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16 questions related to molecular polarity and bonding, including identifying bond types based on electronegativity differences, determining the polarity of molecules, ranking the polarity of bonds, and identifying molecular geometries. It includes detailed explanations and answers.
Typology: Exercises
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This print-out should have 16 questions. Multiple-choice questions may continue on the next column or page – find all choices before answering.
001 10.0 points Based only on the difference in electronega- tivity (∆EN) identify the types of the labeled bonds in the molecule below, from left to right:
bS b bb 3
Explanation: The B-H bond will have a ∆EN of less than 2 but more than zero, and thus will be a polar covalent bond. The C-C bond will have a ∆EN of zero, and thus will be non-polar covalent. The C=S bond will have a ∆EN of less than 1 but more than zero, and thus will be polar covalent.
002 10.0 points Which of the following molecules is/are po- lar?
Explanation: Molecule II is symmetrical and therefore its individual dipole moments cancel, making it non-polar. Molecules I and III are asymmet- rical and therefore polar.
003 10.0 points Which of the following is the correct Lewis structure for ethene (C 2 H 4 )?
correct
Explanation:
004 10.0 points Rank the labeled bonds in the molecule below from least to most polar.
c
b N
bb
e
bb bb H (^) a
Sbbb^ b
d b b Sbb
Explanation: Bonds a, b, c, d, and e have a ∆EN of 1.4, 1.0, 0.5, 0.0, and 0.9, respectively.
005 10.0 points Rank the following by the polarity of their bonds, from most polar to least: LiH, NH 3 , BH 3 , HF.
006 10.0 points In which of the following do the unbonded electron pairs not distort the bond angles?
007 10.0 points Which of the following is most likely to form multiple (double or triple) bonds?
bond.
Explanation: Since F is more electronegative than I, a C-F bond will have a greater difference in electronegativities than a C-I bond.
014 10.0 points Which of the following only has bond angles of 90◦^ and 180◦?
Explanation: BrF 3 exhibits T-shaped molecular geome- try.
015 10.0 points How many σ (sigma) and how many π (pi) bonds are there in the Lewis structure of the following organic molecule?
bO b bb
b b Obb
016 10.0 points Determine the electronegativity difference, the probable bond type, and the more electronegative atom with respect to bonds formed between between the pair of atoms H and F.