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inorganic chemistry: basic concepts to applied, Lecture notes of Inorganic Chemistry

intro to inorganic chemistry, importance classification

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CURRICULUM
OF
CHEMISTRY
BS (4-YEAR)
2008
HIGHER EDUCATION COMMISSION
ISLAMABAD
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CURRICULUM

OF

CHEMISTRY

BS (4-YEAR)

HIGHER EDUCATION COMMISSION

ISLAMABAD

CURRICULUM DIVISION, HEC

Dr. Syed Sohail H. Naqvi Executive Director

Prof. Dr. Riaz ul Haq Tariq Member (Acad)

Miss. Ghayyur Fatima Deputy Director (Curri)

Mr. M. Tahir Ali Shah Assistant Director

Mr. Shafiullah Khan Assistant Director

PREFACE

Curriculum development is a highly organized and systematic process and involves a number of procedures. Many of these procedures include incorporating the results from international research studies and reforms made in other countries. These studies and reforms are then related to the particular subject and the position in Pakistan so that the proposed curriculum may have its roots in the socio-economics setup in which it is to be introduced. Hence, unlike a machine, it is not possible to accept any curriculum in its entirety. It has to be studied thoroughly and all aspects are to be critically examined before any component is recommended for adoption.

In exercise of the powers conferred by sub-section (1) of section 3 of the Federal Supervision of Curricula Textbooks and Maintenance of Standards of Education Act 1976, the Federal Government vide notification No. D773/76-JEA (cur.), dated December 4th^ 1976, appointed the University Grants Commission as the competent authority to look after the curriculum revision work beyond class XII at the bachelor level and onwards to all degrees, certificates and diplomas awarded by degree colleges, universities and other institutions of higher education.

In pursuance of the above decisions and directives, the Higher Education Commission (HEC) is continually performing curriculum revision in collaboration with universities. According to the decision of the special meeting of Vice-Chancellor’s Committee, the curriculum of a subject must be reviewed after every 3 years.

A committee of experts comprising of conveners from the National Curriculum Revision of HEC in Basic, Applied Social Sciences and Engineering disciplines met in April 2007 and developed a unified template to standardize degree programs in the country to bring the national curriculum at par with international standards, and to fulfill the needs of the local industries. It also aimed to give a basic, broad based knowledge to the students to ensure the quality of education. The new BS degree shall be of 4 years duration, and will require the completion of 130-136 credit hours. For those social sciences and basic sciences degrees, 63.50% of the curriculum will consist of discipline specific courses, and 36.50% will consist of compulsory courses and general courses offered through other departments.

For the purpose of curriculum revision various committees are constituted at the national level, comprising of senior teachers nominated by universities, degree awarding institutions, R&D organizations and respective accreditation councils. The National Curriculum Revision

Committee for chemistry in a meeting held on March 10-11, 2008, at the HEC Regional Center, Lahore, in continuation of its earlier meeting held on October 30-31, 2007, at HEC Regional Center, Karachi, revised the curriculum in light of the unified template. The final draft prepared by the National Curriculum Revision Special Committee, duly approved by the competent authority, is being circulated for implementation in the concerned institutions.

DR. RIAZ-UL-HAQ TARIQ

Member Academics June 2008

INTRODUCTION

ational Curriculum Revision Committee (NCRC) in

Convener

tr chi

Member

aceutic nces

sari Member

slamabad

Sher Khan Sadozai Member

t of Chemistry n

Tahir Member

t of Chemistry ity, Islamabad

Member

azi Institute of Chemistry

Member

try rsity, Multan

Member

ar

The Final me eting of N Chemistry was held at HEC Regional Centre Lahore on March 10-11,

  1. This Meeting was a follow up of the previous meeting held on October 30-31, 2007 at HEC Regional Centre, Karachi. The following attended the meetings.

