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The experimental procedure for measuring the specific heat capacity of water using an electrical method. The apparatus includes a calorimeter, heating coil, joulemeter, thermometer, and a power supply. The procedure involves finding the masses of the calorimeter and water, recording initial and final temperatures, and calculating the specific heat capacity of water using the electrical energy supplied. A polystyrene container or alternative methods for measuring electrical energy are also discussed.
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Joulemeter, calorimeter, heating coil, beaker, lagging, thermometer reading to 0.1 °C, electronic balance and a low voltage a.c. supply.
Cover (^) Digital thermometer 10°C
Mass of the calorimeter mcal = Mass of the calorimeter plus the water m 1 = Mass of the water mw = m 1 mcal = Initial temperature of water 1 = Final temperature 2 = Rise in temperature = 2 1 = Final joulemeter reading Q =
Given that the specific heat capacity of the calorimeter ccal is known, the specific heat capacity of water cw can be calculated from the following equation: Electrical energy supplied = energy gained by water + energy gained by calorimeter Q = mwcw + mcalccal.
If a polystyrene container is used in place of the copper calorimeter, then the energy gained by the water is equal to the electrical energy supplied since the heat capacity of the container is negligible. The energy equation now reads: Q = mwcw. If a joulemeter is unavailable, electrical energy can be supplied to the heating coil from a power supply unit connected in series to an ammeter and rheostat. A voltmeter must be placed in parallel with the heating coil to measure the potential difference and a stopwatch used to measure the time of current flow. Switch on the current and the stopwatch simultaneously. Adjust the rheostat to maintain a constant current. Allow the current to flow until a temperature rise of 10 °C has been achieved. Record the steady current I and voltage V readings. Switch off the current and the stopwatch simultaneously. Record the time t in seconds. If a calorimeter is used the energy equation is: VIt = mwcw + mcalccal. If a polystyrene container is used the energy equation is: VIt = mwcw.