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Properties of Liquids and Solids: Intermolecular Forces and Physical Properties - Prof. Be, Study notes of Chemistry

An in-depth exploration of the properties of liquids and solids, focusing on intermolecular forces, vapor pressure, boiling points, viscosity, surface tension, and the structure of water and ice. It covers topics such as the differences between gases, liquids, and solids, the concept of intermolecular bonds, and the various types of intermolecular forces (dispersion forces, dipole forces, and hydrogen bonds). The document also discusses the unique properties of water, including its unusual melting and boiling points.

Typology: Study notes

Pre 2010

Uploaded on 08/19/2009

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Chem 1075 Chapter 13 Liquids and Solids Lecture Outline
Slide 2-3 Properties of Liquids
Unlike gases, liquids_______________respond dramatically to temperature and pressure changes.
We can study the liquid state and make 5 general observations.
1. Liquids have a ____________________________, but a _______________________________.
Liquids take the shape of their _________________________________
2. Liquids usually ______________ readily.
However, not all liquids flow at the ______________________________.
3. Liquids do not ___________________ or ____________________significantly
The volume of a liquid varies ________________________ as the temperature and pressure
change.
4. Liquids have a ______________________________ compared to gases.
Liquids are about ______________________ more dense than gases.
5. Liquids that are soluble mix ____________________________________.
Liquids ____________________________________ than gases but eventually will form a
homogeneous mixture.
Slide 4 Intermolecular Bond Concept
An intermolecular bond is an attraction___________________molecules, whereas intramolecular
bonds are between atoms ___________________a molecule.
Some properties of liquids, such as vapor pressure, viscosity, and surface tension, are determined by
the strength of attraction between molecules.
Intermolecular bonds are _____________________________ than intramolecular bonds.
Slide 5 Intermolecular Bonds
Recall, that a __________________ molecule has positive and negative charges concentrated in
different regions due to __________________________________________ of electrons in bonds.
This uneven distribution of electrons in a molecule is called a ___________________.
Intermolecular attractions result from _________________________________ or
______________________________________dipoles in molecules.
There are three intermolecular forces:
1.
2.
3.
Slide 6 Dispersion Forces Dispersion forces, or London forces, are the result of
_________________________________________.
Electrons are constantly _______________________ and a region
may become temporarily ____________ ________________ and
slightly _________________ while another region becomes slightly
negative.
This creates a temporary dipole and two molecules with temporary
dipoles are _____________________ to each other.
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Download Properties of Liquids and Solids: Intermolecular Forces and Physical Properties - Prof. Be and more Study notes Chemistry in PDF only on Docsity!

Chem 1075 Chapter 13 Liquids and Solids Lecture Outline

Slide 2-3 Properties of Liquids

  • Unlike gases, liquids_______________respond dramatically to temperature and pressure changes.
  • We can study the liquid state and make 5 general observations.
  1. Liquids have a ____________________________, but a _______________________________.
    • Liquids take the shape of their _________________________________
  2. Liquids usually ______________ readily.
    • However, not all liquids flow at the ______________________________.
  3. Liquids do not ___________________ or ____________________significantly
    • The volume of a liquid varies ________________________ as the temperature and pressure change.
  4. Liquids have a ______________________________ compared to gases.
    • Liquids are about ______________________ more dense than gases.
  5. Liquids that are soluble mix ____________________________________.
    • Liquids ____________________________________ than gases but eventually will form a homogeneous mixture.

Slide 4 Intermolecular Bond Concept

  • An intermolecular bond is an attraction___________________ molecules , whereas intramolecular bonds are between atoms ___________________a molecule.
  • Some properties of liquids, such as vapor pressure, viscosity, and surface tension, are determined by the strength of attraction between molecules.
  • Intermolecular bonds are _____________________________ than intramolecular bonds.

Slide 5 Intermolecular Bonds

  • Recall, that a __________________ molecule has positive and negative charges concentrated in different regions due to __________________________________________ of electrons in bonds.
  • This uneven distribution of electrons in a molecule is called a ___________________.
  • Intermolecular attractions result from _________________________________ or ______________________________________dipoles in molecules.
  • There are three intermolecular forces:

Slide 6 Dispersion Forces

  • Dispersion forces, or London forces, are the result of _________________________________________.
  • Electrons are constantly _______________________ and a region may become temporarily ____________ ________________ and slightly _________________ while another region becomes slightly negative.
  • This creates a temporary dipole and two molecules with temporary dipoles are _____________________ to each other.

