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Material Type: Exam; Professor: Ye; Class: Organic Chemistry II; Subject: Chemistry; University: University of Central Florida; Term: Summer Session 2010;
Typology: Exams
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CHM2211-0001 Fall 2010 Instructor: Dr. Jingdong Ye
September 17, 2010 Total number of questions: 25 Total points: 25 Exam duration: 50 min Note: choose only one correct and best answer for each question! Tip: work on the easy and fast questions first, come back for harder ones.
c. (i) 3; (ii) 5 d. (i) 4; (ii) 6 e. none of the above
a. 1. Cl 2 , FeCl 3 ; 2. HNO 3 , H 2 SO 4 ; 3. CH 3 Cl, AlCl 3 ; 4. KMnO 4 , H 3 O+ b. 1. HNO 3 , H 2 SO 4 ; 2. Cl 2 , FeCl 3 ; 3. CH 3 Cl, AlCl 3 ; 4. KMnO 4 , H 3 O+ c. 1. HNO 3 , H 2 SO 4 ; 2. CH 3 Cl, AlCl 3 ; 3. Cl 2 , FeCl 3 ; 4. KMnO 4 , H 3 O+ d. 1. CH 3 Cl, AlCl 3 ; 2. HNO 3 , H 2 SO 4 ; 3. Cl 2 , FeCl 3 ; 4. KMnO 4 , H 3 O+
CH 3 CCH 2 CH 2 COCH 3 O O CH 3 CHCH 2 CH 2 COCH 3 OH O CH 3 CCH 2 CH 2 COCH 3 O O CH 3 CHCH 2 CH 2 CH 2 OH OH
(i)
H 3 O+
(ii)
H 3 O+
(iii)
H 3 O+ a. (i) LiAlH 4 , (ii) LiAlH 4 , (iii) LiAlH 4 b. (i) NaBH 4 , (ii) NaBH 4 , (iii) NaBH 4 c. (i) LiAlH 4 , (ii) NaBH 4 , (iii) NaBH 4 d. (i) NaBH 4 , (ii) NaBH 4 , (iii) LiAlH 4 e. (i) NaBH 4 , (ii) LiAlH 4 , (iii) LiAlH 4
Which of the following transformation is correct? C O CH 3 + BrMgCH 3 C O OCH 3 +^2 BrMgCH 3 C O CH 3 CH 3 + BrMg C OH CH 3 CH 3 a. b. c. d. All of the above.
The follow dehydration can be done with? OH a. H 3 O+, 50 oC b. HBr c. POCl 3 , pyridine d. both a and b e. both a and c
The best route for the following transformation is?
Key: 1.b 2.e 3.d 4.c 5.a 6.a 7.d 8.b 9.d 10.b 11.a 12.e 13.c 14.d 15.d 16.b 17.a 18.c 19.c 20.e 21.d 22.e 23.d 24.c 25.a