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Friedel-Crafts Alkylation and Acylation: Mechanisms, Problems, and Solutions, Study notes of Chemistry

Frostburg State University (FSU)Chemistry

An overview of the Friedel-Crafts alkylation and acylation reactions, their mechanisms, and the problems associated with each process. It also discusses methods to address these issues, such as the use of reducing agents and nucleophilic substitution reactions. useful for students and researchers in the field of organic chemistry.

Typology: Study notes

2021/2022

Uploaded on 09/12/2022

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Friedel-Crafts Alkylation

General scheme:

AlCl3or

FeBr3

(R = alkyl) or

Friedel-Crafts Alkylation

Depends on formation of alkyl cation (or “incipient” cation) intermediate:

2° or 3° halide:

1° or CH3halide:

These intermediates react identically in the Friedel-Crafts

alkylation reaction.

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