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CAMEO Chemicals - ✔✔http://cameochemicals.noaa.gov/browse Which laws and regulations should First Responders become familar with then questions arise? - ✔✔RCRA, CERCLA, SARA, HAZCOM, OPA 90 and HAZWOPER contain in the field standards used by First Responders when working in hazardous sites. What is the Resource Conservation and Recovery Act (RCRA)? - ✔✔Resource Conservation and Recovery Act (RCRA) required the Environmental Protection Agency (EPA) to begin cradle-to-grave tracking or hazardous waste and required the establishment of standards for hazardous waste treatment, storage, and disposal facilities. What is the Comprehensive Environmental Response Compensation Liability Act (CERCLA)? - ✔✔The Superfund law provides funds to the Coast Guard (through EPA) for emergency response containment and cleanup of abandoned hazardous material releases. What are the tasks that emergency responders are trained to perform? - ✔✔Awarness Level Operations Level Technician Specialist Incident Commander Items that are documented in a Contingency Plan that directs First responders on what to do? - ✔✔Emergency Notifications Emergency Response Procedures Command Structure Identification of Resources Scenerios
What is the Superfund Amendments and Reauthorization Act (SARA)? - ✔✔An extension and expansion of CERCLA required the EPA to issue regulations mandating compliance with the OSHA HAZWOPER regulation in all area no under OSHA juridicion. SARA specifically required the EPA to revise how it determines the risk posed to the public and evironment by uncontrolled hazardous waste sites. It also included a provision referred to as Community Right to Know which requires all businessess to provide the government with detailed information about the hazardous materials they work ith and have on site. What is the Hazard Communication Right to Know (HAZCOM)? - ✔✔HAZCOM serves as the foundation for unit's Hazard Communication Program. HAZCOM specifically requires employers to inform their employees about any hazardous materials they might encounter on the job and to provide them with the resouces needed to handle them appropriately. What is the OPA 90? - ✔✔Specifies the following:
- The federal government will direct responses to spills
- Area committees (including the Coast Guard) must develop Area Contingency Plans for spills
- Owner/operators of facilities and vessels must prepare their own Response Plans. The plans developed by each of these entities are valuable resources that will help you determine what to do if you encounter an oil spill or hazardous materials release. Hazardous Waste Operations and Emergency Response (HAZWOPER)? - ✔✔The primary focus is safeguarding you, your shipmates, and the public from the dangers of oil spills and hazardous material releases while responding to incidents outside of your unit (29 CFR 1910.120) Following is a list of authorities who should always be notified of a hazardous meterial release - ✔✔Sector Command Center National Response Center (NRC) District Response Advisory Team (DRAT) Safety & Environment Health Officer Nation Strike Force (NSF) Chain of Command
The stores data on marine accidental and deliberate pollution and other shipping and port accidents in U.S. territorial waters as well as specific vessel information regarding cargo and general construction and capacities. - ✔✔Marine Information for Safety and Law Enforcement (MISLE) are documents that are prepared by facility managers to prevent, mitigate, and prepare for a chemical release which are not limited to evecuation routes, decontamination procedures, and notification procedures. - ✔✔Facility plans and equipment are used for mission parameters to protect personnel and public safety. - ✔✔Personal Protective Equipment (PPE) What are the 7 pre-panning essential elements for managing an emergency effectively? - ✔✔Personnel (Always Ready), Equipment, Training, Communications, Environment, Unknown Varables (Limit), Planned Evacuation Routes. Air monitoring items used during field activities and emergency response? - ✔✔Multi-Gas Detector (e.g., GAMIC - 4), Radiation Detector (e.g., PM3702 Pager), Emergency Escape Breathing Device (EEBD). What are Risk Assessment Models used during an emergency response? - ✔✔Severity, Probability, Exposure (SPE) Model and the Green, Amber Red (GAR) Model What is the purpose of anticipation / pre-mission planning? - ✔✔To protect personnel, the environment, and the public's health and safety. What is the resource used during the pre-planning process of an emergency? - ✔✔Chemical, Hazard, Response Information System (CHRIS) Manual What is the evironmental factors that could increase the probability of personal injury during an evoulution? - ✔✔Types of chemicals on site, Cause of the incident, and extent of chemical release and support What are the preparation and mission planning element considered when anticipating hazards? - ✔✔Personnel, Cause of the Incident, Extent of Chemical release and transport.