  2. Prof. Dr. Fahim Uddin Adjunct Professor Department of Chemis y University of Karachi, Kara

  3. Prof. Dr. G. A. Miana Rector / Director R & D Riphah Institute of Pharm al Scie 7 th^ Avenue, G-7/4, Islamabad

  4. Prof. Dr. Muhammad Shahid An Department of Chemistry Quaid-i-Azam University, I

  5. Prof. Dr. Chairman Departmen Gomal University, D.I.Kha

  6. Prof. Dr. Muhammad Kaleem Chairman Departmen Allama Iqbal Open Univers

  7. Prof. Dr. Ubedullah M.Abbasi Director Dr.M.A.K University of Sindh, Jamshoro

  8. Prof. Dr. Humayun Pervez Professor / Chairman Department of Chemis Bahauddin Zakariya Unive

  9. Prof. Dr. Muhammad Arfan Institute of Chemical Sciences University of Peshawar, Peshaw

  1. Prof. Dr. Abdullah Khan Member

t of Chemistry

  1. rof Dr. Ahmed Saeed Member
  2. yed Ishrat Ali Member

t of Applied Chemistry

Iqbal Zafar Member str rsity

. Jamil Anwar Member

f Chemistry b, Lahore

  1. Prof. Dr. Muhammad Arif Member

rsity

. Muhammad Aslam Shad Member

rsity

. Abdul Shakoor Qureshi Member

mistry

ohammad Saeed Iqbal Member/

Chairman Departmen University of Balochistan Quetta

P

Department of Chemistry Gomal University D.I Khan

Prof. Dr. S Chairman Departmen University of Karachi Karachi

  1. Dr. Zafar Department of Chemi y Bahauddin Zakariya Unive Multan
  2. Prof. Dr Director Institute o University of the Punja

Department of Chemistry Bahauddin Zakariya Unive Multan

  1. Prof. Dr Department of Chemistry Bahauddin Zakariya Unive Multan
  2. Prof. Dr Dr. M.A. Kazi Institute of Che University of Sindh Jamshoro
  3. Prof. Dr. M Chairman Secretary Department of Chemistry G.C. University Lahore

CHEM: Chemistry Courses GEN: General Courses MATH: Mathematics Course COMP: Computer Course STAT: Statistics Course BIO: Biology Course

ii) The letter code will be followed by three digits; the first digit

iii) cond digit specifying the

Analytical Chemistry 1 emistr

iv) The third digit may be used to indicate diversity within the

v) e special courses in 7th^ and 8 th^ semester may be

The

e of social sciences.

g.

will denote level of the course.

For the Chemistry courses, se subject identity will be as follows:

Applied / Industrial Ch y 2 Biochemistry 3 Environmental Chemistry 4 Inorganic Chemistry 5 Organic Chemistry 6 Physical Chemistry 7 Institutional Option 8

specialty.

Codes for th assigned in accordance with the above guidelines.

salient features of this scheme are:

  • Introduction of required weightag
  • Independent life-long learning.
  • Development of creative thinkin

After exhaustive discussion, the following layout of courses was finalized and approved in the light of guidelines provided by the HEC:

Compulsory Requirements (The Student Has No Choice)

General Courses to Be Chosen from Other Dept. 9 Courses 7- 8 Courses 25 Credit hours 21- 24 Credit hours Subject Cr. hr Subject Cr. hr

  1. ENGLISH I
  2. ENGLISH II
  3. ENGLISH III
  4. ENGLISH IV/ UNIVERSITY OPTIONAL *****
  5. PAKISTAN STUDIES
  6. ISLAMIC STUDIES / ETHICS
  7. MATHEMATICS-I
  8. MATHEMATICS-II / UNIVERSITY OPTIONAL
  9. INTRODUCTION TO COMPUTER

3 3 3 3 2 2 3 3 3

  1. GEN-
  2. GEN-
  3. GEN-
  4. GEN-
  5. GEN-
  6. GEN-
  7. GEN-

3 3 3 3 3 3 3

Total 25 21

Discipline specific foundation courses

Major courses including research project/internship

Elective courses within the major 9-10 Courses 11-13 Courses 4 Courses 30-33 Credit hours 36 - 42 Credit hours 12 Credit hours Subject Cr. hr Subject Cr. hr Subject Cr.hr CHEM- CHEM- STAT- CHEM- CHEM- CHEM- CHEM- CHEM-

3+ 3+ 3 2 2 2 3+ 2

CHEM- CHEM- CHEM- CHEM-211/ CHEM- CHEM- CHEM- CHEM-311/ CHEM-PAPER-I CHEM- PAPER-II CHEM- PAPER-III PRACTICAL.-I CHEM-PAPER-IV CHEM-PAPER-V CHEM-PEPER-VI PRACTICAL-II

3+ 3+ 3+ 3+ 3+ 3+ 3+ 3+ 3 3 3 1 3 3 3 1

ELECTIVE COURSE – I ELECTIVE COURSE – II RESEARCH PROJECT / ADVANCED PRACTICAL – I / POSITION PAPER RESEARCH PROJECT / ADVANCED PRACTICAL – II / POSITION PAPER

3

3

2

2

23 52 10

Course Title Credit hours Semester - V Theory Practical CHEM-251 Inorganic Chemistry 3 1 CHEM-261 Organic Chemistry 3 1 CHEM-271 Physical Chemistry 3 1 CHEM-211 Analytical-/ CHEM-231 Bio-Chemistry

