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Chemistry Exam II, October 2007, Exams of Chemistry

A chemistry exam from october 2007, consisting of multiple-choice questions and problems related to various topics in chemistry such as thermodynamics, quantum mechanics, and periodic table. The exam covers concepts like energy changes, specific heat, enthalpy of formation, electron configurations, and ionization energies.

Typology: Exams

Pre 2010

Uploaded on 12/04/2009

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Chemistry 105 Exam II October 26, 2007
I certify I have not used a programming calculator for anything other than simple mathematical
operations.
_______________________________________ (Signature)
_______________________________________ (Printed name)
Multiple choice (3 pts. each) DARKEN THE CORRECT ANSWER ON THE ANSWER
SHEET. Remember there are also 4 problems given after the multiple-choice questions.
Budget your time accordingly.
1. Which process is not exothermic?
a) Burning wood
b) Making ice
c) Boiling water
d) Condensation of water vapor
e) all of the above
2. Determine E for a system that absorbs 67.8 kJ of heat while doing 46.9 kJ of work on the
surroundings.
a) -114.7 kJ
b) 20.9 kJ
c) 67.8 kJ
d) 114.7 kJ
e) -20.9 kJ
3. The specific heat of toluene, C7H8, is 1.13 J/g-K. How many joules of heat are needed to raise
the temperature of 35.0g from 11.8C to 29.0C?
a) 2.30 J b) 39.6 J
c) 680 J d) 19.4 J
4. Which of the following statements is/are true concerning E?
a) When PV is small, E approximates H.
b) E is measured at constant volume.
c) The bomb calorimeter is used to measure E.
d) All of the above.
5. Consider the following reactions and their associated values of H°.
B2H6(g) + 3O2(g) B2O3(s) + 3H2O(l)H° = -2147.5 kJ
4B(s) + 3O2(g) 2B2O3(s)H° = -2509.1 kJ
H2(g) + 1/2O2(g) H2O(l)H = -285.85 kJ
What is the standard enthalpy of formation of gaseous diborane, B2H6?
a) 35.4 kJ b) -933.2 kJ c) -3080.7 kJ d) -4259.1kJ
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Chemistry 105 Exam II October 26, 2007 I certify I have not used a programming calculator for anything other than simple mathematical operations. _______________________________________ (Signature) _______________________________________ (Printed name) Multiple choice (3 pts. each) DARKEN THE CORRECT ANSWER ON THE ANSWER SHEET. Remember there are also 4 problems given after the multiple-choice questions. Budget your time accordingly.

  1. Which process is not exothermic? a) Burning wood b) Making ice c) Boiling water d) Condensation of water vapor e) all of the above
  2. Determine E for a system that absorbs 67.8 kJ of heat while doing 46.9 kJ of work on the surroundings. a) -114.7 kJ b) 20.9 kJ c) 67.8 kJ d) 114.7 kJ e) -20.9 kJ
  3. The specific heat of toluene, C 7 H 8 , is 1.13 J/g-K. How many joules of heat are needed to raise the temperature of 35.0g from 11.8C to 29.0C? a) 2.30 J b) 39.6 J c) 680 J d) 19.4 J
  4. Which of the following statements is/are true concerning E? a) When PV is small, E approximates H. b) E is measured at constant volume. c) The bomb calorimeter is used to measure E. d) All of the above.
  5. Consider the following reactions and their associated values of H°. B 2 H 6 ( g ) + 3O 2 ( g )  B 2 O 3 ( s ) + 3H 2 O( l ) H° = -2147.5 kJ 4B( s ) + 3O 2 ( g )   2B 2 O 3 ( s ) H° = -2509.1 kJ H 2 ( g ) + 1/2O 2 ( g )  H 2 O( l ) H = -285.85 kJ What is the standard enthalpy of formation of gaseous diborane, B 2 H 6? a) 35.4 kJ b) -933.2 kJ c) -3080.7 kJ d) -4259.1kJ