What equipment can help protect against chemical and physical hazards? - ✔✔Emergency Escape Breathing Device (EEBD), Multi-Gas detector and Radiation detector What is the acronym for SPE stand for? - ✔✔Severity, probabiltity, expose What are indications of a Harzardous Materials Release when a chemical spill is not obvious? - ✔✔Dead animals, lack of insect life, unexplained odors, unusual numbers of dying or sick people (mass casualties), blisters / rashes, illness in the confined area, unusual liquid droplets, different - looking areas, low-lying clouds and unusaul metal debris. After identifying the conminated area the will need to be consulted if available that provides vital information for dealing with hazardous materials. - ✔✔Material Safety Data Sheet (MSDS) Terms used to describe the physical characteristics of a hazardous materials? - ✔✔Combustible Liquids Compressed Gas Explosive, Flammable Liquid Terms used to describe the chemical characteristics of a hazardous materials? - ✔✔Oxidizer Unstable and Reactive Water-Sensitive Pyrophoric Key terms used to describe the effects of exposure to hazardous materials? - ✔✔Toxic Chemical Agents Irritants Corrosives Sensitizers Carcinogens
refers to the pressure a saturated vapor exerts above its own liquid, due to its tendency to evaporate and produce vapors, when it is stored in a closed container. - ✔✔Vapor pressure The higher the number on the Material Safety Data Sheet (MSDS), the more likely the will produce vapors. Increaded vapors result in higher pressure when the is stored in a container. - ✔✔liquid tells you whether the vapors produced by a liquid will tend to rise or fall. - ✔✔Vapor Density If a gas has a vapor density of less then the vaport will generally rise in the air. If the vapor has greater then , the gas will generally sink in the air. - ✔✔one tells you whether a liquid will rise or sink when it is put in water. - ✔✔Specific Gravity has a specific gravity of 1.0. Anything greater then 1.0 will sink and anything less then 1.0 will rise. - ✔✔Water Terms used to describe firefighting considerations - ✔✔Flash Point Flammable or Explosive Limits A liquid's is the lowest temperature at which it gives off enough vapor near its surface to form an ignitable mixture with air. - ✔✔Flash Point with low flash points are more combustible that with high flash points. - ✔✔Liquids Liquids are classified by their flash points as either combustible or flammable. However the and have different standards for combustible and flammable liquids. - ✔✔National Fire Protection Agency (NFPA) Department of Transportation (DOT)
Flammable and Combusitble limits as described by the National Fire Protection Agency (NFPA) - ✔✔Flammable - Less then 100 degrees farenheit Combustible - Greater than 100 degrees farenheit Flammable and Combusitble limits as described by the Department of Transportation (DOT) - ✔✔Flammable - Less then 141 degrees farenheit Combustible - Greater than 141 degrees farenheit and below 200 degrees farenheit The Flammable or Explosive Limits section of the provides a concentration range within which vapors produced by a liquid if exposed to an ignition source. - ✔✔Material Safety Data Sheet (MSDS) Concentration limits of vapors - ✔✔Lower Limit - lowest concentration of vapor that will ignite Upper Limit - highest concentration of vapor that will ignite If Iso-Butane has a lower explosive limit of 1.8 percent and an upper limit of 8.44 percent. If you enter a room with a 6 percent concentration of Iso-Butane and light a match, will the vapor ignite? - ✔✔Yes Toluene has a specific gravity of 0.86. If it was spilled in a river, what would the subtance do? - ✔✔Float on top of the water as toluene is less dense than water so it would float. What is an indication of a hazardous materials has been released in an area. - ✔✔Dead animals, illness to a confined area, low - lying clouds What is the definition of a combustible liquid limit - ✔✔Greater then 100 degrees farenheit and Greater than 141 degrees farenheit and below 200 degrees farenheit What is a mystery liquid with vapors that tend to stay close to the ground. - ✔✔Hydrochloric acid - 1.2, because any liquid with a vapor density greater than 1 will tend to stay close to the ground. What is the the color coded manual assists with hazardous material release? - ✔✔Emergency Response Guidebook (ERG)