Total 12 4 Semester - VI Theory Practical CHEM-351 Inorganic Chemistry 3 1 CHEM-361 Organic Chemistry 3 1 CHEM-371 Physical Chemistry 3 1 CHEM-311 Analytical-/ CHEM-331 Bio- Chemistry

Total 12 4 Semester - VII: Specialization (Inorganic/ Organic/Physical/Applied/ Analytical/Bio Chemistry)

Theory Practical

Paper-I 3 0 Paper-II 3 0 Paper-III 3 0 Practical-I 0 1 Elective Course-I (other than the field of specialization)

Research Project / Advanced Practical / Position Paper (literature survey)

Total 12 3 Semester - VIII : Specialization (Inorganic/ Organic/Physical/ Applied/ Analytical-/Bio-Chemistry

Theory Practical

Paper - IV 3 0 Paper - V 3 0 Paper - VI 3 0 Practical - II 0 1 Elective Course - II (other than the field of specialization)

Research Project / Advanced Practical / Position Paper (write-up)

Total 12 3

Total Credit Hours: 131

The list of general courses was also reviewed and approved as follows:

List of General Courses:

(Proposed in NCRC special meeting in Chemistry)

  1. Social Psychology
  2. Community Development
  3. Environmental Sciences
  4. Principles of management
  5. Logic and Reasoning
  6. Teaching and Learning
  7. Social Issues of Pakistan
  8. Entrepreneurship
  9. Human Resource Management
  10. Basic Financial Management
  11. History of Human Civilization
  12. History of Science

OR

Any other, including supportive science courses other than chemistry, depending upon the expertise available

2. Constitution of Sub-Committees to Prepare

Course Outlines of Various Specializations:

Various sub-committees were constituted to prepare course outlines of various specializations. The sub-committees constituted are as under:

Inorganic Chemistry Physical Chemistry

  1. Prof. Dr. M Arif 1. Prof. Dr. Fahim Uddin Chairman Chairman Department of Chemistry Department of Chemistry Bahauddin Zakaria University of Karachi University, Multan Karachi
  2. Prof. Dr. Sher Khan Sadozai 2. Prof. Dr. M. Shahid Ansari Chairman Department of Chemistry Department of Chemistry Quaid-i-Azam University Gomal University Islamabad D. I. Khan
  1. Prof. Dr. Rehana Rashid 6. Prof. Dr. M. Aslam Shad Department of Chemistry Dept. of Chemistry University of Balochistan Bahauddin Zakariya Quetta University, Multan

Analytical/Environmental Applied Chemistry Chemistry 1 Prof. Dr. M. Saeed Iqbal 1. Prof. Dr. Syed Ishrat Ali Chairman Chairman Deptt. of Applied Chem. Department of Chemistry University of Karachi GC University Karachi. Lahore

  1. Prof. Dr. Ubedullah M. Abbasi 2. Prof. Dr. Fazeelat Tahira Director Chairperson Dr. M. A. Kazi Institute of Deptt. of Chemistry Chemistry Univ. of Engg. & University of Sindh, Jamshoro Technology, Lahore
  2. Prof. Dr. Jamil Anwar 3. Prof. Dr. Bakhtiar Director, Institute of Chemistry Muhammad University of the Punjab Chairman Lahore Deptt. of Chemistry Hazara University Mansehra
  3. Prof. Dr. Rasul Jan 4. Dr. Zafar Iqbal Zafar Director, Institute of Chemical Deptt. of Chemistry Sciences, University of Bahauddin Zakariya Pshawar, Peshawar University, Multan
  4. Dr. Ikhtiar Khan 5. Dr. Yousuf Iqbal Institute of Chemical Sciences Institute of Chemical University of Peshawar Science Peshawar University of Peshawar Peshawar
  5. Dr. Aziz Ahmed Chaudhry Department of Chemistry AJK University Muzaffarabad

It was decided that the Convener will coordinate with the sub-committees with the help of HEC to prepare the course outlines which will be presented to the NCRC meetings to be held at an appropriate time and date in Islamabad for approval of these courses. It was further decided that the course outlines of the following subjects will be prepared by

holding separate meetings of the sub-committees constituted for that purpose. However, the following members will coordinate with these committees to assist in preparation of these courses.

Mathematics: Prof. Dr. Fahim Uddin Biology: Prof. Dr. M. Kalim Tahir Statistics: Prof. Dr. M. Saeed Iqbal English: Prof. Dr. Humayun Pervez

The course outlines of the general subjects will be got prepared and provided by the relevant committees under the directions of HEC.

