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Introduction to thermodynamics: - Fundamental concepts - Ideal gas temperature scale - Heat capacity - Enthalpy - Equilibrium state and phase rule - Heat reservoirs and heat engines
Typology: Lecture notes
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KE = [1/2] m u 2 ] o Microscopic energy - Related to the molecular behavior of the system; independent of the outer reference.
dH = dU + P dV + V dP Substituting [dU = dQ - dW] from the first law of thermodynamics in the equation above. dH = dQ โ dW + P dV + v dP Now, [dW = P dV] for a reversible non flow process [V dP = 0] for constant pressure process. dH = dQ i.e., a system heated at constant pressure with only expansion work occurring, the change in enthalpy is equal to the heat supplied. Whereas, for a process occurring at constant volume, work of expansion is zero and the differential equation reveals that the change in internal energy is equal to the heat supplied. dU = dQ (for a constant volume process).