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Understanding Ions and the Octet Rule: Formation of Ions and Ionic Bonds, Lecture notes of Chemistry

An in-depth explanation of ions, the octet rule, and the formation of ionic bonds. It covers the concept of atoms gaining or losing electrons to achieve a full outer shell, resulting in cations or anions. The document also includes examples of neutral atoms becoming ions, the making of an ion using the bohr model, and the learning objectives for understanding the topic.

What you will learn

  • How do atoms form ionic bonds?
  • What causes atoms to form ions?
  • What is the octet rule and why is it important?

Typology: Lecture notes

2021/2022

Uploaded on 09/12/2022

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6.1 IONS AND THE OCTET RULE SOLUTION STUDENT NOTES, CLASSWORK AND HW
full
transfer
negative
Octet
full
cation
Ionic
Metal
gain
positive
protons
Electron
gain
anion
inert
Non-metal
lose
Alkali
metals
halogens
valence
lose
atoms
eight
The Noble gases are unreactive or INERT because they have FULL outer shells. With the exception of Helium,
which only has room for 2 electrons in its outer shell, the other Noble gases all have EIGHT electrons in their
outer shell. These observations led scientists to create the OCTET Rule which says that ATOMS prefer to have
FULL outer shells.
In order to have a full outer shell atoms can GAIN or LOSE electrons.
LOSING ELECTRONS FOR A FULL SHELL - Atoms that have lost electrons have an excess of POSITIVE charge
because they have more PROTONS than ELECTRONS. These positive ions are called CATIONS. To remember
this name notice that it has a “t” in it which looks like a +. Atoms with very few VALENCE electrons, such as
Lithium, would need to gain many electrons for a full shell so it is easier for them to LOSE electrons and
become POSITIVE.
GAINING ELECTRONS FOR A FULL SHELL - Atoms that have gained electrons have an excess of NEGATIVE
charge because they have more ELECTRONS than PROTONS. These negative ions are called ANIONS. To
remember this name notice that it has an “n” in it, which is the first letter in “Negative”.
THE BOHR MODEL AND THE MAKING OF AN ION LITHIUM
NEUTRAL LITHIUM ATOM LITHIUM ION
The neutral atom shown at left has a desire for a full outer
shell. Which possibility most easily obtains a full outer most
shell? GAINING 7 or LOSING ONE
How many protons does it have? 3
How many electrons does it have? 2
What is its net (total) charge? +1
(Add the charges for the protons to the charges of the electrons)
+3 + (-2) = +1
The GROUP 1 OR ALKALI metals and Hydrogen will all LOSE
one electron to become 1+ ions. Positive ions are called
CATIONS.
Learning Objectives:
Why/How do atoms form ions?
What is the Octet Rule?
Why/How do atoms form ionic bonds?
What is an ionic bond?
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6.1 IONS AND THE OCTET RULE SOLUTION– STUDENT NOTES, CLASSWORK AND HW

full transfer negative Octet full cation Ionic Metal gain positive protons Electron gain anion inert Non-metal lose Alkali metals

halogens valence lose atoms eight

The Noble gases are unreactive or INERT because they have FULL outer shells. With the exception of Helium, which only has room for 2 electrons in its outer shell, the other Noble gases all have EIGHT electrons in their outer shell. These observations led scientists to create the OCTET Rule which says that ATOMS prefer to have FULL outer shells.

In order to have a full outer shell atoms can GAIN or LOSE electrons.

LOSING ELECTRONS FOR A FULL SHELL - Atoms that have lost electrons have an excess of POSITIVE charge because they have more PROTONS than ELECTRONS. These positive ions are called CATIONS. To remember this name notice that it has a “t” in it which looks like a “+”. Atoms with very few VALENCE electrons, such as Lithium, would need to gain many electrons for a full shell so it is easier for them to LOSE electrons and become POSITIVE.

GAINING ELECTRONS FOR A FULL SHELL - Atoms that have gained electrons have an excess of NEGATIVE charge because they have more ELECTRONS than PROTONS. These negative ions are called ANIONS. To remember this name notice that it has an “n” in it, which is the first letter in “Negative”.

THE BOHR MODEL AND THE MAKING OF AN ION – LITHIUM

NEUTRAL LITHIUM ATOM LITHIUM ION

Draw in the protons and electrons for the NEUTRAL LITHIUM ATOM above. How many protons does it have? 3 How many electrons does it have? 3

What is its net (total) charge? Neutral ( Add the charges for the protons to the charges of the electrons )

  • 3 + (- 3 ) = 0

To obtain a full outer shell it will LOSE one electron. It will lose its VALENCE electron

The neutral atom shown at left has a desire for a full outer shell. Which possibility most easily obtains a full outer most shell? GAINING 7 or LOSING ONE How many protons does it have? 3 How many electrons does it have? 2 What is its net (total) charge? + ( Add the charges for the protons to the charges of the electrons )

  • 3 + ( - 2 ) = + The GROUP 1 OR ALKALI metals and Hydrogen will all LOSE one electron to become 1+ ions. Positive ions are called CATIONS.

Learning Objectives: Why/How do atoms form ions? What is the Octet Rule? Why/How do atoms form ionic bonds? What is an ionic bond?

The Atom and the Ion - Below is an example showing the dot notation of an Alkali Metal atom and how it becomes an ion.

Na  Na

1+

Draw the Lewis Structure (showing the valence electrons around the element symbol) of each atom and the ion it forms. Sodium (Na) is done for you as an example. Group 1 A Alkali Metals and H

Group 2 A Alkali-earth Metals

Group 6 A Oxygen Group

Group 7 A Halogens

Group 8 A Nobles

H  H

1+

He

Li  Li

1+

Be  Be

2 +

O  O

2 +

F  F

1 -

Ne

Na  Na

1+

Mg  Mg

2 +

S  S

2 +

Cl  Cl

1 -

Ar

K  K

1+

Ca  Ca

2 +

Se  Se

Br  Br

1 -

Kr

Elements in these groups LOSE electrons and become + ions called CATIONS.

Elements in these groups GAIN electrons and become - ions called ANIONS.

6-2 IONS FORM BONDS TO CREATE STABILITY

When a metal combines with a non-metal an ionic bond is formed. Salt or Sodium Chloride ( NaCl ) is a good example of a ionic bonding. Sodium ( Na ) has 1 valance electron and Chlorine ( Cl ) has 7 electrons in its outer orbit. If Sodium lost its valance electron, its next shell will be full. But that would also make Sodium a positive ion. If Chlorine gained 1 valance electron, its shell would be full with a maximum of 8 electrons, and it would then be a negative ion. An IONIC bond is when an electron is TRANSFERRED from one atom to another.

The same process can be illustrated with Lewis Structures as shown below.

Sodium is a ALKALI METAL (type of material) and it combines with a HALOGEN (GAS). The VALENCE electron from sodium is TRANSFERRED to chlorine so it has a FULL outer shell. When this happens the atoms are bonded together. The charge combination is the sum of the all the charges +1 + -1 = ZERO.

Other element groups that fithere left off for this exercise.