benzene acetylene

  1. Consider the decomposition of liquid benzene to gaseous acetylene. 3 1 C 6 H 6 ( l )  C 2 H 2 ( g ) H = 210 kJ What is the H for decomposition of 2 moles of benzene to acetylene? a) 210 kJ b) 630 kJ c) -1260 kJ d) -210 kJ e) 1260 kJ
  2. 0.50 mole of ammonium nitrate is added to 50.0 ml of water in a coffee cup calorimeter. Both are initially at 20.0C. After stirring, the temperature of the solution is found to be less than 10 C. Which statement best explains the temperature change? a) Heat is evolved from the system to the surroundings. b) Heat is absorbed by ammonium nitrate when it dissolves and becomes hydrated. c) Heat is evolved by ammonium nitrate when it dissolves and becomes hydrated. d) The process is exothermic.
  3. Which of the following statements is not true about the principal quantum number, n? a) It is related to the spin of an electron. b) It is related to the energy of an electron. c) The larger the n value of an electron, the higher its energy. d) The larger the n value of an electron, the larger the value of its Bohr radius. e) The lowest energy state for an electron in a Bohr atom corresponds to n =1.
  4. What is the frequency (in Hz) of electromagnetic radiation emitted by an electronic transition from n=7 to n=3 in a hydrogen atom? (RH = 2.18 x 10-^18 J, c = 3.0 x 10^8 m/s, h = 6.63 x 10-34J · s.) a) 2.0 x 10-21Hz b) 2.8 x10-17Hz c) 3.0 x 10^14 Hz d) 1.3 x 10^17 Hz
  5. For the principal quantum number 2, what are the allowed values for the associated azimuthal quantum number? a) 0, 1, and 2 b) 0, -1, and - c) -1, 0, 1 d) 2, 1, 0, -1, - e) none of the above

11. When = 1, the designated subshell can maximally hold how many electrons?

a) 14 b) 10 c) 8 d) 6 e) 2

  1. Which of the following characteristics does not describe a metal? a) shiny b) malleable c) poor conductors d) ductile e) form cations
  2. Which of the following elements forms an acidic oxide? a) Cs b) Cr c) Ca d) C e) Cu
  3. Which group has the largest first ionization energy (I 1 ) of the elements in each period? a) halogens b) alkaline earths c) alkali metals d) chalcogens (O, S, Se, Te) e) inert gases
  4. Which one of the elements below has the largest atomic radius? a) Zn b) Ga c) Ca d) Cr e) Br YOU MUST SHOW YOUR WORK ON THE ANSWER SHEET FOR THE FOLLOWING PROBLEMS
  5. (10 pts.) Calculate

H (^) rxn(in kJ) for the following process. Explain if the reaction is exothermic or endothermic. 4NH 3 ( g ) + O 2 ( g )  2N 2 H 4 ( g ) + 2H 2 O(l) Substance         mole kJ Hf NH 3 (g) -46. N 2 H 4 (g) 95. H 2 O(l) -285. NO 2 (g) 33.

  1. (11 pts.) An M&M candy is approximately 0.76g. Assuming complete combustion of the candy in a bomb calorimeter with heat capacity of 5.431 kJ/C with a temperature change from 25.00C to 27.93C, give the energy content of the candy in kilocalories/gram (same as food calories, 1 calorie = 4.184 J). How many kilocalories are there in a 47.9g package?
  2. (12 pts.) Write the electron configurations for the ground states of Ti and I using longhand notation. Label both the core electrons and the valence electrons. How many unpaired electrons are present?
  3. (5 pts.) Define the ionization energy of an atom. Explain the trends of first ionization energy on the periodic chart.

ANSWER KEY – Exam 2 - 2007

  1. C 2. B 3. C
  2. D 5. A 6. E
  3. B 8. A 9. C
  4. E 11. D 12. B
  5. E 14. C 15. B
  6. B 17. A 18. C
  7. D 20. E 21. C
  8. (10 pts.) 4NH 3 ( g ) + O 2 ( g )  2N 2 H 4 ( g ) + 2H 2 O(l) H 196.1 kJ ) mole kJ ) 4 moles( 46. 19 mole kJ ) 2 moles( 285. 83 mole kJ H 2 moles( 95. 4 H 2 moles( HN H ) 2 moles( HH O) 4 moles( H NH ) rxn rxn rxn f 2 4 f 2 f 3                       The reaction is exothermic. Heat is given off as indicated by the negative value of H.
  9. (11 pts.)

2.4 10 kcal g 5.0 kcal

  1. 9 g g kcal

  2. 0 0.76 g 3 .80 kcal

  3. 80 kcal 4.184 kJ 1 kcal

  4. 9 kJ

  5. 93 C 15. 9 kJ C kJ q 5. 431 ΔTT 27.93C-25.00C 2. 93 C 2 rxn.                

  6. (12 pts.) Ti 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^2 2 unpaired electrons I 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^10 4p^6 4d^10 5s^2 5p^5 1 unpaired e-

  7. (5pts.) The ionization energy is the minimum energy required to remove an electron from the ground state of an isolated atom in the gaseous phase. Ionization energy (I 1 ) increases from left to right in a row and decreases from top to bottom in a column. core valence core valence