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Study Guide for Chemical Context of Life - General College Chemistry | CHEM 101A, Study notes of Chemistry

Material Type: Notes; Class: General College Chemistry; Subject: Chemistry; University: City College of San Francisco; Term: Unknown 1989;

Typology: Study notes

Pre 2010

Uploaded on 08/18/2009

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Study Guide Chapter 2: The Chemical Context of Life
Campbell et al. Biology. 8th ed., Chapter 2
Study hint: While working through this study guide, make a list of key terms in
the right margin. Usually, these terms are boldfaced in the study guides or they
appear in the referenced figures. Consult one of the glossaries if you are not
sure of definitions.
Do all concept checks.
0. Application
1. Read the interview with Deborah M. Gordon (pp. 28-29). In this interview,
Dr. Gordon draws an analogy between an ant colony and human
development, one of the topics in our class. Ants communicate with each
other through chemical signals, which, as we have seen in chapter 7, also
govern communication between and within cells. Location,
concentration and specificity give meaning to the chemical signals in an
ant colony just as they do in a cell (key strategy 4). What is a complex
system and can cells be considered such?
2. How does exposure to UV light promote skin cancer?
3. Why are most drugs manufactured as salts?
4. Why does a human brain react to the chemical message delivered by
heroin?
5. What are free radicals? Why are they dangerous? And why can you
minimize their negative effects with antioxidants?
Note: usually it is not enough to write down the answers to the following
questions. You also need to understand and learn them. For help memorizing
these concepts check out the interactive "study drills" on your CD ROM or the
worksheet at the Biology Place
I. The big picture
Cells are lipid-bound droplets of water in which various ions and molecules
are dissolved. The properties of life are based on chemical interactions.
6. Chemical interactions are important on every level of biological
organization (see DNA, transmembrane protein channels, and ant
colonies). Whether atoms and molecules interact with each other and to
which effect depends on their location, concentration, and specific
© Crima Pogge, CCSF for Bio 101A, page 1
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Study Guide Chapter 2: The Chemical Context of Life

Campbell et al. Biology. 8th ed., Chapter 2 Study hint: While working through this study guide, make a list of key term s in the right margin. Usually, these terms are boldfaced in the study guides or they appear in the referenced figures. Consult one of the glossaries if you are not sure of definitions. Do all concept checks.

0. Application

  1. Read the interview with Deborah M. Gordon (pp. 28-29). In this interview, Dr. Gordon draws an analogy between an ant colony and human development, one of the topics in our class. Ants communicate with each other through chemical signals, which, as we have seen in chapter 7, also govern communication between and within cells. Location, concentration and specificity give meaning to the chemical signals in an ant colony just as they do in a cell (key strategy 4). What is a complex system and can cells be considered such?
  2. How does exposure to UV light promote skin cancer?
  3. Why are most drugs manufactured as salts?
  4. Why does a human brain react to the chemical message delivered by heroin?
  5. What are free radicals? Why are they dangerous? And why can you minimize their negative effects with antioxidants? Note : usually it is not enough to write down the answers to the following questions. You also need to understand and learn them. For help memorizing these concepts check out the interactive "study drills" on your CD ROM or the worksheet at the Biology Place

I. The big picture

Cells are lipid-bound droplets of water in which various ions and molecules are dissolved. The properties of life are based on chemical interactions.

  1. Chemical interactions are important on every level of biological organization (see DNA, transmembrane protein channels, and ant colonies). Whether atoms and molecules interact with each other and to which effect depends on their location, concentration, and specific

structure ( key concept 4). Illustrate this concept with examples from different levels.

  1. Some of the bonds that hold molecules together need to be strong, others need to be weak. Why? Give examples.

II. Elements and atomic structure

As Chemistry 101A is a prerequisite for Biology 101A, I assume that you are familiar with the following terms. If not, please review. Matter Element Atom Neutron Proton Electron Atomic nucleus Atomic number Mass number Atomic weight Isotope Radioactive isotope Energy level Electron shell Orbital Valence electron Valence shell Cation Anion Molecule Structural formula Molecular formula Electronegativity Polar covalent Ion Chemical reactions Equilibrium Compound

  1. How many of the 92 naturally occurring elements are essential to life?
  2. Name the six elements that make up more than 98% of human body weight and are constituents of proteins, carbohydrates, lipids, and/or nucleic acids (mnemonic: CHNOPS) and list their valences (Figure 2. and p. 39). Element Valence
  1. Compare and contrast the chemical bonds most important for life. Covalent Ionic Hydrogen Definition, basis of interaction Strength under different circumstances Atoms likely to form these bonds, know why
  2. Why is the relevance of the following information? The C-C bond in DNA has a bond energy of 83 kcal/mole, while a mole of photons (500 nm) contains 57 kcal. UV light (300 nm), on the other hand contains 95.3 kcal. Refer to application question 1.
  3. Distinguish between single and double covalent bonds.
  4. Under what circumstances do polar covalent bond s occur?
  5. Explain how the electronegativity of atoms determines which kind of bonds they most likely form with each other.
  6. Compare and contrast hydrogen bonds and van der Waals interactions.
  7. How do electron orbitals affect the size and shape of molecules (Figure 2.17)?
  8. Give an example that illustrates how a molecule’s shape can determine its biological function (e.g., Figure 2.18).
  9. Name one factor that affects the rate of a chemical reaction.
  10. Explain what is meant by a chemical equilibrium. Essay question
  11. Compare and contrast hydrogen, ionic, covalent bonds and van der Waals interactions. Include a definition of each bond, explain between which kinds of atoms each bond forms, and compare the strength of the different bonds. Give examples where applicable.