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SAFETY DATA SHEET
Creation Date 23-Feb-2011 Revision Date 24-Dec-2021 Revision Number 5
1. Identification
Product Name Methyl 3-nitrobenzoate
Cat No. : AC168440000; AC168440250; AC168441000; AC
CAS No 618-95- Synonyms No information available Recommended Use Laboratory chemicals. Uses advised against Food, drug, pesticide or biocidal product use. Details of the supplier of the safety data sheet Emergency Telephone Number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-
2. Hazard(s) identification
Classification Classification under 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements None required Hazards not otherwise classified (HNOC) None identified
3. Composition/Information on Ingredients
Company Fisher Scientific Company One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796- Acros Organics One Reagent Lane Fair Lawn, NJ 07410 This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
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Component CAS No Weight % Benzoic acid, 3-nitro-, methyl ester 618-95-1 >
4. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur. Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur. Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur. Most important symptoms and effects None reasonably foreseeable. Notes to Physician Treat symptomatically 5. Fire-fighting measures Suitable Extinguishing Media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Unsuitable Extinguishing Media No information available Flash Point No information available Method - No information available Autoignition Temperature No information available Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Nitrogen oxides (NOx). Carbon monoxide (CO). Carbon dioxide (CO 2 ). Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA 6. Accidental release measures Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. Environmental Precautions Should not be released into the environment. See Section 12 for additional Ecological Information. Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Health 0 Flammability 1 Instability 0 Physical hazards N/A
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Stability Stable under recommended storage conditions. Conditions to Avoid Incompatible products. Excess heat. Avoid dust formation. Incompatible Materials Strong bases Hazardous Decomposition Products Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO 2 ) Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing.
11. Toxicological information Acute Toxicity Product Information No acute toxicity information is available for this product Component Information Toxicologically Synergistic Products No information available Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation No information available Sensitization No information available Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS No IARC NTP ACGIH OSHA Mexico Benzoic acid, 3-nitro-, methyl ester 618-95-1 Not listed Not listed Not listed Not listed Not listed Mutagenic Effects No information available Reproductive Effects No information available. Developmental Effects No information available. Teratogenicity No information available. STOT - single exposure None known STOT - repeated exposure None known Aspiration hazard No information available Symptoms / effects,both acute and delayed No information available Endocrine Disruptor Information No information available Other Adverse Effects The toxicological properties have not been fully investigated. 12. Ecological information Ecotoxicity Do not empty into drains. Persistence and Degradability Insoluble in water Persistence is unlikely Bioaccumulation/ Accumulation No information available. Mobility Is not likely mobile in the environment due its low water solubility.
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Component log Pow Benzoic acid, 3-nitro-, methyl ester 1.
13. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT Not regulated TDG Not regulated IATA Not regulated IMDG/IMO Not regulated 15. Regulatory information United States of America Inventory Component CAS No TSCA TSCA Inventory notification - Active-Inactive TSCA - EPA Regulatory Flags Benzoic acid, 3-nitro-, methyl ester 618-95-1 X ACTIVE - Legend: TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710) X - Listed '-' - Not Listed TSCA 12(b) - Notices of Export Not applicable International Inventories Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), China (IECSC), Korea (KECL). Component CAS No DSL NDSL EINECS PICCS ENCS ISHL AICS IECSC KECL Benzoic acid, 3-nitro-, methyl ester 618-95-1 - X 210-573-0 - X X - X - KECL - NIER number or KE number (http://ncis.nier.go.kr/en/main.do) U.S. Federal Regulations SARA 313 Not applicable SARA 311/312 Hazard Categories See section 2 for more information CWA (Clean Water Act) Not applicable Clean Air Act Not applicable OSHA - Occupational Safety and Health Administration Not applicable CERCLA Not applicable California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Not applicable
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