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Group Theory: Subgroups, Products, and Representations, Slides of Solid State Physics

The concept of subgroups in group theory, providing examples and theorems. It also covers the product of groups, the inner product, and matrix representations. based on a research paper from Roland Winkler and collaborators from NIU, Argonne, and NCTU, published between 2011 and 2015.

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Introduction to Group Theory
With Applications to Quantum Mechanics
and Solid State Physics
Roland Winkler
rwinkler@niu.edu
August 2011
(Lecture notes version: November 3, 2015)
Please, let me know if you find misprints, errors or inaccuracies in these notes.
Thank you.
Roland Winkler, NIU, Argonne, and NCTU 20112015
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Introduction to Group Theory

With Applications to Quantum Mechanics

and Solid State Physics

Roland Winkler rwinkler@niu.edu

August 2011

(Lecture notes version: November 3, 2015)

Please, let me know if you find misprints, errors or inaccuracies in these notes. Thank you.

General Literature

I (^) J. F. Cornwell, Group Theory in Physics (Academic, 1987) general introduction; discrete and continuous groups

I (^) W. Ludwig and C. Falter, Symmetries in Physics (Springer, Berlin, 1988). general introduction; discrete and continuous groups

I (^) W.-K. Tung, Group Theory in Physics (World Scientific, 1985). general introduction; main focus on continuous groups

I (^) L. M. Falicov, Group Theory and Its Physical Applications (University of Chicago Press, Chicago, 1966). small paperback; compact introduction

I (^) E. P. Wigner, Group Theory (Academic, 1959). classical textbook by the master

I (^) Landau and Lifshitz, Quantum Mechanics, Ch. XII (Pergamon, 1977)

brief introduction into the main aspects of group theory in physics

I (^) R. McWeeny, Symmetry (Dover, 2002) elementary, self-contained introduction

I (^) and many others

These notes are dedicated to

Prof. Dr. h.c. Ulrich R¨ossler

from whom I learned group theory

R.W.

Introduction and Overview

Definition: Group

A set G = {a, b, c,.. .} is called a group, if there exists a group multiplication connecting the elements in G in the following way

(1) a, b ∈ G : c = a b ∈ G (closure)

(2) a, b, c ∈ G : (ab)c = a(bc) (associativity)

(3) ∃ e ∈ G : a e = a ∀a ∈ G (identity / neutral element)

(4) ∀a ∈ G ∃ b ∈ G : a b = e, i.e., b ≡ a−^1 (inverse element)

Corollaries

(a) e−^1 = e

(b) a−^1 a = a a−^1 = e ∀a ∈ G (left inverse = right inverse)

(c) e a = a e = a ∀a ∈ G (left neutral = right neutral)

(d) ∀a, b ∈ G : c = a b ⇔ c−^1 = b−^1 a−^1

Commutative (Abelian) Group

(5) ∀a, b ∈ G : a b = b a (commutatitivity)

Order of a Group = number of group elements

Group Theory in Physics

Group theory is the natural language to describe symmetries of a physical system

I (^) symmetries correspond to conserved quantities

I (^) symmetries allow us to classify quantum mechanical states

  • (^) representation theory
  • (^) degeneracies / level splittings

I (^) evaluation of matrix elements ⇒ Wigner-Eckart theorem e.g., selection rules: dipole matrix elements for optical transitions

I (^) Hamiltonian ˆH must be invariant under the symmetries of a quantum system ⇒ construct ˆH via symmetry arguments

I (^)...

Group Theory in Physics

Classical Mechanics

I (^) Lagrange function L(q, q˙),

I (^) Lagrange equations d dt

∂L

∂ q˙i

∂L

∂qi

i = 1,... , N

I (^) If for one j : ∂L ∂qj

= 0 ⇒ pj ≡

∂L

∂ q˙j

is a conserved quantity

Examples

I (^) qj linear coordinate

  • translational invariance
  • linear momentum pj = const.
  • translation group

I (^) qj angular coordinate

  • rotational invariance
  • angular momentum pj = const.
  • rotation group

Group Theory in Physics

Quantum Mechanics

(1) Evaluation of matrix elements (cont’d)

Group theory provides systematic generalization of these statements

I (^) representation theory ≡ classification of how functions and operators transform under symmetry operations

I (^) Wigner-Eckart theorem ≡ statements on matrix elements if we know how the functions and operators transform under the symmetries of a system

Group Theory in Physics

Quantum Mechanics

(2) Degeneracies of Energy Eigenvalues

I (^) Schr¨odinger equation Hˆψ = E ψ or iℏ∂t ψ = Hˆψ

I (^) Let ˆO with iℏ∂t Oˆ = [ Oˆ, Hˆ] = 0 ⇒ Oˆ is conserved quantity

⇒ eigenvalue equations Hˆψ = E ψ and ˆOψ = λ (^) Oˆ ψ can be solved simultaneously