Potential hazards found on Freight / Container Vessels - ✔✔Any number of potentially hazardous materials can be found on freight / container vessels. The is a system that standardized the use of colors in hazardous materials recognition. - ✔✔National Fire Protection Association (NFPA) 704 The conveys information about hazardous materials through markings, labels, and placards. - ✔✔U.S. DOT Chart 14 The National Fire Protection Association (NFPA) 704 is a - ✔✔Designed by firefighters, the color coding used in this easily understood, non-technical system is commonly found outside the entrances of buildings. Four diamond - shaped elements are used to provide specific information about the material contained within. on packages and containers of hazardous materials provide a descriptive name, identification number, instruction, cautions, weight, specifications or UN marks, or combinations thereof. - ✔✔Markings U.S. Department of Transportation (DOT) and are formatted in the same fashion. Each provides diffenent types of informaton needed to properly identify important characteristics of hazardous materials. - ✔✔labels and placards are divided according to the nine U.S. DOT Hazard Classes. These diamond-shaped, 4 by 4 labels are placed on packages containing hazardous materials. - ✔✔Hazardous Material Warning Labels What are the 9 U.S. DOT Harzard Classes? - ✔✔Class 1 - Explosives Class 2 - Gases Class 3 - Flammable Liquid Class 4 - Flammable Solid, Spontanelously Combustible, and Dangerous when wet Class 5 - Oxidizer and Organic Peroxide Class 6 - Poison (Toxic), Poison Inhalation Hazard, Infectious Substance Class 7 - Radioactive
Class 8 - Corrosive Class 9 - Miscellaneous Hazardous Material is a 10.8 by 10.8 inch, diamond shaped marking identifies the contest of a vehicle or container used for transporting hazardous materials. Under the strict definition of , it must be displayed point on end and all four sides of the contain the same. - ✔✔Placard A potential hazardous materials release displays obvious , such as a fire or an explosion. - ✔✔External Warning Signs Containers can suffer stress from? - ✔✔Thermal exposure (i.e., fire) Mechanical stress (e.g., a forklift punctures a drum) Chemical stress (e.g., a container is weakened by a corrosive material) Leaks (or intentional release) Employers are required to provide an for every hazardous substance used in the workplace. An must identify the name, harzard class, components, and properties of the substance, in addition to instruction on how to respond to a spill. - ✔✔Material Safety Data Sheet (MSDS) is considered the last line of defense when trying to recognize a harzardous materials release because it is the most dangerous. - ✔✔A person five senses is a mnemonic for hazardous materials recognition. It stands for container, Occupancy / Location, Markings / Colors, Placards / Labels, Appearance, Shipping Papers / MSDS, and Senses. - ✔✔COMPASS The external warning signs of a possible hazardous materials realease that can be identified when examining containers - ✔✔Thermal exposure Mechanical Stress Leaks
Identifying hazards in the Operational Risk Management (ORM) correlates with the phase of the Anticipation, Recognition, Evaluation, and Control (AREC) process. - ✔✔Recognition phase Operational Risk Management (ORM) specifically focuses on hazard identification in the following areas?
