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This study guide provides the most recent and verified questions with correct answers for the 2025 Firefighter Hazardous Materials Operations (HazMat Ops) final exam. It covers critical topics such as hazardous material identification, PPE use, decontamination procedures, emergency response protocols, and safety operations. An excellent resource for firefighters aiming for top performance in HazMat certification. Keywords: hazmat operations firefighter exam hazardous materials final exam prep emergency response decontamination PPE procedures real exam questions
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material that is capable of posing a unreasonable risk to human health, safety, or the environment when transported in commerce, used incorrectly, or not properly contained or stored
Weapons whose use is intended to cause mass causalities, damage, and chaos. (NFPA classifies as hazardous material )
damage to the nervous system
is used for fixed facilities
tendency to deteriorate in the presence of another substance or in a particular environment
concentration of vapor to air below which a flame will not propagate in the presence of an ignition source
vapor to air concentration above which a flame will not propagate
liquid will give off sufficient vapors that will ignite readily given an ignition source
liquid or solid as compared to an equal amount of water
the area of release for a long period of time
expressed in microns or percent passing through a meshed screen
temperature required to cause self-sustained combustion in the absence of any source of ignition
Explosives
Gases
Flammable/Combustible Liquids
Flammable solids/ spontaneously combustible materials/ dangerous- when-wet materials/water-reactive substances
Oxidizing Substances/Organic Peroxides
You're driving alongside the railroad tracks and see a tank car with a white body and two red vertical bands. A label on the tank reads "HIGHLY TOXIC." You have just seen a: -
Strong, tight packages are designed to transport radioactive materials
uranium and rubble from nuclear reactors and packaged in steel, wood, or fiberboard Intermodal equipment, including tank containers will have all of the
abbreviation for the owner, followed by an "X" and numbers As you survey an incident, you DO NOT need to consider: -
CHEMTREC has access to all of the following resources
Association Information about the role of local, state, and Federal authorities
You are at a HazMat incident that you suspect involves criminal or terrorist activity. There are munitions involved and you need an Explosives Ordinance Disposal team to respond to the scene. The
U.S. Army Operations Center
A material's flash point is the primary characteristic used to determine
Flammability When radioactive contamination occurs and the person is removed
contaminated material ingested or inhaled continues to emit radiation A chemical inside a container has come into contact with an incompatible substance and is now degrading its own container. When Responder Watson describes the situation to CHEMTREC,
Chemical Stress The type of release that is associated with runaway cracking is: -
A material that is not necessarily toxic but can cause unconsciousness and death by displacing or depriving oxygen is
Exposure to a high dose of radiation for a short time is considered: -
If the intensity of the incident increases and could pose an unreasonable threat to the responders at the scene, the responders
To find out the distances for evacuation at a HazMat incident, use the Emergency Response Guidebook to determine the size of the
Operations level responder Grabbe is at a HazMat incident near Lake Eerie. Grabbe is ready to monitor the size of the perimeter of the hazard-control zones. Identify the TWO items he should take into account when making
Immediately wash any exposed body parts with flooding quantities of water The purpose of the Operations level goal, "implement the planned
outcomes while making sure they are consistent with local emergency response plans and the organization's standard operating procedures
At an incident at a fixed facility, you notice a product name and an identification number stenciled on the container. The
Plan Using the U.N. hazard class system, materials other than gas that are either known to be so toxic to humans as to afford a hazard to health during transport, OR in the absence of adequate data on human toxicity are presumed to be toxic to humans, would fall under: -
At a site, your binoculars aren't strong enough to read the numbers on the placard, but you do see a yellow and white placard with a
CHEMTREC will have the shipper or manufacturer call you
exceed intended limits and radioactive material is transferred to people, animals, or the environment All the following statements are true about nonionizing radiation
materials and skin
Neutron
abnormalities in embryos, or genetic modifications in cells
International Agency for Research on Cancer
interacts with DNA and causes a mutation.
corrosives, flammable liquids, toxics Identify THREE items found in the EXPOSURE
Appropriate engineering controls
The U.N. hazard class division for the choking agent phosgene is -
Identify THREE ways in which you can identify materials stored at
NFPA 704 symbol
Identify FOUR resources that an Operations level responder has available for use when determining the concentrations of a released hazardous material within an endangered area.
High pressure tank trucks A tank carrier designed to carry flammable liquids, combustible liquids, class B poisons, and liquid food products with vapor pressures up to 4 psi is an A. MC306 / DOT406 B. MC307 / DOT C. MC312 / DOT
Nonpressure cargo tank trucks A carboy may be used for transporting materials containing A. radioactive substances B. corrosives C. expolosives
as a responder trained to the operations level, one of the ways to verify chlorine could emit vapors is to: A. contact CHEMTREC for assistance B. enter the hot zone to read the label on the cylinder C. bring a chlorine monitor into the vapor cloup to check the reading D. apply water to the spill to determine if a gas cloud is formed -
packing used for transport with extremely low levels of radioactivity that present no risk to the public or environment is known as A. Type B B. Expected
C. industrial
type ________ packaging contains low-level commercial radioactive shipments in cardboard boxes, wooden crates, and metal drums: A. A B. B C. C
Which is mandatory information found on a pestiside label? A. Environmental protection agency registration number B. flammability level C. national fire protection association 704 data
Environmental protection agency registration number The statement "Keep Away from Waterways," is found on a pesticide label. This statement is referred to as a(n): A. signal word B. precautionary statement C. pest control product warning
precautionary statement the environmental protection agency (EPA) signal word - Warning - represents A. high level of toxicity
when exposed to heat or fire, a liquid with a low boiling point will A. less readily change to vapor than a liquid with a high boiling point B. spontaneously combust C. become more corrosive D. more readily change to vapor than a liquid with a high boiling point
The minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture, with air near the surface is called the _______ point A. combustion B. ignition C. flash
radiation that can be stopped by a piece of paper consists of _________ particles A. Alpha
B. Beta C. Neuron
Alpha particles can be described as A. large particles that pass through structural PPE B. ionizing rediation like X-rays C. particles with weight and mass D. deadly radiation as it cna pass through structural PPE -
determining whether a vapor will rise or fall is commonly referred to as A. Vapor dispersion B. Vapor density C. Vaporization
pressure of a substance at 100 Degrees F A. will remain the same substance at 68 Degrees B. always higher than the same substance at 68 degrees C. will be lower than the same substance at 68 degrees
B. always higher than the same substance at 68 degrees The immediate concern when dealing with combustible liquid spills is to A. apply aqueous film forming foam to the combistible liquid B. prevent ignition of the fuel
B. burning sensation to the eyes C. convulsions
to the eyes Toxic gases, blood agents, such as arsine and cyanogen chloride, would fall under which UN/DOT hazard class A. 1.1 B.
C. 6.
the products that IM101 intermodal portable tanks typically carry are A. molten sulfur B. flammable gases C. Flammable liquids
liquids which DOT hazard class covers nerve agents used in chemical warfare A. DOT 6.3 B. DOT 6. C. DOT 6.
the physical destruction or decomposition of chemical protective clothing by a chemical action is called A. degradation
B. breakthrough time C. penetration
a process in which a material is added to soak up a hazardous material to prevent enlargement or spread of the contaminated area is known as A. Neutralization B. solidification C. adsorption
the chemical action involving the movement of chemicals, on a modular level, through intact materials best defines A. degradation B. breakthrough time C. penetration
when dealing with a level 3 incident, it is expected that evacuation of people will cover an area of A. several square blocks B. large scale evacuation C. one mile upwind
large scale evacuation when sheltering people in place, the citizens should be directed to