3. Before the Start of the formal Proceedings on 10-

11 March 2008, Fateha was offered for the

Departed Soul of Prof. Dr. Rashid Iqbal, former

Chairman, Department of Chemistry, Quaid-e-

Azam University, Islamabad

The course outlines prepared by the sub-committees were reviewed, finalized and approved by the NCR Special Committee. The Heads of the sub-committees were advised to send the course contents to the respective members and to incorporate the minor changes as proposed by the members. Each Heads of subcommittee shall submit the final modules of the course contents to the Convener NCRC latest by March 30, 2008 for onward transmission to the HEC.

Final Version is detailed below:

MISSION STATEMENT

  1. The common purpose is to achieve the highest possible standards of scholarship, teaching and research in chemistry and allied subjects.
  2. Theobjectives of this curriculum are:

i) To encourage intellectual development and scholarship in and through chemistry;

ii) To impart a sound knowledge of chemistry to students and to help them to use this knowledge creatively and analytically;

iii) To develop in students an awareness of the applications of chemistry including its practical, social and economic

delocalized approach to bonding: molecular orbital theory as applied to diatomic and polyatomic molecules, three center bonds, bonding theory of metals and intermetallic compounds; conductors, insulators and semiconductors; bonding in electron deficient compounds; hydrogen bonding.

3. Acids and Bases

Concepts of acids and bases including SHAB concept, relative strength of acids and bases, significance of pH, pKa, pKb and buffer solutions. Theory of Indicators, solubility, solubility product, common ion effect and their industrial applications.

4. Chemistry of p-block Elements

Chemistry and structure of p- block elements; main emphasis on the chemistry and structure of noble gases and their compounds, chemistry and structure of interhalogens, pseudohalogens and polyhalides. Prediction of shapes of molecules using VSEPR model and hybridization.

PRACTICAL (CHEM-151) (1-Cr. Hr.)

1. Laboratory Ethics and safety measures

Awareness about the toxic nature of chemicals and their handling, cleaning of glassware, safe laboratory operations

2. Qualitative analysis

Analysis of four ions (two anions and two cations) from mixture of salts

3. Quantitative analysis

Laboratory work illustrating topics covered in the lecture of CHEM-

Recommended Books

  1. Huheey, J. E., Keiter, E. A. and Keiter, R. L., “Inorganic Chemistry: Principles of Structure and Reactivity”, 4th Ed., Harper and Row, New York, 2001
  2. Cotton, F. A., Wilkinson, G. and Gaus, P. L., “Basic Inorganic Chemistry”, 3rd Ed., Wiley, New York, 1995.
  3. Clyde Day, M. & Selbin, J., “Theoretical Inorganic Chemistry”, 2nd Ed., Van Nustrand Reinhold, 1969.
  4. Lee, J.D., “Concise Inorganic Chemistry”, Chapman and Hall, 5th Edition,1996.
  5. Shriver, D. F., Atkins, P. W. and Langford, C. H., “Inorganic Chemistry”, Oxford University Press, 2nd^ Edition, 1994.
  1. Bassette, J., Denney, G. H. and Mendham, J., “Vogel’s Textbook of Quantitative Inorganic Analysis Including Elementary Instrumental Analysis” English Language Book Society, 4 th Edition, 1981.
  2. Vogel, A. I., “A Textbook of Micro and Semi-micro Qualitative Inorganic Analysis” Longman Green & Co. 1995.

BS 1

st

Year

Semester-II

Title of the Course: Organic Chemistry Code: CHEM-

Credit Hours: 03 Marks: 100

Introduction to Organic Chemistry

Organic chemistry-the chemistry of carbon compounds; the nature of organic chemistry-a historical perspective.

Chemical Bonding and Properties of Organic Molecules

Localized and delocalized chemical bonding; concept of hybridization leading to bond angles, bond lengths, bond energies and shape of organic molecules; dipole moment; inductive and field effects; resonance; aromaticity; tautomerism; hyperconjugation; hydrogen bonding; acids and bases; factors affecting the strengths of acids and bases.

Classes and Nomenclature of Organic Compounds

Classification of organic compounds; development of systematic nomenclature of organic compounds; IUPAC nomenclature of hydrocarbons and heteroatom functional groups.

Functional Group Chemistry

A brief introduction to the chemistry of hydrocarbons, alkyl halides, alcohols, phenols, ethers, aldehydes, ketones, amines, and carboxylic acids and their derivatives. ]

Recommended Literature

(Latest available editions of the following books)

  1. Clayden, J., Greeves, N., Warren, S. and Wothers, P., “Organic Chemistry”, Oxford University Press, New York.