- ✔✔P - Planning E - Event Complexity A - Asset Selection C - Communication E- Environmental Conditions Assessing risks in the Operational Risk Management (ORM) correlates with the phase of the Anticipation, Recognition, Evaluation, and Control (AREC) process. - ✔✔Evaluation phase At the Operational Risk Management (ORM) point in the process, the model and / or General Assessment of Risk (GAR) model is used to determine the individual risks of the hazards identified in the PEACE model. - ✔✔Severity, Probability, and Exposure (SPE) model In general, Severity, Probability, and Exposure (SPE) identifies risks for specific hazards, such as recovering a small aircraft, while provides more general data. - ✔✔General Assessment of Risk (GAR) Identifying options in the Operational Risk Management (ORM) correlates with the phase in the Anticipation, Recognition, Evaluation, and Control (AREC) process. - ✔✔Control phase The 3 main categories of controls implemented during the control phase of the Anticipation, Recognition, Evaluation, and Control (AREC) process? - ✔✔Engineering Controls (e.g., ventilation & machinery guards, etc are removed) Administrative Controls (e.g., training, monitoring & tracking) Personal Protective Equipment (PPE)
The steps involved in in Operational Risk Management (ORM) are part of the Anticipation, Recognition, Evaluation, and Control (AREC) processes and provide important informaton to guide your continued maintenance of the Risk Management Process. - ✔✔Risk verses Gain The in Operational Risk Management (ORM) is used to calculate the degree of risk given the controls identified during the control phase of the Anticipation, Recognition, Evaluation, and Control (AREC) process. - ✔✔Risk verses Gain After the risks have been identified and assessed, and the control decisions have been made in the Operational Risk Management (ORM) process, it is time to implement the controls and. - ✔✔Execute the decisions The final step in the Operational Risk Management (ORM) process is as efforts progress to clean up the hazardous materials. - ✔✔Monitor the Situation If a change in the situation is identified or if a presumed condition does not exist, the Operational Risk Management (ORM) process needs to be to take the change into account. - ✔✔repeated entirely Which process is used to asses the level of risk of identified hazards? - ✔✔SPE and GAR are used to calculate risks before, during, and after work has begun at a site. Each process has a specific function and provides a different type of information. The evaluation of potention hazards is accomplished by. - ✔✔The Operational Risk Management (ORM) process is used to evaluate potential hazards. The steps in the Operational Risk Management (ORM) support the Anticipation, Recognition, Evaluation, and Control (AREC) process. If risk assessment determines that current plans are not sufficient to address the hazards on site, the next level in the chain of command should be notified to take the appropriate actions. - ✔✔True. As the assessor of risks you should not immediately take any actions on your own before first notifying the next level in the chain of command in the current plans do not address the site hazards. What is not a basic saftey control measure? - ✔✔Waste Management Controls
white (synonymous iwth special info about hazards) Sensitizers cause a substantial proportion of exposed people or animals to develop an allergic reaction in normal tissue after repeated exposure. - ✔✔True As a member of the Coast Guard, you will most likely encounter hazardous materials in which of the following locations? - ✔✔Fishing vessels Bulk Cargo Vessels Freight/Container Vessels If you discover a hazardous materials release, you should immediately notify the Sector Command Center and/or the National Response Center (NRC). - ✔✔True The National Response Center (NRC) is the primary federal point of contact for reporting oil and chemical spills. - ✔✔True The National Response Center (NRC) is the primary federal point of contact for reporting oil and chemical spills. - ✔✔True The General Assessment of Risk (GAR) model evaluates risk by assigning ratings to which of the following factors? - ✔✔Planning Which of the following is the most common standard-issue piece of equipment that must be carried on all boardings and inspections? - ✔✔-Radiation detectors - PM3702 (carried on all boardings)
- Multi-gas detectors - GAMIC4 (carried on all boardings)
- Emergency Escape Breathing Device (EEBD) (used to a contamined space quickly) Coast Guard members are authorized to work in environments considered Immediately Dangerous to Life and Health (IDLH) if they are wearing the appropriate Personal Protective Equipment (PPE). - ✔✔False
