Chapter 3
•Brønsted/Lowery Acid/Base Reactions
•Lewis Acid/Base Reactions
Chapter 6
•SN2
•SN1
Chapter 7
•E2
•E1
•Dehydration of Alcohols to form Alkenes (E1)
(Carbocation Rearrangement)
•Dihalide Synthesis of Alkynes (2 E2)
•Terminal Alkyne Conversion to Nucleophiles
(Acid/Base then SN2)
•Hydrogenation of Alkynes to form Alkanes
•Synthesis of Cis Alkenes from Alkynes
•Synthesis of Trans Alkenes from Alkynes
Chapter 8
•Addition of Hydrogen Halides to Alkenes to
form Halides (Markovnikov) (Regioselective)
•Addition of Other Things to Alkenes to form
Halides (Regioselective)
•Hydration of Alkenes
•Acid-Catalyzed Addition of Water to Alkenes
to form Alcohols
•Oxymercuration-Demercuration to form
Alcohols (Avoids Carbocation Rearrangement)
•Hydroboration of Alkenes to form Alcohols
(Avoids Markovnikov’s)
•Addition of Br2 and Cl2 to Alkenes to form
Dihalides
•Synthesis of Halohydrins (Same as Above
Topic, but Utilizes Water)
•Addition of Br2 and Cl2 to Alkynes
•Carbenes
•Carbenes from Diazomethane
•Carbenes from Alpha-Elimination
•Carbenes from the Simmon-Smith Reaction
•Oxidation of Alkenes
•Oxidative Cleavage of Alkenes
•Hot KMnO4
•Ozonolysis
Chapter 10
•Br2 and Cl2 Radical Reactions with Alkanes
•NBS
•Anti-Markovnikov Addition of HBr to Alkenes
Chapter 11
•Reactions of Alcohols with H-X
•PBr3/SOCl2
•Tosylates, Mesylates, and Triflates
•Willianson Ether Synthesis
•Intermolecular Dehydration of Alcohols
•Oxymercuration-Demercuration Synthesis of
Ethers
•Cleavage of Ethers using H-X
•TBS
•MCPBS
•Base-Catalyzed Reactions of Epoxides
•Acid-Catalyzed Reactions of Epoxides
