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Titration Curves: Understanding pH Changes in Acid-Base Reactions, Study Guides, Projects, Research of Chemistry

The concept of titration curves, focusing on the changes in ph during the titration of strong and weak acids and bases using standard solutions. It covers the use of indicators and the production of neutral, basic, and acidic salt solutions.

What you will learn

  • What is a standard solution in a titration?
  • How does the pH change during the titration of a weak acid with a strong base?
  • What indicator should be used for the titration of a weak base with a strong acid?

Typology: Study Guides, Projects, Research

2021/2022

Uploaded on 09/27/2022

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Titration Curves
in order to perform a titration, you must start
with a standardized solution
standard (or standardized) solution = solution
with a precisely known concentration
standard solutions can be prepared by
> using a substance which can be obtained in a pure and stable
form (does not absorb water or CO2 from air) and which has
a known molar mass so that it can be used to prepare a
solution of known concentration (primary standard)
ex. potassium hydrogen phthalate - KHC8H4O4
oxalic acid dihydrate - H2C2O4•2H2O
> titrating a base with an acidic primary standard
a titration curve is produced by plotting the pH
change that occurs during a titration
pf3
pf4

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Titration Curves

  • in order to perform a titration, you must start with a standardized solution standard (or standardized) solution = solution with a precisely known concentration
  • standard solutions can be prepared by

using a substance which can be obtained in a pure and stable form (does not absorb water or CO 2 from air) and which has a known molar mass so that it can be used to prepare a solution of known concentration (primary standard) ex. potassium hydrogen phthalate - KHC 8 H 4 O 4 oxalic acid dihydrate - H 2 C 2 O 4 • 2 H 2 O titrating a base with an acidic primary standard

  • a titration curve is produced by plotting the pH change that occurs during a titration

a) Titration of a strong acid with a strong base

  • the pH rises almost vertically around the value of VB
  • VB is the volume of the base required to reach the equivalence point
  • strong acid - strong base titration produce a neutral salt solution so pH = 7 at the equivalence point
  • choose indicator which changes colour around pH = 7 (pKin = 7 ) such as phenol red or neutral red

c) Titration of a weak base with a strong acid

  • similar to weak acid and strong base, except curve is flipped upside down
  • graph gives pH values not pOH, therefore pHs need to be converted to pOH
  • weak base - strong acid titration produces acidic salt solution with pH < 7 at equivalence point
  • titration requires an indicator which changes colour at pH < 7 (pKa < 7 ) such as methyl red strong acid + strong base → neutral (pH = 7 ) weak acid + strong base → basic (pH > 7 ) strong acid + weak base → acidic (pH < 7 ) Note: Phenolpthalein (pH 8. 2 - 10. 0 ) is used for weak acid - strong base titrations but it is also often used for strong acid - strong base titrations even though pH = 7 at the equivalence point. This is because there is a dramatic colourless to magenta colour change.