he Severity, Probability, Exposure (SPE) model is used to assess risks before response efforts begin and when new or more specific information about the hazardous materials release and/or the site of the release arises. - ✔✔True Which of the following chemical properties refers to the lowest temperature at which a liquid gives off enough vapor near its surface to form an ignitable mixture with air? - ✔✔Flash point The information you provide when reporting a hazardous materials release should include the location of the incident, the size of the release, and the type of hazardous material at the site. - ✔✔True Engineering controls, administrative controls, and protective equipment controls are associated with which step of the Coast Guard's Operational Risk Management (ORM) process? - ✔✔Identify Options If risk assessment determines that current plans are not sufficient to address the hazards on site, the next level in the chain of command should be notified to take the appropriate actions. - ✔✔True An environment that has a concentration of a hazardous material far above the upper explosive limit will ignite when a flame is introduced. - ✔✔False PEACE is a pneumonic associated with which step in the Coast Guard's Operational Risk Management (ORM) process? - ✔✔Identify hazards A mystery liquid has vapors that tend to rise into the air. Which of the following listed below (along with its vapor density) might it be? - ✔✔Diethanolamine - 1. Nickel Carbonyl - 1. Hexachlorocyclopentaidiene - 1. Acetone - 0.79 (Answer) Which of the following is NOT a basic safety control measure? - ✔✔Personal Protectvie Equipment (PPE) controls Administrative controls Engineering controls
a choking agent. CHRIS - ✔✔Chemical Hazards Response Information System Combustible liquid - ✔✔Liquids that have a flash point greater than 60.5 °C (141 °F) and below 93 °C (200 °F). U.S. regulations permit a flammable liquid with a flash point between 38 °C (100 °F) and 60.5 °C (141 °F) to be reclassified as a combustible liquid. Control zones - ✔✔Designated areas at hazardous materials incidents, based on safety and the degree of hazard. These zones are commonly referred to as the hot/exclusion/red/restricted zone, warm/contamination reduction/yellow/limited access zone, and cold/support/green/clean zone. CPC - ✔✔Chemical Protective Clothing CWA - ✔✔Clean Water Act (1972) Decontamination - ✔✔The removal of hazardous contamination from personnel and equipment to the extent necessary to prevent potential adverse health effects. Always avoid direct or indirect contact with hazardous materials; however, if contact occurs, personnel should be decontaminated as soon as possible. Since the methods used to decontaminate personnel and equipment differ from one chemical to another, contact the chemical manufacturer to determine the appropriate procedure. Contaminated clothing and equipment should be removed after use and stored in a controlled area (warm/contamination reduction/limited access zone) until cleanup procedures can be initiated. In some cases, protective clothing and equipment cannot be decontaminated and must be disposed of in a proper manner. DOT - ✔✔Department of Transportation EPA - ✔✔Environmental Protection Agency EPCRA - ✔✔Emergency Planning and Community Right-to-know Act
Flammable liquid - ✔✔A liquid that has a flash point of 60.5oC (141oF) or lower. Flash point - ✔✔Lowest temperature at which a liquid or solid gives off vapor in such a concentration that, when the vapor combines with air near the surface of the liquid or solid, a flammable mixture is formed. Hence, the lower the flash point, the more flammable the material. FRA - ✔✔First Responder Awareness FRO - ✔✔First Responder Operations Hot zone - ✔✔Area immediately surrounding a hazardous materials incident which extends far enough to prevent adverse effects from released hazardous materials to personnel outside the zone. This zone is also referred to as exclusion zone, red zone or restricted zone IDLH - ✔✔Immediately Dangerous to Life or Health LEL - ✔✔Lower Explosive Limit MSDS - ✔✔Material Safety Data Sheet NCP - ✔✔National Contingency Plan Nerve agents - ✔✔Substances that interfere with the central nervous system. Exposure is primarily through contact with the liquid (via skin and eyes) and secondarily through inhalation of the vapor. Tabun (GA), Sarin (GB), Soman (GD) and VX are nerve agents. NFPA - ✔✔National Fire Protection Association NIOSH - ✔✔National Institute for Occupational Safety and Health
