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Physical Properties of
Solvents
Solvents Density Boiling
Point
(^0 C)
Melting
Point
(^0 C)
UV Cut
off (nm)
Miscibi
lity
with
Water
1,1,2 Trichlorotrifluoroethane 1.570 47 - 48 - 35 231 X 1,2-Dichlorobenzene 1.306 180 - 17 295 X 1,2-Dichloroethane 1.256 83 - 35 225 X 1,3-Dimethyl- 2 - imidazolinone (DMI)
1.056 224 - 226 8.2 - O
1,3-Dimethyl-3,4,5,6- tetrahydro - 2(1H)- pyrimidinone (DMPU)
mm Hg)
- 20 - O
1,4-Dioxane 1.034 100 - 102 12 215 O 1 - Butanol 0.810 117.7 - 90 215 P 1 - Chlorobutane 0.886 77 - 78 - 123 225 X 1 - Methyl- 2 - pyrrolidinone (NMP)
mm Hg)
285 O
1 - Octanol 0.827 196 - 15 215 X 1 - Propanol 0.804 97 - 127 210 O 2,2,4-Trimethylpentane 0.692 98 - 99 - 107 215 X 2 - Butanone 0.805 80 - 87 329 P 2 - Chloropyridine 1.209 168 - 46 - P 2 - Methoxyethanol 0.965 124 - 125 - 85 210 O 2 - Methoxyethyl acetate 1.009 145 - 65 254 P
2 - Methyl- 1 - propanol 0.803 108 - 108 200 X 2 - Methyl- 2 - propanol 0.775 83 25 - 26 215 O 2 - Methylbutane 0.620 30 - 192 X 2 - Methylpyridine 0.943 128 - 129 - 70 - O 2 - Propanol 0.785 82.4 - 89.5 210 O 3 - Chloropyridine 1.194 148 66 - P 3 - Methyl- 1 - butanol 0.809 130 - 117 215 X 3 - Pentanone 0.813 102 - 40 330 X 4 - Methyl- 2 - pentanone 0.801 117 - 118 - 80 334 X Acetic acid (AcOH) 1.049 118 17 - O Acetic anhydride 1.082 138 - 140 - 73 - - Acetone 0.791 56 - 94 330 O Acetonitrile 0.786 82 - 48 190 O Benzene 0.874 80 6 280 X Benzonitrile 1.010 191 - 13 300 X Butyl acetate 0.882 124 - 126 - 78 254 X Carbon disulfide 1.266 46 - 112 380 X Carbon tetrachloride 1.594 77 - 23 263 X Chlorobenzene 1.106 132 - 45 287 X Chloroform 1.492 61 - 64 245 X Cyclohexane 0.779 80 7 200 X Cyclopentane 0.751 50 - 94 200 X Di(ethylene glycol) diethyl ether
260 X
Dichloromethane 1.325 40 - 97 233 X
Tetrahydrofuran (THF) 0.889 65 - 67 - 108 212 P Toluene 0.865 110.6 - 93 284 X Triethylamine (Et 3 N) 0.728 89.3 - 114.7 - O Water 1.000 100 0 <190 O O: freely miscible P: partially miscible X: practically immiscible (solubility: less than 1%)
Abbreviations (Solvents)
BCS Butyl Cellosolve CAC Cellosolve acetate DAA Diacetone alcohol DCM Dichloromethane DIBK Diisobutyl ketone DMA N,N - Dimethylacetamide DMI 1,3-Dimethyl- 2 - imidazolinone DMF N,N - Dimethylformamide DMK Acetone DMPU 1,3-Dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone EAc Ethyl acetate HMPA Hexamethylphosphoric Triamide IBA Isobutyl alcohol IPA Isopropyl alcohol IPE Di isopropyl ether MEK Methyl ethyl ketone MIBK Methyl isobutyl ketone MMA Methyl methacrylate NBA n-Butyl alcohol NMP 1 - Methyl- 2 - pyrrolidinone THF Tetrahydrofuran
Trityl Triphenylmethyl- Tosyl p - Toluenesulfonyl- Ts p - Toluenesulfonyl- Z Carbobenzoxy- (Benzyloxycarbonyl-)
Abbreviations (Solids)
BSA N,O - Bis(trimethylsilyl)acetamide AIBN 2,2'-Azobis(isobutyronitrile) CD Cyclodextrin CSA Camphorsulfonic Acid DAST (Diethylamino)sulfur Trifluoride DBU 1,8-Diazabicyclo[5.4.0]- 7 - undecene DCC N,N' - Dicyclohexylcarbodiimide DEAD Diethyl Azodicarboxylate Deoxo-Fluor Bis(2-methoxyethyl)aminosulfur trifluoride DHP 3,4-Dihydro-2H-pyran dmit 4,5-Dimercapto-1,3-dithiole- 2 - thione DOXYL 4,4-Dimethyloxazolidine- 1 - oxyl DVB Divinylbenzene EDC 3 - (3-Dimethylaminopropyl)- 1 - ethylcarbodiimide EDTA Ethylenediaminetetraacetic Acid Fc Ferrocene HMDS 1,1,1,3,3,3-Hexamethyldisilazane HMPT Hexamethylphosphorous Triamide HOAt 1 - Hydroxy- 7 - azabenzotriazole HOBt 1 - Hydroxybenzotriazole m CPBA m - Chloroperoxybenzoic Acid NBS N - Bromosuccinimide NCS N - Chlorosuccinimide NIS N - Iodosuccinimide