Slide 7 Dispersion Forces Continued

  • Dispersion forces are the ____________________ intermolecular force.
  • Dispersion forces are present in _________ molecules.
  • The ___________________________ of the dispersion forces in a molecule is related to the _____________________________________ in the molecule: - The _____________________________ in a molecule, the ___________________________ the dispersion forces.

Slide 8 Dipole Forces

  • Polar molecules have a _________________________________ dipole.
  • The oppositely charged ends of polar molecules are attracted to each other, this is the ________________________________________.
  • The strength of a dipole force is typically __________ of a covalent bond’s strength.
  • Dipole forces are _______________________ than dispersion forces.

Slide 9 Hydrogen Bonds

  • Hydrogen bonds are a special type of dipole attraction.
  • Hydrogen bonds are present when a molecule has an _______, _______, or _______ bond.
  • Hydrogen bonds are especially important in water and living organisms.

Slide 10 Physical Properties of Liquids

  • There are 4 physical properties of liquids that we can relate to the intermolecular attractions present in the molecules:

Slide 11 Vapor Pressure

  • At the _____________________ of a liquid, some molecules gain enough energy to ______________ the intermolecular attractions of neighboring molecules and enter the __________________________. This is _________________________________.
  • The ____________________ process is condensation.
  • When the rates of evaporation and condensation are equal, the pressure exerted by the gas molecules above a liquid is called the____________________________________________.

Slide 15 Boiling Point

  • The normal boiling point of a substance is the temperature where the vapor pressure is ___________ to the standard atmospheric pressure.
  • As we saw in the previous graph, the ______________________ the intermolecular attractions, the ______________________ the boiling point of the liquid.
  • A liquid with a _____________ boiling point has a ____________ vapor pressure.

Slide 16 Viscosity

  • The viscosity of a liquid is a liquid’s ____________________________________________________.
  • Viscosity is the result of an_____________________________________between molecules.
  • The ___________________ the intermolecular forces, the ________________________ the viscosity.

Slide 17 Surface Tension

  • The ______________________________ between molecules at the ___________________ of a liquid is called surface tension.
  • For an object to sink in a liquid, it must first break through the surface.
  • The _______________________ the intermolecular attractions, the _________________________the surface tension of a liquid.

Slide 18-19 Properties of Solids

  • Unlike gases, solids do not respond dramatically to temperature and pressure changes.
  • We can study the solid state and make 5 general observations.
  1. Solids have a ________________shape and volume.
    • Unlike liquids, solids are _____________________
  2. Solids are either __________________________________ or _______________________________.
    • Crystalline solids contain particles in a regular, repeating _________________________.
  3. Solids _________________ compress or expand to any degree
    • Assuming no change in physical state, temperature and pressure have a ___________________ ____________________ on the volume of a solid.
  4. Solids have a slightly __________________ density than their corresponding liquid
    • One important _________________________ is __________________; ice is less dense than liquid water.
  5. Solids ____________________________________ by diffusion
    • The particles are ________________________ to diffuse in a solid heterogeneous mixture.

Slide 20 Crystalline Solids

  • There are three types of crystalline solids examples of which are shown below: a) b) c)

Slide 21 Ionic Solids

  • A crystalline______________________________is composed of positive and negative ions arranged in a ______________________________________________________ pattern.
  • In table salt, NaCl, sodium ions and chloride ions are arranged in a regular three-dimensional structure referred to as a crystal lattice.
  • Other ionic compounds will have different crystal lattices.

Slide 22 Molecular Solids

  • A crystalline________________________________has __________________________ arranged in a particular conformation.
  • In water, H 2 O, the molecules are arranged in a regular three-dimensional structure.
  • Other examples of crystalline molecular solids are table sugar, C 12 H 22 O 11 , and sulfur, S 8.

Slide 23 Metallic Solids

  • A crystalline _________________________________ is composed of _________________________ arranged in a definite pattern.
  • A metallic crystal is made up of ________________________________________surrounded by __________________________________________.
  • Metals are good conductors of electricity because electrons are _______________________________ about the crystal.
  • This is referred to as the ________________________________________________________.

Slide 24 General Properties of Solids Table 13.4 in Text Type of Solid General Properties Examples IONIC

MOLECULAR

METALLIC