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It contains objective and assertion-reason type questions with detailed solutions.
Typology: Exercises
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1. Nylon-6 is made from [MP PMT 2002; BHU 2002]
(a) Butadiene (b) Chloroprene (c) Adipic acid (d) Caprolactum
2. A polymer containing nitrogen is
[UPSEAT 2004; MP PET 2003] (a) Bakelite (b) Dacron (c) Rubber (d) Nylon- 66
3. Cellulose acetate is a [JIPMER 2002]
(a) Natural polymer (b) Semisynthetic polymer (c) Synthetic polymer (d) Plasticiser
4. Ethylene-propylene rubber can be
(a) Vulcanized by sulphur (b) Vulcanized by peroxides (c) Both (a) and (b) (d) Non-vulcanizable
5. Buna-S is a polymer of [CPMT 1987; JIPMER 1999]
(a) Butadiene and styrene (b) Butadiene (c) Styrene (d) Butadiene and chloroprene
6. Nylon is generic name for all synthetic fibre forming (a) Polyesters (b) Polymeric amides (c) Polystyrene (d) Polyethylene 7. Polymerisation in which two or more chemically different monomers take part is called [MP PMT 1991, 93]
(a) Addition polymerisation (b) Copolymerisation (c) Chain polymerisation (d) Homopolymerisation
8. Whether small molecules liberate in addition polymerisation (a) Yes (b) No (c) Sometimes (d) Only H 2 O 9. Orlon has a unit [AFMC 2004] (a) Vinyl cyanide (b) Acrolein (c) Glycol (d) Isoprene 10. The common acid used in the manufacture of rayon and plastics is [Kerala (Engg.) 2002] (a) Methanoic acid (b) Ethanoic acid (c) Propanoic acid (d) Butanoic acid 11. Buna-s rubber is which of the following of 1- 3 - butadiene and styrene [Pb. PMT 2000] (a) Polymers (b) Copolymer (c) Addition (d) Condensation polymer 12. Which one of the following polymers will not catch fire [MP PET 1994] (a) (^) ( CF 2 (^) CF 2 ) n (b)( CH (^) 2 CH 2 ) n (c) n Cl
CH Cl
( CH | | ) (d) n Cl
( CH (^) 2 CH | )
1. (d) Caprolactun is the monomer of nylon – 6. 2. (d) Nylon- 66 - It is a polymer containing alitrogen
n
||
Ny lon- 66
||^24
| 26
| ( ) ( )
3. (b) Because cellulose is a natural polymer. 4. (b) It is vulcanized by peroxide because it requires the more electronegative element to form cross - link structure. 5. (a) Styrene 2 2 2
Butadiene
2 2 2 ( )
( ) ( CH CH CH CH CH CH n
Na
nCH CH CH CH nCH CH
It is also called SBR (styrene butadiene rubber).
6. (b) Nylon is a polyamide fibre representing the polyamide linkage. 7. (b) e.g. Adipicacid Hexamethylenediamine Nylon - 6 6 8. (b) In addition polymerization simple addition of monomer unit takes place without any loss of small molecules. 9. (a) Orlon is prepared by polymerization of vinyl cyanide in presence of ferrous sulphate & hydrogen peroxide
Orlon
Poly merisation^2 2 | FeSO (^) 4 H 2 O 2 CN n
nCH CHCN
10. (b) Ethanoic acid is used in the manufacture of regin and plastics. 11. (b) Buna- S is a coplymer of 1, 3- butadiene and styrene. 12. (a) Teflon ( CF 2 (^) CF 2 ) n is stable upto 598 K.