves e) ultraviolet light b) microwaves d) visible light
a) 1.61 x 10-^16 m c) 4.82 x 10-^8 m e) 6.22 x 10^15 m b) 1.24 x 10-^9 m d) 2.07 x 10^7 m
a) Al b) As c) Cl d) S e) Sn
a) N 2 O b) P 2 O 5 c) SO 2 d) XeO 3 e) Y 2 O 3
a) Alkali metals are strong oxidizing agents. b) Alkaline earth metals react with oxygen to form compounds with the general formula MO. c) Non-metals tend to form anions in reactions. d) The halogens are very reactive. e) The noble gases are generally unreactive.
Discussion Questions: (You must show your work to receive credit.)
4 B(s) + 3 O 2 (g) → 2 B 2 O 3 (s) ∆Hº = -2509.1 kJ 2 H 2 (g) + O 2 (g) → 2 H 2 O (^) (l) ∆Hº = -571.7 kJ B 2 H 6 (g) + 3 O 2 (g) → B 2 O 3 (s) + 3 H 2 O(l) ∆Hº = -2147.5 kJ a) Calculate the heat of formation of one mole of B 2 H 6 (g). b) Is the reaction endothermic or exothermic? c) How much heat is produced or is required in the preparation of 5.00 g of B 2 H 6?
a) 4 B(s) + 3 O 2 (g) → 2 B 2 O 3 (s) ∆Hº = [-2509.1 kJ] x 0. 2 H 2 (g) + O 2 (g) → 2 H 2 O (^) (l) ∆Hº = [-571.7 kJ] x 1. B 2 O 3 (s) + 3 H 2 O(l) → B 2 H 6 (g) + 3 O 2 (g) ∆Hº = [-2147.5 kJ] x - 2 B(s) + 3 H2 (g) → B 2 H 6 (g) ∆Hº = 35.2 kJ [Problem 5.76 a] b) endothermic
c) ∆H = (5.00 gB2H6) (^)
B2H6 B2H
B2H 1 mol
352 kJ 2767 g
1 mol. .
quantum – the discreet amounts of energy emitted or absorbed by an atom ground state – the lowest energy state electron affinity – the energy change that occurs when an electron is added to a gas phase atom or ion amphoteric – species that can act as either (or both) an acid or base
2 i
2 f n
n
Energy is emitted because the electron moves from a more distant orbital from the nucleus to a closer one. Since the electron and nucleus possess opposite charges, the shorter distance results in a greater attraction and a concomitant energy release.