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PSU Chem 210 Final Review questions with accurate detailed answers
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E2 || Reaction || - || Correct || answer || ✔One-Step || with || no || intermediates, || Base || takes || off || proton || + || LG || leaves || with || double || bond || formation. What || type || of || carbons || do || E2 || rxns || favor? || - || Correct || answer || ✔Tertiary What || is || a || Zaitsev || product? || - || Correct || answer || ✔Double || bond || formation || on || more || substituted || carbon What || is || a || Hoffman || product? || - || Correct || answer || ✔Double || bond || formation || on || less || substituted || carbon When || using || a || stericallly || hindered || base || (t-BuOK, || LDA), || which || product || is || more || favorable? || - || Correct || answer || ✔Hoffman When || using || Eto- || or || less || sterically || hindered || base, || which || product || is || more || favorable? || - || Correct || answer || ✔Zaitsev E1 || Reaction || - || Correct || answer || ✔ 2 || step || process, || LG || leaves || and || forms || carbocation, || then || base || takes || off || proton || and || makes || double || bond
What || type || of || carbocations || do || elimination || reactions || prefer? || - || Correct || answer || ✔Tertiary What || is || the || rate || determining || step || of || an || E1 || reaction? || - || Correct || answer || ✔LG || leaving What || stereochemistry || do || E1 || reactions || usually || want? || - || Correct || answer || ✔Trans If || the || substrate || is || OH || in || a || potential || E1 || reaction, || what || must || be || done || before || anything || else? || - || Correct || answer || ✔Need || a || SA || to || protonate What || makes || a || better || nucleophile? || - || Correct || answer || ✔Large || atoms What || do || halogens || usually || react || as? || - || Correct || answer || ✔Nucleophiles What || energy || level || does || the || electrophile || contribute || to? || - || Correct || answer || ✔Lumo What || energy || level || does || the || nucleophile || contribute || to? || - || Correct || answer || ✔Homo If || OH || is || a || leaving || group, || what || can || you || convert || it || to? || - || Correct || answer || ✔TsCl
What || type || of || electrophiles || does || Sn2 || rxns || favor? || - || Correct || answer || ✔Primary What || type || of || nucleophiles || does || Sn2 || favor? || - || Correct || answer || ✔Strong || (neg || charge) What || type || of || solvents || does || Sn2 || like? || - || Correct || answer || ✔Polar || Aprotic || (DMSO, || DME, || DMF) Sn1 || Reactions || - || Correct || answer || ✔LG || leaves, || carbocation || intermediate || forms, || then || nucleophile || attacks || to || get || racemic || mixture || of || products. What || type || of || electrophile || intermediates || do || Sn1 || reactions || like? || - || Correct || answer || ✔Tertiary What || type || of || nucleophile || do || Sn1 || reactions || like? || - || Correct || answer || ✔Weak || (H20, || F-, || ROH) The || leaving || group || of || a || Sn1 || type || reaction || must || be || ____________. || - || Correct || answer || ✔Highly || stabilized. || (CB || of || SA) What || is || the || rate || determining || step || of || an || Sn1 || Reaction? || - || Correct || answer || ✔LG || leaving || (like || E1)
What || does || a || markovnikov || reaction || indicate? || - || Correct || answer || ✔Placing || X || (HX) || on || the || more || the || substituted || carbon What || does || a || anti-markovnikov || reaction || indicate? || - || Correct || answer || ✔Placing || H || (HX) || on || the || more || substituted || carbon When || is || stereochemistry || relevant? || - || Correct || answer || ✔When || two || stereocenters || are || being || formed When || is || regiochemistry || relevant? || - || Correct || answer || ✔When || adding || two || different || groups || to || a || double || bond When || is || a || meso || compund || relevant? || - || Correct || answer || ✔When || two || stereocenters || are || R || and || S Hydrogenation || Reaction || - || Correct || answer || ✔Adding || H+H || across || a || double || bond || on || alkene || and || stereochemistry || is || syn. || WATCH || for || meso! Hydride || shifts || in || addition || reactions || - || Correct || answer || ✔When || methyls || shift || to || more || substituted || carbons || for || better || stability. Markovnikov || HX || addition || reaction || - || Correct || answer || ✔X || ends || up || on || more || substituted || carbon