⇒ eigenvalue λ (^) Oˆ of ˆO is good quantum number for ψ

Example: H atom

I Hˆ = ℏ

2 2 m

∂^2

∂r 2

r

∂r

ˆL^2

2 mr 2

e^2 r

⇒ group SO(3)

⇒ [Lˆ^2 , Hˆ] = [Lˆz , Hˆ] = [Lˆ^2 , Lˆz ] = 0 ⇒ eigenstates ψnlm(r): index l ↔ Lˆ^2 , m ↔ ˆLz I (^) really another example for representation theory I (^) degeneracy for 0 ≤ l ≤ n − 1: dynamical symmetry (unique for H atom)

Group Theory in Physics

Quantum Mechanics

(3) Solid State Physics

(ii) Phonons

I (^) Consider square lattice

by 90o

rotation

I (^) frequencies of modes are equal I (^) degeneracies for particular propagation directions

(iii) Theory of Invariants I (^) How can we construct models for the dynamics of electrons or phonons that are compatible with given crystal symmetries?

Group Theory in Physics

Quantum Mechanics

(4) Nuclear and Particle Physics

Physics at small length scales: strong interaction

Proton mp = 938.28 MeV

Neutron mn = 939.57 MeV

rest mass of nucleons almost equal ∼ degeneracy

I (^) Symmetry: isospin ˆI with [ˆI , Hˆstrong] = 0

I (^) SU(2): proton | 1212 〉, neutron | 12 − 12 〉

Conclusions from

Group Multiplication Table

P 3 e a b c d f e e a b c d f a a b e f c d b b e a d f c c c d f e a b d d f c b e a f f c d a b e

I (^) Symmetry w.r.t. main diagonal ⇒ group is Abelian

I (^) order n of g ∈ G: smallest n > 0 with g n^ = e

I (^) {g , g 2 ,... , g n^ = e} with g ∈ G is Abelian subgroup (a cyclic group)

I (^) in every row / column every element appears exactly once because:

Rearrangement Lemma: for any fixed g ′^ ∈ G, we have G = {g ′g : g ∈ G} = {gg ′^ : g ∈ G} i.e., the latter sets consist of the elements in G rearranged in order. proof: g 1 6 = g 2 ⇔ g ′g 1 6 = g ′g 2 ∀g 1 , g 2 , g ′^ ∈ G

Goal: Classify elements in a group

(1) Conjugate Elements and Classes

I (^) Let a ∈ G. Then b ∈ G is called conjugate to a if ∃ x ∈ G with b = x ax−^1.

Conjugation b ∼ a is equivalence relation:

  • (^) a ∼ a reflexive
  • (^) b ∼ a ⇔ a ∼ b symmetric
  • (^) a ∼ c b ∼ c

} ⇒ a ∼ b transitive a^ =^ xcx

− (^1) ⇒ c = x− (^1) ax b = ycy −^1 = (xy −^1 )−^1 a(xy −^1 )

I (^) For fixed a, the set of all conjugate elements C = {x ax−^1 : x ∈ G} is called a class.

Example: P 3 x e a b c d f e e a b c d f a e a b d f c b e a b f c d c e b a c f d d e b a f d c f e b a d c f ⇒ classes {e}, {a, b}, {c, d, f }

  • identity e is its own class x e x−^1 = e ∀x ∈ G
  • Abelian groups: each element is its own class x ax−^1 = ax x−^1 = a ∀a, x ∈ G
  • (^) Each b ∈ G belongs to one and only one class ⇒ decompose G into classes
  • in broad terms: “similar” elements form a class

Goal: Classify elements in a group

(3) Invariant Subgroups and Factor Groups

connection: classes and cosets I (^) A subgroup U ⊂ G containing only complete classes of G is called invariant subgroup (aka normal subgroup). I (^) Let U be an invariant subgroup of G and x ∈ G ⇔ x Ux−^1 = U ⇔ x U = Ux (left coset = right coset) I (^) Multiplication of cosets of an invariant subgroup U ⊂ G: x, y ∈ G : (x U) (y U) = xy U = z U where z = xy

well-defined: (x U) (y U) = x (U y ) U = xy U U = z U U = z U I (^) An invariant subgroup U ⊂ G and the distinct cosets x U form a group, called factor group F = G/U

  • group multiplication: see above
  • U is identity element of factor group
  • x−^1 U is inverse for x U I (^) Every factor group F = G/U is homomorphic to G (see below).

Example: Permutation Group P 3

e a b c d f e e a b c d f a a b e f c d b b e a d f c c c d f e a b d d f c b e a f f c d a b e

invariant subgroup U = {e, a, b}

⇒ one coset cU = dU = f U = {c, d, f }

factor group P 3 /U = {U, cU} U cU U U cU cU cU U

I (^) We can think of factor groups G/U as coarse-grained versions of G.

I (^) Often, factor groups G/U are a helpful intermediate step when working out the structure of more complicated groups G.

I (^) Thus: invariant subgroups are “more useful” subgroups than other subgroups.