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Understanding Vapor Pressure & Boiling Points: Water in Denver, CO & Long Island, Study Guides, Projects, Research of Chemistry

An explanation of vapor pressure and its relationship to boiling points. It includes examples of how atmospheric pressure affects the boiling point of water in different locations, such as denver, co and long island. The document also discusses the role of intermolecular forces in determining vapor pressure and boiling points.

Typology: Study Guides, Projects, Research

2021/2022

Uploaded on 09/12/2022

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HChemVaporPressure2017.notebook
1
November06,2017
Nov72:39PM
Vapor Pressure and Table H
Aim: Why does water boil at 95°C in Denver, Colorado?
Nov72:39PM
Vapor Pressure: the pressure exerted by gas molecules
(vapor) above the surface of a liquid as it evaporates.
Vapor pressure increases as e vaporation increases.
Two factors that influence the vapor pressure of a substance :
‐Temperature
‐Intermolecular forces of attraction
H
2
O(l)
H
2
O(g)
Vapor
Pressure
Nov72:39PM
Vapor Pressure & Boiling
Increasing temperature causes more evaporation and
an increase in the vapor pressure because more liquid
particles escape as a gas.
The vapor pressure becomes strong enough to overcome the
atmospheric pressure and the liquid boils.
Nov72:39PM
Vapor Pressure & Boiling
Atmospheric pressure ‐ The
pressure pushing down on the
surface of a liquid.
This pressure interferes with
evaporation (liquid particles
can't escape as easily) and
therefore it is more difficult
to boil.
Two ways to get a liquid to boil:
1)Increase the temperature in order to increase the vapor pressure.
2)Decrease the atmospheric pressure until it equals the vapor pressure.
A liquid will only boil when the vapor pressure of the
liquid is equal to the atmospheric pressure.
AtmosphericPressure
pf3

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Nov 72:39 PM

Vapor Pressure and Table H

Aim: Why does water boil at 95°C in Denver, Colorado?

Nov 72:39 PM

Vapor Pressure: the pressure exerted by gas molecules

(vapor) above the surface of a liquid as it evaporates.

Vapor pressure increases as evaporation increases.

Two factors that influence the vapor pressure of a substance:

‐Temperature

‐Intermolecular forces of attraction

H 2 O (l) H 2 O (g) Vapor Pressure

Nov 72:39 PM

Vapor Pressure & Boiling

Increasing temperature causes more evaporation and

an increase in the vapor pressure because more liquid

particles escape as a gas.

The vapor pressure becomes strong enough to overcome the

atmospheric pressure and the liquid boils.

Nov 72:39 PM

Vapor Pressure & Boiling

Atmospheric pressure ‐ The

pressure pushing down on the

surface of a liquid.

This pressure interferes with

evaporation (liquid particles

can't escape as easily) and

therefore it is more difficult

to boil.

Two ways to get a liquid to boil: 1)Increase the temperature in order to increase the vapor pressure. 2)Decrease the atmospheric pressure until it equals the vapor pressure.

A liquid will only boil when the vapor pressure of the

liquid is equal to the atmospheric pressure.

Atmospheric Pressure

Nov 72:39 PM

Why does water on Long Island boils at 100°C while in Denver,

CO water boils at 95°C?

‐This is because the atmospheric pressure is lower in Denver

and it requires less energy to get the vapor pressure of the

liquid to overcome the atmospheric pressure on a mountain

than at sea level.

http://www.youtube.com/watch?v=VjgfelzQ_aE

Nov 72:39 PM

Table H is used to determine the vapor pressure of a liquid at a

specific temperature.

Table H is used to determine the boiling point of a liquid at a

given vapor pressure.

Nov 72:39 PM

  1. Which sample of propanone has the greatest vapor pressure? a. 100 ml at 20°C b. 100 ml at 30°C c. 100 ml at 25°C d. 100 ml at 35°C
  2. At what vapor pressure will ethanol boil with a temperature of 75°C?
  3. What is the vapor pressure of water at 50°C? 12 kPa 85 kPa

Nov 72:39 PM

  1. What is the vapor pressure of water at 105°C?
  2. At which temperature would ethanol have the highest vapor pressure? a. 30°C b. 50°C c. 40°C d. 60°C
  3. What is the normal boiling point of ethanoic acid? 120 kPa 117 °C