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Exam 4 Multiple Choice Questions - General Chemistry | CHEM 142, Exams of Chemistry

Material Type: Exam; Professor: Watts; Class: GENERAL CHEMISTRY; Subject: Chemistry; University: Jackson State University; Term: Spring 2008;

Typology: Exams

Pre 2010

Uploaded on 08/08/2009

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NAME _______________________ CHEM 142
April 23, 2008 Exam 4
Please write your name at the top of each page of this examination in the space provided. I
will deduct 5 points from your score if you do not do so!
Section A. MULTIPLE CHOICE QUESTIONS: (5 pts each)
Choose the best answer. Clearly circle your answer. No credit will be given if more than
answer is marked or if there is any ambiguity about what your answer is. Each question in
this section is worth 5 points. Zero points are given for incorrect answers: therefore, it is to
your advantage to give an answer for each question.
1. Which of the following is the strongest acid? [This is not a trick question.]
a. HNO3b. H2S c. PH3d. SiH4 e. CH4
2. Will a precipitate be formed if 0.100 mol of Ag+ and 0.001 mol of SO42- are added to
water to make 1.0 L of solution? (Ksp = 1.4 x 10-5)
a. Yes, because Q > Ksp
b. Yes, because Q < Ksp
c. No, because Q > Ksp
d. No, because Q < Ksp
3. Which of the following describes what happens to the solubility of a slightly soluble
ionic compound when a common ion is added to a saturated solution of the compound?
a. The solubility of the ionic compound is reduced.
b. The solubility of the ionic compound is increased.
c. There is no effect on the solubility of the ionic compound.
d. More of the ionic compound dissolves.
4. What is the smallest [Ag+] that would cause the precipitation of Ag2CrO4 from 0.050 M
Na2CrO4 (aq)? (the Ksp of Ag2CrO4 is 2.4 x 10-12)
a. 4.8 x 10-11 M
b. 6.9 x 10-6 M
c. 1.5 x 10-6 M
d. 8.4 x 10-5 M
e. 2.4 x 10-11 M
5. Identify the acid and base on each side of the following equation:
pf3
pf4
pf5

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April 23, 2008 Exam 4

Please write your name at the top of each page of this examination in the space provided. I will deduct 5 points from your score if you do not do so! Section A. MULTIPLE CHOICE QUESTIONS: (5 pts each) Choose the best answer. Clearly circle your answer. No credit will be given if more than answer is marked or if there is any ambiguity about what your answer is. Each question in this section is worth 5 points. Zero points are given for incorrect answers: therefore, it is to your advantage to give an answer for each question.

  1. Which of the following is the strongest acid? [This is not a trick question.] a. HNO 3 b. H 2 S c. PH 3 d. SiH 4 e. CH 4
  2. Will a precipitate be formed if 0.100 mol of Ag+^ and 0.001 mol of SO 4 2-^ are added to water to make 1.0 L of solution? (Ksp = 1.4 x 10-5) a. Yes, because Q > Ksp b. Yes, because Q < Ksp c. No, because Q > Ksp d. No, because Q < Ksp
  3. Which of the following describes what happens to the solubility of a slightly soluble ionic compound when a common ion is added to a saturated solution of the compound? a. The solubility of the ionic compound is reduced. b. The solubility of the ionic compound is increased. c. There is no effect on the solubility of the ionic compound. d. More of the ionic compound dissolves.
  4. What is the smallest [Ag+] that would cause the precipitation of Ag 2 CrO 4 from 0.050 M Na 2 CrO 4 (aq)? (the Ksp of Ag 2 CrO 4 is 2.4 x 10-12) a. 4.8 x 10-11^ M b. 6.9 x 10-6^ M c. 1.5 x 10-6^ M d. 8.4 x 10-5^ M e. 2.4 x 10-11^ M
  5. Identify the acid and base on each side of the following equation:

April 23, 2008 Exam 4

HSO 3 -^ (aq) + HPO 4 2-^ (aq)  SO 3 2-^ (aq) + H 2 PO 4 -^ (aq) a. acid + base  acid + base b. base + acid  acid + base c. base + acid  base + acid d. acid + base  base +acid e. It is not an acid-base reaction.

  1. Which of the following pairs of species is a conjugate acid base pair? a. HCl, HBr b. HI, NaOH c. H 2 SO4. HSO 4 -^ d. H 3 O+, OH- e. HNO 3 , HNO 2
  2. A pH meter reads 4.48. What is the [H 3 O+] in the solution? a. 3.0 x 10^4 M b. 3.3 x 10-5^ M c. 9. d. 10-7^ M e. 3.0 x 10-10^ M
  3. Which is the correct solubility product constant expression for Ag 2 CO 3?

a. Ksp = [^ ][ ]

2 3 2 2 Ag ^ CO^ 

b. Ksp =

[ ][ ]

2 3

Ag ^2 CO 

c. Ksp = [^ ][ ]

2 3 Ag ^2 CO

d. Ksp = 2 [ ][ ]

2 3  AgCO^ 

e. Ksp = [^ ][ ]

2 3 Ag ^ CO^  Section B. Write-out Problems

April 23, 2008 Exam 4

12. (10 points) Determine the pH of the following two solutions: (a) 0.200 M HCl

(aq); (b) 0.0500 M NaOH (aq).

13. (15 points) Suppose 50.0 mL of 0.100 M Ca(NO 3 ) 2 (aq) are mixed with 50.0 mL

of 0.100 M Na 2 SO 4 (aq).

April 23, 2008 Exam 4

(a) Calculate the initial values of [Ca2+] and [SO 4 2-] in the reaction mixture.

(b) Calculate the equilibrium values of [Ca2+] and [SO 4 2-] (Ksp = 9.1 x 10-6).

(c) Calculate the percentage of Ca2+^ ions that remain in solution and the precipitation

percentage.