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Concepts and Calculations in Molecular Mass and Formula Mass, Study notes of Chemistry

Various concepts and calculations related to molecular mass and formula mass, including determining molar mass, mass in grams, number of moles, and percent composition of compounds. It also discusses empirical and molecular formulas, and their relationship with elemental composition and molar mass.

Typology: Study notes

2021/2022

Uploaded on 09/12/2022

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Molecular Mass
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Molecular Mass

synonymous with molar mass and

molecular weight

Molecular Mass

is the sum of the atomic masses of all

the atoms in a molecule

the mass in grams of one mole of a

compound

Determine the molar mass of Sr(NO 3 ) 2. pg. 322 problem 25 1 mol Sr(NO 3 ) 2 2 mol N = 2(14.00 g) 1 mol Sr = 87.62g 6 mol O = 6(16.00 g) = 211.62 g

pg. 323 problem 27 What is the mass in grams of 3.25 mol sulfuric acid ( H 2 SO 4 ). 3.25 mol H 2 SO 4 98.07 g H 2 SO 4 1 mol H 2 SO 4 x = 319 g H 2 SO 4 1 mol H 2 SO 4 2 mol H = 2(1.00 g) 1 mol S = 32.07g 4 mol O = 4(16.00 g) = 98.07 g

pg. 326 problem 31a A sample of silver chromate (Ag 2 CrO 4 ) has a mass of 25.8 g. 25.8 g Ag 2 CrO 4 1 mol Ag 2 CrO 4 331.74 g Ag 2 CrO 4 x = 9.36 x 10 22 ions Ag

1 mol Ag 2 CrO 4 1 mol Cr = 52.00 g 2 mol Ag = 107.87g 4 mol O = 4(16.00 g) = 331.74 g a. How many Ag

ions are present? 2 mol Ag

1 mol Ag 2 CrO 4 x 6.02 x 10 23 ions Ag

1 mol Ag

x

pg. 326 problem 31b A sample of silver chromate (Ag 2 CrO 4 ) has a mass of 25.8 g. 25.8 g Ag 2 CrO 4 1 mol Ag 2 CrO 4 331.74 g Ag 2 CrO 4 x = (^) 4.68 x 10^22 atoms CrO 4 2- 1 mol Ag 2 CrO 4 1 mol Cr = 52.00 g 2 mol Ag = 107.87g 4 mol O = 4(16.00 g) = 331.74 g b. How many CrO 4 2- ions are present? 1 mol CrO 4 2- 1 mol Ag 2 CrO 4 x 6.02 x 10 23 ions CrO 4 2- 1 mol CrO 4 2- x

Percent Composition

of Compounds

Percent composition is the percent by

mass of each element the compound

contains.

Obtained by dividing the mass of each

element in one mole of the compound by

the molar mass of the compound and

multiplying by 100%

Molar mass = 3(1.008g) + 30.97g + 4(16.00) = 97.

%H =^ x^ 100 % =

97.99g

3(1.008g)

%P = x 100% =

30.97g

97.99g

%O = 100% =

x

97.99g

Example

A sample of a compound containing carbon and

oxygen had a mass of 88g. Of this sample 24g

was carbon, 64g was oxygen. What is the

percent composition of this compound.

%oxygen = 100% =

88g

x

64g

%carbon = 100% =

88g

x

24g

Elemental Composition

Levels of Structure

Empirical Formula

Molecular Formula

Constitution

Configuration

Conformation

Examples:

Elemental Composition

Formaldehyde Glucose

C: 40.00% C: 40.00%

H: 6.73% H: 6.73%

O: 53.27% O: 53.27%

The empirical formula tells us which

elements are present and the simplest

whole-number ratio of their atoms.

Empirical Formula

Examples: Formaldehyde and Glucose

Empirical Formula

Elemental Composition

C: 40.00%

H: 6.73%

O: 53.27%

assume a 100g sample

calculate atom ratios by dividing by atomic

weight

40.00 g

6.73 g

53.27 g